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Novel manganese(II)-based deep eutectic solvents: Synthesis and physical properties analysis

Koon-Kee Kow ,  Kamaliah Sirat

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Citation:  Koon-Kee Kow, Kamaliah Sirat. Novel manganese(II)-based deep eutectic solvents: Synthesis and physical properties analysis[J]. Chinese Chemical Letters, 2015, 26(10): 1311-1314. doi: 10.1016/j.cclet.2015.05.049 shu

Novel manganese(II)-based deep eutectic solvents: Synthesis and physical properties analysis

    • 通讯作者: Koon-Kee Kow,
摘要: Type IV deep eutectic solvent (DES) involves the formation of metal-based eutectics from metal salts or metal salt hydrate incombination with various hydrogen-bonddonors(HBDs) suchas urea, ethylene glycol or acetamide. In current study, twodistinguished approaches were used to synthesize potential DESs, given as the direct heating and the evaporatingmethods. Successful synthesized DESswere subjected forphysical properties characterization by Fourier TransformInfrared (FTIR) Spectroscopy, thermal stability, viscosity, and conductivity analyses. Five novelmanganese (II)-basedDESswere successfully synthesized as reported in this study. Data obtained indicated that the MnCl2·4H2O·acetamide DES exhibits the lowest freezing point (27.5℃), highest thermal stability (193℃ point of dehydration), lowest viscosity (η=112.8 cP) and the highest conductivity (0.12723 mS/cm). The findings obtained reveal the characteristics, nature or features of synthesized DESs as potential industrial solvents.

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  • 发布日期:  2015-06-04
  • 收稿日期:  2015-02-26
  • 网络出版日期:  2015-05-19
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