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以2,4’-联苯二羧酸及咪唑并[4,5-f][1,10]邻菲咯啉为配体的钴(Ⅱ)、锰(Ⅱ)配合物的水热合成及晶体结构

刘春波 ,  赵晗 ,  王珊珊 ,  查小林 ,  李秀颖 ,  车广波

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引用本文: 刘春波, 赵晗, 王珊珊, 查小林, 李秀颖, 车广波. 以2,4’-联苯二羧酸及咪唑并[4,5-f][1,10]邻菲咯啉为配体的钴(Ⅱ)、锰(Ⅱ)配合物的水热合成及晶体结构[J]. 无机化学学报, 2013, 29(7): 1533-1538. doi: 10.3969/j.issn.1001-4861.2013.00.207 shu
Citation:  LIU Chun-Bo, ZHAO Han, WANG Shan-Shan, ZHA Xiao-Lin, LI Xiu-Ying, CHE Guang-Bo. Syntheses and Crystal Structures of Co(Ⅱ) and Mn(Ⅱ) Complexes with 2,4’-Biphenyldicarboxylic Acid and Imidazo[4,5-f][1,10]phenanthroline Ligands[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1533-1538. doi: 10.3969/j.issn.1001-4861.2013.00.207 shu

以2,4’-联苯二羧酸及咪唑并[4,5-f][1,10]邻菲咯啉为配体的钴(Ⅱ)、锰(Ⅱ)配合物的水热合成及晶体结构

  • 基金项目:

    国家自然科学基金(No.60978059) (No.60978059)

    教育部新世纪优秀人才(No.NCET-10-0176)资助项目。 (No.NCET-10-0176)

摘要: 在水热条件下,以2,4'-联苯二羧酸(2,4'-H2bpdc)和咪唑并[4,5-f][1,10]邻菲咯啉(L)为配体构筑了两种配合物{[Co(2,4'-bpdc)(L)(H2O)]·H2O}n (1)和[Mn(2,4'-bpdc)(L)(H2O)]n (2),并利用元素分析、X-射线单晶衍射和热重分析对其结构进行了表征。配合物1具有一维链状结构,配合物2展示了一维双链结构,两个配合物都通过分子间氢键和π-π相互作用形成三维网状结构。

English

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  • 收稿日期:  2012-06-26
  • 网络出版日期:  2013-02-02
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