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基于四(3-吡啶氧亚甲基)甲烷及氰化铜螺旋链手性金属有机骨架化合物的合成及其性质研究

江靖 ,  任世斌 ,  林勇强 ,  吴涛 ,  张小鹏 ,  韩得满 ,  梁华定 ,  李芳 ,  贾文平

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引用本文: 江靖, 任世斌, 林勇强, 吴涛, 张小鹏, 韩得满, 梁华定, 李芳, 贾文平. 基于四(3-吡啶氧亚甲基)甲烷及氰化铜螺旋链手性金属有机骨架化合物的合成及其性质研究[J]. 无机化学学报, 2013, 29(7): 1539-1544. doi: 10.3969/j.issn.1001-4861.2013.00.257 shu
Citation:  JIANG Jing, REN Shi-Bin, LIN Yong-Qiang, WU Tao, ZHANG Xiao-Peng, HAN De-Man, LIANG Hua-Ding, LI Fang, JIA Wen-Ping. Synthesis of Chiral Metal-Organic Framework and Study of Its Properties Based on Tetrakis(3-pyridyloxymethylene)methane and Helical CuCN Chains[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1539-1544. doi: 10.3969/j.issn.1001-4861.2013.00.257 shu

基于四(3-吡啶氧亚甲基)甲烷及氰化铜螺旋链手性金属有机骨架化合物的合成及其性质研究

  • 基金项目:

    浙江省自然科学基金(No.LY12B01006) (No.LY12B01006)

    浙江省科技计划项目(No.2012C37028,2011C37055) (No.2012C37028,2011C37055)

    台州市科技局项目(No.102XCP08) (No.102XCP08)

    化工资源 有效利用国家重点实验室开放课题（No.CRE-2012-C-303）资助项目。 

摘要: 通过一个非手性配体和1D氰化铜链螺旋成功构建了一种新型的手性金属有机骨架:[Cu4(CN)4(L)2]n (1,L=四(3-吡啶氧亚甲基甲烷));铜(Ⅰ)和原位生成的氰基组装而生成的螺旋是左旋并且它使得金属有机框架具有手性。这是首例通过半刚性四面体配体多变的构像诱导合成独特的手性金属有机骨架化合物。此外还研究了该化合物的手性、热稳定性以及介电性质。

English

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    1. [1] (a)Mason S F. Molecular Optical Activity and the Chiral Discriminations. Cambridge: Cambridge University Press, 1982. (b)Bonner W A. Origins Life Evol. Biosphere, 1994:63[1] (a)Mason S F. Molecular Optical Activity and the Chiral Discriminations. Cambridge: Cambridge University Press, 1982. (b)Bonner W A. Origins Life Evol. Biosphere, 1994:63

    2. [2] Loewenstein W R. Touchstone of Life Molecular Information: Cell, Communication, and the Foundations of Life. Oxford: Oxford University Press, 1999.[2] Loewenstein W R. Touchstone of Life Molecular Information: Cell, Communication, and the Foundations of Life. Oxford: Oxford University Press, 1999.

    3. [3] (a)Gruselle M, Train C, Boubekeur K, et al. Coord. Chem. Rev., 2006,250:2491-2500 (b)Chelucci G, Thummel R P. Chem. Rev., 2002,102:3129-3170[3] (a)Gruselle M, Train C, Boubekeur K, et al. Coord. Chem. Rev., 2006,250:2491-2500 (b)Chelucci G, Thummel R P. Chem. Rev., 2002,102:3129-3170

    4. [4] (a)Zhang J, Chen S M, Wu T, et al. J. Am. Chem. Soc., 2008, 130:12882-12883 (b)Bu X H, Tong M L, Chang H C, et al. Angew. Chem., Int. Ed., 2004,43:192-195[4] (a)Zhang J, Chen S M, Wu T, et al. J. Am. Chem. Soc., 2008, 130:12882-12883 (b)Bu X H, Tong M L, Chang H C, et al. Angew. Chem., Int. Ed., 2004,43:192-195

    5. [5] (a)Wen H R, Wang C F, Song Y, et al. Inorg. Chem., 2005, 44:9039-9045 (b)Meng X R, Song Y L, Hou H W, et al. Inorg. Chem., 2003,42:1306-1315[5] (a)Wen H R, Wang C F, Song Y, et al. Inorg. Chem., 2005, 44:9039-9045 (b)Meng X R, Song Y L, Hou H W, et al. Inorg. Chem., 2003,42:1306-1315

    6. [6] (a)An H Y, Wang E B, Xiao D R, et al. Angew. Chem. Int. Ed., 2006,45:904-908 (b)Zhu Q, Sheng T, Fu R, et al. Chem. Commun., 2010,46: 9001-9003 (c)Liang X Q, Jia J T, Wu T, et al. CrystEngComm, 2010,12: 3499-3501 (d)Lin Z, Slawin A M Z, Morris R E. J. Am. Chem. Soc., 2007,129:4880-4881[6] (a)An H Y, Wang E B, Xiao D R, et al. Angew. Chem. Int. Ed., 2006,45:904-908 (b)Zhu Q, Sheng T, Fu R, et al. Chem. Commun., 2010,46: 9001-9003 (c)Liang X Q, Jia J T, Wu T, et al. CrystEngComm, 2010,12: 3499-3501 (d)Lin Z, Slawin A M Z, Morris R E. J. Am. Chem. Soc., 2007,129:4880-4881

    7. [7] Banerjee M, Das S, Yoon M, et al. J. Am. Chem. Soc., 2009, 131:7524-7525[7] Banerjee M, Das S, Yoon M, et al. J. Am. Chem. Soc., 2009, 131:7524-7525

    8. [8] (a)Ren S B, Zhou L, Zhang J, et al. CrystEngComm, 2009, 11:1834-1836 (b)Ren S B, Zhou L, Zhang J, et al. Inorg. Chem. Commun., 2011,14:558-561[8] (a)Ren S B, Zhou L, Zhang J, et al. CrystEngComm, 2009, 11:1834-1836 (b)Ren S B, Zhou L, Zhang J, et al. Inorg. Chem. Commun., 2011,14:558-561

    9. [9] Zhang Q, Bu X, Lin Z, et al. Inorg. Chem., 2008,47:9724-9726[9] Zhang Q, Bu X, Lin Z, et al. Inorg. Chem., 2008,47:9724-9726

    10. [10] (a)Sheldrick G M. SHELXS-97, Programs for X-ray Crystal Structure Solution, University of Göttingen, Göttingen, Germany, 1997. (b)Sheldrick G M. SHELXL-97, Programs for X-ray Crystal Structure Refinement, University of Göttingen, Göttingen, Germany, 1997.[10] (a)Sheldrick G M. SHELXS-97, Programs for X-ray Crystal Structure Solution, University of Göttingen, Göttingen, Germany, 1997. (b)Sheldrick G M. SHELXL-97, Programs for X-ray Crystal Structure Refinement, University of Göttingen, Göttingen, Germany, 1997.

    11. [11] Spek A L. PLATON, A Multipurpose Crystallographic Tool, Utrecht University, Utrecht, 1999.[11] Spek A L. PLATON, A Multipurpose Crystallographic Tool, Utrecht University, Utrecht, 1999.

    12. [12] Kumar G R, Raj S G, Mohan R, et al. Cryst. Growth Des., 2006,6:1308-1310[12] Kumar G R, Raj S G, Mohan R, et al. Cryst. Growth Des., 2006,6:1308-1310

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  • 收稿日期:  2013-03-06
  • 网络出版日期:  2013-04-20
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