氧气浓度对劣质煤掺混生活污泥燃烧特性的影响

闫云飞 张磊 张力 雷强 张杰

引用本文: 闫云飞, 张磊, 张力, 雷强, 张杰. 氧气浓度对劣质煤掺混生活污泥燃烧特性的影响[J]. 燃料化学学报, 2013, 41(4): 430-435. shu
Citation:  YAN Yun-fei, ZHANG Lei, ZHANG Li, LEI Qiang, ZHANG Jie. Influence of oxygen concentration on combustion characteristics of inferior coal and sludge mixture[J]. Journal of Fuel Chemistry and Technology, 2013, 41(4): 430-435. shu

氧气浓度对劣质煤掺混生活污泥燃烧特性的影响

    通讯作者: 闫云飞(1978-), 男, 河南平顶山人, 副教授, Tel: 023-65103114, E-mail: yunfeiyan@yahoo.com.cn.
  • 基金项目:

    中央高校基本科研业务费(CDJZR10140011, CDJZR12140034). (CDJZR10140011, CDJZR12140034)

摘要: 采用热重分析方法研究了劣质煤掺混生活污泥在氧气浓度20%、30%、50%、70%、90%条件下的燃烧特性和动力学特性.随着氧气浓度的增加,失重率曲线DTG向低温区移动.对着火温度、失重率峰值以及对应温度、燃尽温度、混合物燃烧综合特性指数进行了对比分析,并对固定碳燃烧阶段的表观活化能进行了计算,结果表明,提高氧气浓度能显著改善燃烧条件,表观活化能随着氧气浓度的提高而增大,随掺混比的增加而减小.定义燃烧促进因子C.E.F.(Combustion Enhancement Factor)表征燃料内外部燃烧促进条件,在固定碳燃烧段,燃烧促进因子随氧气浓度增加迅速增大,表明增大氧气浓度对燃烧具有良好促进作用.燃烧促进因子C.E.F.与表观活化能之间具有动力学补偿效应.

English

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    1. [1] 樊越胜, 邹峥, 高巨宝, 曹子栋. 富氧气氛中煤粉燃烧特性改善的实验研究[J]. 西安交通大学学报, 2006, 40(1): 20-21. (FAN Yue-sheng, ZOU Zheng, GAO Ju-bao, CAO Zi-dong. Experimental research of rich oxygen content on improving combustion characteristics of pulverized coal[J]. Journal of Xi’an Jiao Tong University, 2006, 40(1): 20-21.)[1] 樊越胜, 邹峥, 高巨宝, 曹子栋. 富氧气氛中煤粉燃烧特性改善的实验研究[J]. 西安交通大学学报, 2006, 40(1): 20-21. (FAN Yue-sheng, ZOU Zheng, GAO Ju-bao, CAO Zi-dong. Experimental research of rich oxygen content on improving combustion characteristics of pulverized coal[J]. Journal of Xi’an Jiao Tong University, 2006, 40(1): 20-21.)

    2. [2] 韩亚芬. 富氧条件下煤燃烧特性的热重法实验研究. 哈尔滨: 哈尔滨工业大学, 2007. (HAN Ya-fen. Study on combustion characteristics of coal at oxygen enriched condition by thermogravimetric. Harbin: Harbin Institute of Technology, 2007.)[2] 韩亚芬. 富氧条件下煤燃烧特性的热重法实验研究. 哈尔滨: 哈尔滨工业大学, 2007. (HAN Ya-fen. Study on combustion characteristics of coal at oxygen enriched condition by thermogravimetric. Harbin: Harbin Institute of Technology, 2007.)

    3. [3] 刘国伟, 董芃, 韩亚芬, 别如山. 富氧条件下煤燃烧特性的热重分析实验研究[J]. 哈尔滨工业大学学报, 2011, 1(43): 104-108. (LIU Guo-wei, DONG Peng, HAN Ya-fen, BIE Ru-shan. Experimental study on combustion characteristics of coals under enriched-oxygen condition by thermo-gravimetric analysis[J]. Journal of Harbin Institute of Technology, 2011, 1(43): 104-108.)[3] 刘国伟, 董芃, 韩亚芬, 别如山. 富氧条件下煤燃烧特性的热重分析实验研究[J]. 哈尔滨工业大学学报, 2011, 1(43): 104-108. (LIU Guo-wei, DONG Peng, HAN Ya-fen, BIE Ru-shan. Experimental study on combustion characteristics of coals under enriched-oxygen condition by thermo-gravimetric analysis[J]. Journal of Harbin Institute of Technology, 2011, 1(43): 104-108.)

