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由2,6-吡啶二羧酸根构筑的两种铈(Ⅳ)配合物的合成、结构及热性质

曾晓哲 ,  张爱芸 ,  贺冲 ,  李彦伟

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引用本文: 曾晓哲, 张爱芸, 贺冲, 李彦伟. 由2,6-吡啶二羧酸根构筑的两种铈(Ⅳ)配合物的合成、结构及热性质[J]. 无机化学学报, 2013, 29(7): 1557-1562. doi: 10.3969/j.issn.1001-4861.2013.00.211 shu
Citation:  ZENG Xiao-Zhe, ZHANG Ai-Yun, HE Chong, LI Yan-Wei. Synthesis, Structure and Thermal Properties of Two Cerium(Ⅳ) Complexes with 2,6-Pyridinedicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1557-1562. doi: 10.3969/j.issn.1001-4861.2013.00.211 shu

由2,6-吡啶二羧酸根构筑的两种铈(Ⅳ)配合物的合成、结构及热性质

  • 基金项目:

    河南省高等院校自然科学研究项目(No.2009A150011)资助项目。 (No.2009A150011)

摘要: 采用水热法合成了2种铈(Ⅳ)配合物[Ce(dipic)3]·(H2bipy)·4H2O (1)和[Ce(dipic)3]·(H2bpa)·3.5H2O (2)(2,6-H2dipic=2,6-吡啶二羧酸,bipy=4,4'-联吡啶,bpa=二(4-吡啶基)胺),并通过X射线单晶衍射、元素分析、FTIR及热重分析对其结构和组成进行了表征。单晶衍射结构表明:配合物1和2的晶体都属于三斜晶系,P1空间群。配合物的中心金属铈(Ⅳ)离子被3个完全去质子化的2,6-吡啶二羧酸根环绕,配体2,6-吡啶二羧酸的羧基均以单齿形式配位。热分析表明2个配合物在64和50 ℃开始发生分解。

English

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    1. [1] Piguet C, Bünzil J C, Bernardinelli G. J. Am. Chem. Soc, 1996,118:6681-6697[1] Piguet C, Bünzil J C, Bernardinelli G. J. Am. Chem. Soc, 1996,118:6681-6697

    2. [2] Li B, Gu W, Zhang L Z, et al. Inorg. Chem., 2006,45:10425-10427[2] Li B, Gu W, Zhang L Z, et al. Inorg. Chem., 2006,45:10425-10427

    3. [3] Darren B, Timothy J P, Edmund J C. J. Am. Chem. Soc., 2004,126:6106-6114[3] Darren B, Timothy J P, Edmund J C. J. Am. Chem. Soc., 2004,126:6106-6114

    4. [4] CHEN Zhi-Min(陈志敏), LI Dong-Ping(李东平), LI Hui-Quan(李慧泉). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24:1907-1911[4] CHEN Zhi-Min(陈志敏), LI Dong-Ping(李东平), LI Hui-Quan(李慧泉). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24:1907-1911

    5. [5] Wang N, Yue S T, Liu Y L, et al. Cryst. Growth Des., 2009, 9:368-371[5] Wang N, Yue S T, Liu Y L, et al. Cryst. Growth Des., 2009, 9:368-371

    6. [6] Shi F N, Silva L C, Trindade T, et al. Cryst. Growth Des., 2009,9:2098-2109[6] Shi F N, Silva L C, Trindade T, et al. Cryst. Growth Des., 2009,9:2098-2109

    7. [7] Yang P, Wu J Z, Yu Y. Inorg. Chim. Acta, 2009,362:1907-1912[7] Yang P, Wu J Z, Yu Y. Inorg. Chim. Acta, 2009,362:1907-1912

    8. [8] Li X H, Shi Q, Hu M L, et al. Inorg. Chem. Commun., 2004, 7:912-914[8] Li X H, Shi Q, Hu M L, et al. Inorg. Chem. Commun., 2004, 7:912-914

    9. [9] Song H H, Li Y J. Inorg. Chim. Acta, 2008,361:1421-1425[9] Song H H, Li Y J. Inorg. Chim. Acta, 2008,361:1421-1425

    10. [10] Luo J H, Hong M C, Wang R H, et al. Inorg. Chem., 2003, 42:4486-4488[10] Luo J H, Hong M C, Wang R H, et al. Inorg. Chem., 2003, 42:4486-4488

    11. [11] Wang Z, Bai F Y, Xing Y H, et al. Inorg. Chim. Acta, 2010, 363:669-675[11] Wang Z, Bai F Y, Xing Y H, et al. Inorg. Chim. Acta, 2010, 363:669-675

