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铅离子与镉离子高选择性的大环化合物：对称四甲基六元瓜环与过渡金属及重金属离子的配合作用

卢小军 ,  周发根 ,  冯星 ,  薛赛风 ,  陶朱 ,  祝黔江

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引用本文: 卢小军, 周发根, 冯星, 薛赛风, 陶朱, 祝黔江. 铅离子与镉离子高选择性的大环化合物：对称四甲基六元瓜环与过渡金属及重金属离子的配合作用[J]. 无机化学学报, 2013, 29(7): 1513-1520. doi: 10.3969/j.issn.1001-4861.2013.00.192 shu
Citation:  LU Xiao-Jun, ZHOU Fa-Gen, FENG Xing, XUE Sai-Feng, TAO Zhu, ZHU Qian-Jiang. Highly Selective Compounds for Lead and Cadmium：Complexation of α,α’,δ,δ’-Tetramethylcucurbit[6]uril with Transition-Metal and Heavy-Metal Ions[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1513-1520. doi: 10.3969/j.issn.1001-4861.2013.00.192 shu

铅离子与镉离子高选择性的大环化合物：对称四甲基六元瓜环与过渡金属及重金属离子的配合作用

  • 基金项目:

    国家自然科学基金(No.21272045)资助项目。 (No.21272045)

摘要: 利用微分脉冲伏安法研究了对称四甲基六元瓜环(TMeQ[6])与过渡金属的相互作用。结果表明该主体大环化合物对Pb2+和Cd2+离子具有较好的选择性作用。伏安数据测定表明Pb2+及Cd2+离子与对称四甲基六元瓜环以nM2+/nTMeQ[6]=2配位,其配合平衡常数分别为(KPb2+=2.12×109 L2·mol-2,KCd2+=2.10×109 L2·mol-2)。Pb2+离子与TMeQ[6]的晶体结构进一步证实了上述实验结果。

English

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  • 收稿日期:  2012-07-27
  • 网络出版日期:  2013-02-25
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