    4. [4] MURPHY J J, SHADDIX C R. Combustion kinetics of coal chars in oxygen-enriched environments[J]. Comb Flame, 2006, 144(4): 710-729.[4] MURPHY J J, SHADDIX C R. Combustion kinetics of coal chars in oxygen-enriched environments[J]. Comb Flame, 2006, 144(4): 710-729.

    5. [5] QIN Y P, LIU W, YANG C, FAN Z Z, WANG L L, JIA G W. Experimental study on oxygen consumption rate of residual coal in goaf[J]. Safety Science, 2012, 50(4): 787-791.[5] QIN Y P, LIU W, YANG C, FAN Z Z, WANG L L, JIA G W. Experimental study on oxygen consumption rate of residual coal in goaf[J]. Safety Science, 2012, 50(4): 787-791.

    6. [6] YUZBASI N S, SELUK N. Air and oxy-fuel combustion behaviour of petcoke/lignite blends[J]. Fuel, 2012, 92(1): 137-144.[6] YUZBASI N S, SELUK N. Air and oxy-fuel combustion behaviour of petcoke/lignite blends[J]. Fuel, 2012, 92(1): 137-144.

    7. [7] LIU H, ZAILANI R, GIBBS B M. Comparisons of pulverized coal combustion in air and in mixtures of O2/CO2 [J]. Fuel, 2005, 84(7-8): 833-840.[7] LIU H, ZAILANI R, GIBBS B M. Comparisons of pulverized coal combustion in air and in mixtures of O2/CO2 [J]. Fuel, 2005, 84(7-8): 833-840.

    8. [8] 万嘉瑜, 金余其, 池涌. 不同氧浓度下城市污泥燃烧特性及动力学分析[J]. 中国电机工程学报, 2010, 5(30): 35-40. (WAN Jia-yu, JIN Yu-qi, CHI Yong. Study on combustion characteristics and kinetics of municipal sludge under different oxygen concentrations[J]. Proceedings of the CSEE, 2010, 5(30): 35-40.)[8] 万嘉瑜, 金余其, 池涌. 不同氧浓度下城市污泥燃烧特性及动力学分析[J]. 中国电机工程学报, 2010, 5(30): 35-40. (WAN Jia-yu, JIN Yu-qi, CHI Yong. Study on combustion characteristics and kinetics of municipal sludge under different oxygen concentrations[J]. Proceedings of the CSEE, 2010, 5(30): 35-40.)

    9. [9] 李春雨, 蒋旭光, 费振伟, 安春国, 池涌, 严建华,俞恺, 傅娟娟, 潘金华, 施政. 制革、造纸和湖泊污泥燃烧特性的研究[J]. 燃料化学学报, 2009, 6(37): 757-762. (LI Chun-yu, JIANG Xu-guang, FEI Zhen-wei, AN Chun-guo, CHI Yong, YAN Jian-hua, YU Kai, FU Juan-juan, PAN Jin-hua, SHI Zheng. Study on the combustion characteristics of the sludge from leather industry and lake[J]. Journal of Fuel Chemistry and Technology, 2009, 6(37): 757-762.)[9] 李春雨, 蒋旭光, 费振伟, 安春国, 池涌, 严建华,俞恺, 傅娟娟, 潘金华, 施政. 制革、造纸和湖泊污泥燃烧特性的研究[J]. 燃料化学学报, 2009, 6(37): 757-762. (LI Chun-yu, JIANG Xu-guang, FEI Zhen-wei, AN Chun-guo, CHI Yong, YAN Jian-hua, YU Kai, FU Juan-juan, PAN Jin-hua, SHI Zheng. Study on the combustion characteristics of the sludge from leather industry and lake[J]. Journal of Fuel Chemistry and Technology, 2009, 6(37): 757-762.)