    12. [12] Liu M S, Yu Q Y, Cai Y P, et al. Cryst. Growth Des., 2008, 8:4083-4091[12] Liu M S, Yu Q Y, Cai Y P, et al. Cryst. Growth Des., 2008, 8:4083-4091

    13. [13] Prasad T K, Sailaja S, Rajasekharan M V. Polyhedron, 2005,24:1487-1496[13] Prasad T K, Sailaja S, Rajasekharan M V. Polyhedron, 2005,24:1487-1496

    14. [14] Chantal B C, Jeannette D G, Auguste F, et al. Inorg. Chim. Acta, 2008,361:2909-2917[14] Chantal B C, Jeannette D G, Auguste F, et al. Inorg. Chim. Acta, 2008,361:2909-2917

    15. [15] HUANG Yan-Ju(黄艳菊), CUI Yun-Cheng(崔运成), DU Gang(杜刚). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009,25:1882-1884[15] HUANG Yan-Ju(黄艳菊), CUI Yun-Cheng(崔运成), DU Gang(杜刚). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009,25:1882-1884

    16. [16] HUANG Yan-Ju(黄艳菊), NI Liang(倪良), WANG Lei(王 蕾), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27:157-161[16] HUANG Yan-Ju(黄艳菊), NI Liang(倪良), WANG Lei(王 蕾), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27:157-161

    17. [17] CHEN Zi-Yun(陈梓云), PENG Meng-Xia(彭梦侠). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23:2093-2096[17] CHEN Zi-Yun(陈梓云), PENG Meng-Xia(彭梦侠). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23:2093-2096

    18. [18] Bo Q B, Sun G X, Geng D L. Inorg. Chem., 2010,49:561-571[18] Bo Q B, Sun G X, Geng D L. Inorg. Chem., 2010,49:561-571

    19. [19] Stephen M S, Ronald M S, Robert L L. Inorg. Chim. Acta, 2008,361:317-326[19] Stephen M S, Ronald M S, Robert L L. Inorg. Chim. Acta, 2008,361:317-326

    20. [20] Sheldrick G M. SHELX-97, Program for the Solution and the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.[20] Sheldrick G M. SHELX-97, Program for the Solution and the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.

    21. [21] Swarnabala G, Rajasekharan M V. Inorg. Chem., 1998,37: 1483-1485[21] Swarnabala G, Rajasekharan M V. Inorg. Chem., 1998,37: 1483-1485

    22. [22] Sailaja S, Rajasekharan M V. Acta Cryst. E, 2001,57:341-343[22] Sailaja S, Rajasekharan M V. Acta Cryst. E, 2001,57:341-343

    23. [23] Paula C R, Silva L C, Filipe A P, et al. Inorg. Chem., 2010,49:3428-3440[23] Paula C R, Silva L C, Filipe A P, et al. Inorg. Chem., 2010,49:3428-3440

    24. [24] Prasad T K, Rajasekharan M V. Cryst. Growth Des., 2006,6: 488-491[24] Prasad T K, Rajasekharan M V. Cryst. Growth Des., 2006,6: 488-491

    25. [25] LIN Yong(林勇), CHEN Zi-Yun(陈梓云), YU Xiao-Lan(余 晓岚), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2006,22:1468-1472[25] LIN Yong(林勇), CHEN Zi-Yun(陈梓云), YU Xiao-Lan(余 晓岚), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2006,22:1468-1472

    26. [26] LI Xia(李夏), LI Wen-Jun(李文君). Chinese J. Spectroscopy and Spectral Analysis(Guangpuxue Yu Guangpu Fenxi), 1999,19:450-452[26] LI Xia(李夏), LI Wen-Jun(李文君). Chinese J. Spectroscopy and Spectral Analysis(Guangpuxue Yu Guangpu Fenxi), 1999,19:450-452

    27. [27] FANG Guang-Rong(方光荣), ZHU Yuan-Yuan(祝媛媛), DU Chun-Fang(杜春芳), et al. Chinese J. Molecular Science (Fenzi Kexue Xuebao), 2006,22:368-371[27] FANG Guang-Rong(方光荣), ZHU Yuan-Yuan(祝媛媛), DU Chun-Fang(杜春芳), et al. Chinese J. Molecular Science (Fenzi Kexue Xuebao), 2006,22:368-371

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  • 收稿日期:  2012-03-29
  • 网络出版日期:  2013-03-07
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