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由肉桂酸和甲基联吡啶喹喔啉配体构筑的双核铅(Ⅱ)的配合物的水热合成、表征及自然键轨道(NBO)分析

方燕 ,  王蕾 ,  倪良 ,  姚加

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引用本文: 方燕, 王蕾, 倪良, 姚加. 由肉桂酸和甲基联吡啶喹喔啉配体构筑的双核铅(Ⅱ)的配合物的水热合成、表征及自然键轨道(NBO)分析[J]. 无机化学学报, 2013, 29(7): 1551-1556. doi: 10.3969/j.issn.1001-4861.2013.00.216 shu
Citation:  FANG Yan, WANG Lei, NI Liang, YAO Jia. Hydrothermal Synthesis, Characterization and Natural Bond Orbital(NBO) Analysis of a Binuclear Lead(Ⅱ) Complex with Cinnamic Acid and Medpq Ligands[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1551-1556. doi: 10.3969/j.issn.1001-4861.2013.00.216 shu

由肉桂酸和甲基联吡啶喹喔啉配体构筑的双核铅(Ⅱ)的配合物的水热合成、表征及自然键轨道(NBO)分析

  • 基金项目:

    江苏省研究生创新计划(No.CXLX11-0851)资助项目。 (No.CXLX11-0851)

摘要: 采用水热法合成了一种新型双核铅(Ⅱ)配合物[Pb2(CA)4(Medpq)2](HCA=cinnamic acid,Medpq=2-methyldipyrido[3,2-f:2,3'-h]quinoxaline),并对其进行了元素分析、红外光谱、紫外可见光光谱、热重表征、荧光光谱、X射线单晶衍射测定和理论计算。标题配合物属于三斜晶系,空间群为P1。在晶体中,铅与来自Medpq配体的2个氮原子和3个肉桂酸配体的5个氧原子形成七配位。应用Gaussian 03程序,对标题配合物进行了自然键轨道(NBO)分析,结果表明Pb(Ⅱ)与配位原子间的价键类型都属于共价键范畴。

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  • 收稿日期:  2012-09-20
  • 网络出版日期:  2013-02-26
通讯作者: 陈斌, bchen63@163.com
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