    10. [10] ARIAS B, PEVIDA C, RUBIERA F, PIS J J. Effect of biomass blending on coal ignition and burnout during oxy-fuel combustion[J]. Fuel, 2008, 87(12): 2753-2759.[10] ARIAS B, PEVIDA C, RUBIERA F, PIS J J. Effect of biomass blending on coal ignition and burnout during oxy-fuel combustion[J]. Fuel, 2008, 87(12): 2753-2759.

    11. [11] 陈祎, 段佳, 林鹏, 罗永浩. 氧量对典型生物质燃烧特性的影响[J]. 中国电机工程学报, 2008, 28(2): 43-48. (CHEN Yi, DUAN Jia, LIN Peng, LUO Yong-hao. Effect of oxygen concentration on combustion characteristics of typical biomass materials [J].Proceedings of the CSEE, 2008, 28(2): 43-48.)[11] 陈祎, 段佳, 林鹏, 罗永浩. 氧量对典型生物质燃烧特性的影响[J]. 中国电机工程学报, 2008, 28(2): 43-48. (CHEN Yi, DUAN Jia, LIN Peng, LUO Yong-hao. Effect of oxygen concentration on combustion characteristics of typical biomass materials [J].Proceedings of the CSEE, 2008, 28(2): 43-48.)

    12. [12] 樊越胜, 邹峥, 高巨宝, 曹子栋. 煤粉在富氧条件下燃烧特性的实验研究[J]. 中国电机工程学报, 2005, 25(24): 118-121. (FAN Yue-sheng, ZOU Zheng, GAO Ju-bao, CAO Zi-dong. Study of oxygen content on combustion characteristics of pulverized coal[J]. Proceedings of the CSEE, 2005, 25(24): 118-121.)[12] 樊越胜, 邹峥, 高巨宝, 曹子栋. 煤粉在富氧条件下燃烧特性的实验研究[J]. 中国电机工程学报, 2005, 25(24): 118-121. (FAN Yue-sheng, ZOU Zheng, GAO Ju-bao, CAO Zi-dong. Study of oxygen content on combustion characteristics of pulverized coal[J]. Proceedings of the CSEE, 2005, 25(24): 118-121.)

    13. [13] ZHANG N, NING X A, ZHOU J B, WEI P T, LUO H J. Investigation on the co-combustion characteristics of pulverized coal and paper mill sludge[J]. Appl Mech Mater, 2011, 55-57: 1132-1137[13] ZHANG N, NING X A, ZHOU J B, WEI P T, LUO H J. Investigation on the co-combustion characteristics of pulverized coal and paper mill sludge[J]. Appl Mech Mater, 2011, 55-57: 1132-1137

    14. [14] OTERO M, DZE C, CALVO L F, GARCA A I, MORN A. Analysis of the co-combustion of sewage sludge and coal by TG-MS[J].Biomass and Bioenergy, 2002, 22(4): 319-329.[14] OTERO M, DZE C, CALVO L F, GARCA A I, MORN A. Analysis of the co-combustion of sewage sludge and coal by TG-MS[J].Biomass and Bioenergy, 2002, 22(4): 319-329.

    15. [15] OTERO M, GMEZ X, GARCA A, MORN A. Effects of sewage sludge blending on the coal combustion: A thermogravimetric assessment[J]. Chemosphere, 2007, 69(11): 1740-1750.[15] OTERO M, GMEZ X, GARCA A, MORN A. Effects of sewage sludge blending on the coal combustion: A thermogravimetric assessment[J]. Chemosphere, 2007, 69(11): 1740-1750.

    16. [16] OTERO M, SNCHEZ M E, GARCA A, MORN A. Simultaneous thermogravimetric-mass spectrometric study on the co-combustion of coal and sewage sludges[J]. Journal of Thermal Analysis and Calorimetry, 2006, 86(2): 489-495.[16] OTERO M, SNCHEZ M E, GARCA A, MORN A. Simultaneous thermogravimetric-mass spectrometric study on the co-combustion of coal and sewage sludges[J]. Journal of Thermal Analysis and Calorimetry, 2006, 86(2): 489-495.

