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A facile preparation and electrochemical properties of nickel based compound-graphene sheet composites for supercapacitors

Li-Bin Zhang ,  Sheng-Rong Yang ,  Jin-Qing Wang ,  Ye Xu ,  Xiang-Zheng Kong

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Citation:  Li-Bin Zhang, Sheng-Rong Yang, Jin-Qing Wang, Ye Xu, Xiang-Zheng Kong. A facile preparation and electrochemical properties of nickel based compound-graphene sheet composites for supercapacitors[J]. Chinese Chemical Letters, 2015, 26(5): 522-528. doi: 10.1016/j.cclet.2015.01.025 shu

A facile preparation and electrochemical properties of nickel based compound-graphene sheet composites for supercapacitors

    • 通讯作者: Sheng-Rong Yang,
    Xiang-Zheng Kong,
  • 基金项目:

    This study has been financially supported by National Natural Science Foundation of China (No. 51075384). (No. 51075384)

摘要: Composites of a nickel based compound incorporated with graphene sheets (NiBC-GS) are prepared by a simple flocculation, using hydrazine hydrate as flocculant and reductant, from a homogeneous intermixture of nickel dichloride and graphene oxide dispersed in N,N-dimethylformamide. Morphology, microstructure and thermal stability of the obtained products were characterized by field-emission scanning electron microscopy, X-ray diffraction and thermal gravimetric analysis. Furthermore, the electrochemical properties of NiBC-GS, as electrodematerials for supercapacitors, were studied by cyclic voltammetry and galvanostatic charge/discharge in 2 mol L-1 KOH solution. It was determined that for NiBC-GS annealed at 250 8C, a high specific capacitance of 2394 F g-1 was achieved at a current density of 1 A g-1, with 78% of the value (i.e., 1864 F g-1) retained after 5000 times of repeated galvanostatic charge/discharge cycling. The high specific capacitance and available charge/discharge stability indicate the synthesized NiBC-GS250 composite is a good candidate as a novel electrode material for supercapacitors.

English

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  • 发布日期:  2015-01-31
  • 收稿日期:  2014-11-24
  • 网络出版日期:  2015-01-19
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