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Sub-100 nm hollow SnO2@C nanoparticles as anode material for lithium ion batteries and significantly enhanced cycle performances

Shuang-Lei Yang ,  Bang-Hong Zhou ,  Mei Lei ,  Lan-Ping Huang ,  Jun Pan ,  Wei Wu ,  Hong-Bo Zhang

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Citation:  Shuang-Lei Yang, Bang-Hong Zhou, Mei Lei, Lan-Ping Huang, Jun Pan, Wei Wu, Hong-Bo Zhang. Sub-100 nm hollow SnO2@C nanoparticles as anode material for lithium ion batteries and significantly enhanced cycle performances[J]. Chinese Chemical Letters, 2015, 26(10): 1293-1297. doi: 10.1016/j.cclet.2015.05.051 shu

Sub-100 nm hollow SnO2@C nanoparticles as anode material for lithium ion batteries and significantly enhanced cycle performances

    • 通讯作者: Wei Wu,
    Hong-Bo Zhang,
  • 基金项目:

    We greatly acknowledge partial financial support by the Program for the NSFC (Nos. 51302325, 51201115, 51471121) (Nos. 51302325, 51201115, 51471121)

    New Century Excellent Talents in University (No. NCET-12-0553) (No. NCET-12-0553)

    Program for Shenghua Overseas Talent (No. 1681-7607030005) from Central South University, Hubei Provincial Natural Science Foundation (No. 2014CFB261) (No. 1681-7607030005)

    Precision Instruments of Central South University (No. CSUZC2014032) (No. CSUZC2014032)

    Fundamental Research Funds for the Central Universities (No. 2042015kf0184)  (No. 2042015kf0184)

摘要: Rational designing and controlling of nanostructures is a key factor in realizing appropriate properties required for the high-performance energy fields. In the present study, hollow SnO2@C nanoparticles (NPs) with a mean size of 50 nm have been synthesized in large-scale via a facile hydrothermal approach. The morphology and composition of as-obtained products were studied by various characterized techniques. As an anode material for lithium ion batteries (LIBs), the as-prepared hollow SnO2@C NPs exhibit significant improvement in cycle performances. The discharge capacity of lithium battery is as high as 370 mAh g-1, and the current density is 3910 mA g-1(5 C) after 573 cycles. Furthermore, the capacity recovers up to 1100 mAh g-1 at the rate performances in which the current density is recovered to 156.4 mA g-1(0.2 C). Undoubtedly, sub-100 nm SnO2@C NPs provide significant improvement to the electrochemical performance of LIBs as superior-anode nanomaterials, and this carbon coating strategy can pave the way for developing high-performance LIBs.

English

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  • 发布日期:  2015-06-04
  • 收稿日期:  2015-03-25
  • 网络出版日期:  2015-05-19
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