    17. [17] 邹学权, 王新红, 吴建军, 陈越. 用热重-差热-红外光谱技术研究煤粉的燃烧特性[J]. 煤炭转化, 2003, 26(1): 71-73. (ZOU Xue-quan, WANG Xin-hong, WU Jian-jun, CHEN Yue. Study on combustion characteristic of coal by means of technology of TG-DSC-FTIR[J]. Coal Conversion, 2003, 26(1): 71-73.)[17] 邹学权, 王新红, 吴建军, 陈越. 用热重-差热-红外光谱技术研究煤粉的燃烧特性[J]. 煤炭转化, 2003, 26(1): 71-73. (ZOU Xue-quan, WANG Xin-hong, WU Jian-jun, CHEN Yue. Study on combustion characteristic of coal by means of technology of TG-DSC-FTIR[J]. Coal Conversion, 2003, 26(1): 71-73.)

    18. [18] 姜秀民, 李巨斌, 邱健荣. 超细化煤粉燃烧特性的研究[J]. 中国电机工程学报. 2000, 20(6): 71-74. (JIANG Xiu-min, LI Ju-bin, QIU Jian-rong. Study on combustion characteristic of micro-pulverized coal[J]. Proceeding of the CSEE, 2000, 20(6): 71-74.)[18] 姜秀民, 李巨斌, 邱健荣. 超细化煤粉燃烧特性的研究[J]. 中国电机工程学报. 2000, 20(6): 71-74. (JIANG Xiu-min, LI Ju-bin, QIU Jian-rong. Study on combustion characteristic of micro-pulverized coal[J]. Proceeding of the CSEE, 2000, 20(6): 71-74.)

    19. [19] 胡荣祖, 史启祯. 热分析动力学[M]. 北京: 科学出版社, 2001, 99-100. (HU Rong-zhu, SHI Qi-zhen. Kinetics of thermal analysis[M]. Beijing: Science Press, 2001, 99-100.)[19] 胡荣祖, 史启祯. 热分析动力学[M]. 北京: 科学出版社, 2001, 99-100. (HU Rong-zhu, SHI Qi-zhen. Kinetics of thermal analysis[M]. Beijing: Science Press, 2001, 99-100.)

    20. [20] FANG M X, SHEN D K, LI Y X, YU C J, LUO Z Y, CEN K F. Kinetic study on pyrolysis and combustion of wood under different oxygen concentrations by using TG-FTIR analysis[J]. J Anal Appl Pyrolysis, 2006, 77(1): 22-27.[20] FANG M X, SHEN D K, LI Y X, YU C J, LUO Z Y, CEN K F. Kinetic study on pyrolysis and combustion of wood under different oxygen concentrations by using TG-FTIR analysis[J]. J Anal Appl Pyrolysis, 2006, 77(1): 22-27.

    21. [21] YU Z S, MA X Q, LIU A. Thermogravimetric analysis of rice and wheat straw catalytic combustion in air-and oxygen-enriched atmospheres[J]. Energy Convers Manage, 2009, 50(3): 561-566.[21] YU Z S, MA X Q, LIU A. Thermogravimetric analysis of rice and wheat straw catalytic combustion in air-and oxygen-enriched atmospheres[J]. Energy Convers Manage, 2009, 50(3): 561-566.

    22. [22] 闵凡飞, 张明旭. 生物质与不同变质程度煤混合燃烧特性的研究[J]. 中国矿业大学学报, 2005, 34(2): 236-241. (MIN Fan-fei, ZHANG Ming-xu. Research on combustion characteristics of biomass and coals with different ranks[J]. Journal of China University of Mining and Technology, 2005, 34(2): 236-241.)[22] 闵凡飞, 张明旭. 生物质与不同变质程度煤混合燃烧特性的研究[J]. 中国矿业大学学报, 2005, 34(2): 236-241. (MIN Fan-fei, ZHANG Ming-xu. Research on combustion characteristics of biomass and coals with different ranks[J]. Journal of China University of Mining and Technology, 2005, 34(2): 236-241.)

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  • 收稿日期:  2012-11-15
  • 网络出版日期:  2013-01-05
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