二个含水杨酰腙配体的钒配合物的合成与晶体结构研究

陈小华 吴琼洁 吕玮 杨明星 陈丽娟

引用本文: 陈小华, 吴琼洁, 吕玮, 杨明星, 陈丽娟. 二个含水杨酰腙配体的钒配合物的合成与晶体结构研究[J]. 无机化学学报, 2013, 29(7): 1521-1526. doi: 10.3969/j.issn.1001-4861.2013.00.235 shu
Citation:  CHEN Xiao-Hua, WU Qiong-Jie, LU Wei, YANG Ming-Xing, CHEN Li-Juan. Syntheses and Crystal Structures of Two Vanadium Complexes with Salicyloylhydrazone Ligands[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1521-1526. doi: 10.3969/j.issn.1001-4861.2013.00.235 shu

二个含水杨酰腙配体的钒配合物的合成与晶体结构研究

  • 基金项目:

    福建省教育厅课题(No.JB10007)资助项目。 (No.JB10007)

摘要: 2种水杨酰腙配体H2L1(H2L1=邻羟基苯乙酮缩水杨酰腙)和H2L2(H2L2=水杨醛缩水杨酰腙)分别与VO(acac)2反应,合成了2个钒配合物[VOL1(C2H5O)]2 (1)和[VOL2(i-C3H7O)](2),利用元素分析、红外光谱、紫外光谱和单晶衍射等手段进行表征。配合物1是由酚氧原子桥联2个金属中心形成的具有晶体学中心对称性的双核钒(V)配合物结构,每个V(V)原子具有扭曲的八面体配位构型。配合物2为单核结构,每个V(V)原子具有扭曲的四角锥配位构型,相邻的配合物分子通过分子间氢键作用形成一维超分子链状结构。采用循环伏安法研究了化合物2的电化学性质。

English

  • 
    1. [1] Murphy T B, Rose N J, Schomaker V, et al. Inorg. Chim. Acta, 1985,108:183-194[1] Murphy T B, Rose N J, Schomaker V, et al. Inorg. Chim. Acta, 1985,108:183-194

    2. [2] Seena E B, Mathew N, Kuriakose M, et al. Polyhedron, 2008,27:1455-1462[2] Seena E B, Mathew N, Kuriakose M, et al. Polyhedron, 2008,27:1455-1462

    3. [3] Ghosh T, Mondal B, Ghosh T, et al. Inorg. Chim. Acta, 2007, 360:1753-1761[3] Ghosh T, Mondal B, Ghosh T, et al. Inorg. Chim. Acta, 2007, 360:1753-1761

    4. [4] Kuriakose M, Kurup M R P, Suresh E. Polyhedron, 2007,26: 2713-2718[4] Kuriakose M, Kurup M R P, Suresh E. Polyhedron, 2007,26: 2713-2718

    5. [5] LI Lian-Zhi(李连之), XU Tao(许涛), WANG Da-Qi(王大奇), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2004,20:236-240[5] LI Lian-Zhi(李连之), XU Tao(许涛), WANG Da-Qi(王大奇), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2004,20:236-240

    6. [6] Liu S X, Gao S. Polyhedron, 1998,17,81-84[6] Liu S X, Gao S. Polyhedron, 1998,17,81-84

    7. [7] DENG Zhao-Peng(邓兆鹏), GAO Shan(高山), ZHAO Hui (赵辉), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2007,23:173-176[7] DENG Zhao-Peng(邓兆鹏), GAO Shan(高山), ZHAO Hui (赵辉), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2007,23:173-176

    8. [8] Huang S M, Jiang F F, Chen X H, et al. Acta Cryst., 2010, E66:m456[8] Huang S M, Jiang F F, Chen X H, et al. Acta Cryst., 2010, E66:m456

    9. [9] LIU Jiu-Hui(刘九辉), WU Xiao-Yuan(吴小园), ZHANG Quan-Zheng(张全争), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2006,22:1028-1032[9] LIU Jiu-Hui(刘九辉), WU Xiao-Yuan(吴小园), ZHANG Quan-Zheng(张全争), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2006,22:1028-1032

    10. [10] Sheldrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution, University of Göttingen, Germany, 1997.[10] Sheldrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution, University of Göttingen, Germany, 1997.

    11. [11] Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Refinement, University of Göttingen, Germany, 1997.[11] Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Refinement, University of Göttingen, Germany, 1997.

    12. [12] Palacios M S, Rocio M J, Domnguez S, et al. Polyhedron, 1997,16:1143-1147[12] Palacios M S, Rocio M J, Domnguez S, et al. Polyhedron, 1997,16:1143-1147

    13. [13] Monfared H H, Kheirabadi S, Lalami N A, et al. Polyhedron, 2011,16:1375-1384[13] Monfared H H, Kheirabadi S, Lalami N A, et al. Polyhedron, 2011,16:1375-1384

    14. [14] Chen X H, Wu Q J, Liang Z Y, et al. Acta Cryst., 2009, C65:m190-m194[14] Chen X H, Wu Q J, Liang Z Y, et al. Acta Cryst., 2009, C65:m190-m194

    15. [15] WU Qiong-Jie(吴琼洁), CHEN Xiao-Hua(陈小华), CAI Bi-Qiong(蔡碧琼), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28:201-206[15] WU Qiong-Jie(吴琼洁), CHEN Xiao-Hua(陈小华), CAI Bi-Qiong(蔡碧琼), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28:201-206

    16. [16] Addison A W, Rao T N, Reedijk J, et al. J. Chem. Soc., Dalton Trans., 1984:1349-1356[16] Addison A W, Rao T N, Reedijk J, et al. J. Chem. Soc., Dalton Trans., 1984:1349-1356

    17. [17] Monfared H H, Kheirabadi S, Lalami, et al. Polyhedron, 2011,30:1375-1384[17] Monfared H H, Kheirabadi S, Lalami, et al. Polyhedron, 2011,30:1375-1384

    18. [18] Sutradhar M, Mukherjee G, Drew M G B, et al. Inorg. Chem., 2006,45:5150-5161[18] Sutradhar M, Mukherjee G, Drew M G B, et al. Inorg. Chem., 2006,45:5150-5161

    19. [19] Gao S, Weng Z Q, Liu S X. Polyhedron, 1998,17,3595-3606[19] Gao S, Weng Z Q, Liu S X. Polyhedron, 1998,17,3595-3606

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  • 收稿日期:  2012-09-04
  • 网络出版日期:  2013-02-24
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