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A colorimetric chemosensor based on new water-soluble PODIPY dye for Hg2+ detection

Xin-Dong Jiang ,  Hai-Feng Yu ,  Jiu-Li Zhao ,  Chang-Liang Sun ,  Ying Xie ,  Lin-Jiu Xiao

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Citation:  Xin-Dong Jiang, Hai-Feng Yu, Jiu-Li Zhao, Chang-Liang Sun, Ying Xie, Lin-Jiu Xiao. A colorimetric chemosensor based on new water-soluble PODIPY dye for Hg2+ detection[J]. Chinese Chemical Letters, 2015, 26(10): 1241-1245. doi: 10.1016/j.cclet.2015.07.002 shu

A colorimetric chemosensor based on new water-soluble PODIPY dye for Hg2+ detection

    • 通讯作者: Xin-Dong Jiang,
    Chang-Liang Sun,
  • 基金项目:

    This work was supported by the Public Research Foundation of Liaoning Province for the Cause of Science (No. 2014003009) (No. 2014003009)

    Technology Key Project of Liaoning Province (No. 2013304007) (No. 2013304007)

    Technology Research Projects (No. 13A150046) (No. 13A150046)

摘要: The phosphorus-containing PODIPY 1 as a chemosensor can detect Hg2+ by a color change from pink to violet red without the use of any instrumentation. PODIPY 1 was selective to Hg2+ with a remarkable absorption change, and addition of other relevant metal ions caused almost no absorption change. The new PODIPY dye 1 was sensitive to various concentrations of Hg2+. The energy gap between the HOMO and LUMO of the metal complex 1-Hg2+ is smaller than that of chemosensor 1, which is in good agreement with the red shift in the absorption observed upon treatment of 1 with Hg2+. The 1-based test strips were easily fabricated and low-cost, useful in practical and efficient Hg2+ test kits.

English

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  • 发布日期:  2015-07-06
  • 收稿日期:  2015-05-06
  • 网络出版日期:  2015-06-16
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