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An oxygen reduction sensor based on a novel type of porous carbon composite membrane electrode

En-Dong Xing ,  Long-Qi Liang ,  Yu-Jie Dong ,  Wei-Min Huang

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Citation:  En-Dong Xing, Long-Qi Liang, Yu-Jie Dong, Wei-Min Huang. An oxygen reduction sensor based on a novel type of porous carbon composite membrane electrode[J]. Chinese Chemical Letters, 2015, 26(10): 1322-1326. doi: 10.1016/j.cclet.2015.05.043 shu

An oxygen reduction sensor based on a novel type of porous carbon composite membrane electrode

    • 通讯作者: Wei-Min Huang,
  • 基金项目:

    We acknowledge financial supports from the National Natural Science Foundation of China (No. 21273097) (No. 21273097)

    the project from the State Key Laboratory of Electroanalytical Chemistry (No. 2013)  (No. 2013)

    the Science Foundation of Jilin Province (No. 20130204003GX). (No. 20130204003GX)

摘要: The development of a simple, efficient and sensitive sensor for dissolved oxygen is proposed using a novel type of porous carbon composite membrane/glassy carbon electrode based on the low-cost common filter paper by a simple method. The resulting device exhibited excellent electrocatalytic activities toward the oxygen reduction reaction. Scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy and electrochemical measurements demonstrated that the porous morphology and uniformly dispersed Fe3C nanoparticles of the PCCM play an important role in the oxygen reduction reaction. A linear response range from 2μmol/L up to 110 μmol/L and a detection limit of 1.4 μmol/L was obtained with this sensor. The repeatability of the proposed sensor, evaluated in terms of relative standard deviation, was 3.0%. The successful fabrication of PCCM/GC electrode may promote the development of new porous carbon oxygen reduction reaction material for the oxygen reduction sensor.

English

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  • 发布日期:  2015-06-03
  • 收稿日期:  2015-02-13
  • 网络出版日期:  2015-05-07
通讯作者: 陈斌, bchen63@163.com
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