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吡啶-2,5-二羧酸钐(Ⅲ)、镝(Ⅲ)配合物的合成、结构及性质

解凤霞 ,  张欣欣 ,  张丹 ,  华敏 ,  张逢星

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引用本文: 解凤霞, 张欣欣, 张丹, 华敏, 张逢星. 吡啶-2,5-二羧酸钐(Ⅲ)、镝(Ⅲ)配合物的合成、结构及性质[J]. 无机化学学报, 2013, 29(7): 1497-1503. doi: 10.3969/j.issn.1001-4861.2013.00.214 shu
Citation:  XIE Feng-Xia, ZHANG Xin-Xin, ZHANG Dan, HUA Min, ZHANG Feng-Xing. Synthesis, Structure and Properties of Sm(Ⅲ) and Dy(Ⅲ) Complexes with Pyridine-2,5-dicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1497-1503. doi: 10.3969/j.issn.1001-4861.2013.00.214 shu

吡啶-2,5-二羧酸钐(Ⅲ)、镝(Ⅲ)配合物的合成、结构及性质

  • 基金项目:

    西安工程大学校科研启动基金(No.BS0902)资助项目。 (No.BS0902)

摘要: 以Sm(NO3)3·6H2O、Dy(NO3)3·6H2O、吡啶-2,5-二羧酸(H2pydc)为原料,用水热合成法合成了2个新的稀土金属配合物[Ln(pydc)2(H2O)5]·4H2O(Ln=Sm (1),Dy (2)),单晶结构经X单晶衍射仪分析确定,两种配合物的晶系均为单斜晶系,C2/c空间群。对晶体的性质进行元素分析、热重、红外光谱,荧光等分析。结果表明,配合物1和2在常温下表现出稀土离子相应的特征荧光发射。另外,本文对两种配合物进行了热稳定性及动力学分析。

English

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    1. [1] Ma H Y, Spaniol T P, Okuda J. Dalton Trans., 2003:4770-4780[1] Ma H Y, Spaniol T P, Okuda J. Dalton Trans., 2003:4770-4780

    2. [2] Thibon A, Pierre V C. J. Am. Chem. Soc., 2009,131:434-435[2] Thibon A, Pierre V C. J. Am. Chem. Soc., 2009,131:434-435

    3. [3] Shen Z Q, Ouyang J. Handbook on the Physics and Chemistry of Rare Earths. North Holand: Elsevier Science Publisher, 1987:61[3] Shen Z Q, Ouyang J. Handbook on the Physics and Chemistry of Rare Earths. North Holand: Elsevier Science Publisher, 1987:61

    4. [4] Jia J H, Lin X, Blake A J, et al. Inorg. Chem., 2006,45:8838-8840[4] Jia J H, Lin X, Blake A J, et al. Inorg. Chem., 2006,45:8838-8840

    5. [5] ZHANG Xing-Jing (张兴晶), XING Yong-Heng (邢永恒), WANG Chun-Guang (王春光), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009,25:407-411[5] ZHANG Xing-Jing (张兴晶), XING Yong-Heng (邢永恒), WANG Chun-Guang (王春光), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009,25:407-411

    6. [6] Chen B L, Yang Y, Zapata F, et al. Adv. Mater., 2007,19: 1693-1696[6] Chen B L, Yang Y, Zapata F, et al. Adv. Mater., 2007,19: 1693-1696

    7. [7] FENG Lin(冯林), JIANG Chong-Qiu(江崇球), SHI Jing-Min (石敬民). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(9):1635-1638[7] FENG Lin(冯林), JIANG Chong-Qiu(江崇球), SHI Jing-Min (石敬民). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(9):1635-1638

    8. [8] YANG Rui(杨锐), HE Shui-Yang(何水样), WU Wang-Ting (武望婷), et al. Chem. J. Chinese Universities(Gaodeng Xuexiao Huaxue Xuebao), 2005,26(3):401-406[8] YANG Rui(杨锐), HE Shui-Yang(何水样), WU Wang-Ting (武望婷), et al. Chem. J. Chinese Universities(Gaodeng Xuexiao Huaxue Xuebao), 2005,26(3):401-406

    9. [9] GUO Dong-Cai(郭栋才), SU Wan-Liang(舒万良), ZHOU Yue(周悦), et al. Chinese Rare Earths(Xitu), 2004,25(2):4-6[9] GUO Dong-Cai(郭栋才), SU Wan-Liang(舒万良), ZHOU Yue(周悦), et al. Chinese Rare Earths(Xitu), 2004,25(2):4-6

    10. [10] ZHOU Xia-Ying(周夏英), HUANG Yong-Qing(黄永清), SUN Wei-Yin(孙为银). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24(11):1733-1737[10] ZHOU Xia-Ying(周夏英), HUANG Yong-Qing(黄永清), SUN Wei-Yin(孙为银). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24(11):1733-1737

    11. [11] JIANG Zu-Cheng(江祖成), CAI Ru-Xiu(蔡汝秀), ZHANG Hua-Shan(张华山). REE Analysis Chemistry. 2nd Ed.(稀土 元素分析化学.2版). Beijing: Science Press, 2001:2-25[11] JIANG Zu-Cheng(江祖成), CAI Ru-Xiu(蔡汝秀), ZHANG Hua-Shan(张华山). REE Analysis Chemistry. 2nd Ed.(稀土 元素分析化学.2版). Beijing: Science Press, 2001:2-25

    12. [12] Wang C G, Xing Y H, Li Z P, et al. J. Mol. Struct., 2009, 921:126-131[12] Wang C G, Xing Y H, Li Z P, et al. J. Mol. Struct., 2009, 921:126-131

    13. [13] Huang Y G, Jiang F L, Yuan D Q, et al. Cryst. Growth Des., 2008,8:166-168[13] Huang Y G, Jiang F L, Yuan D Q, et al. Cryst. Growth Des., 2008,8:166-168

    14. [14] Bruker 2000, SMART (Version 5.0), SAINT-plus(Version 6), SHELXTL (Version 6.1)[14] Bruker 2000, SMART (Version 5.0), SAINT-plus(Version 6), SHELXTL (Version 6.1)

    15. [15] Liu Q Y, Xu L. Eur. J. Inorg. Chem., 2005:3458-3466[15] Liu Q Y, Xu L. Eur. J. Inorg. Chem., 2005:3458-3466

    16. [16] Pan L, Huang X Y, et al. Angew. Chem., Int. Ed., 2000,39: 527-529[16] Pan L, Huang X Y, et al. Angew. Chem., Int. Ed., 2000,39: 527-529

    17. [17] Malek J. Thermochim. Acta, 1989,138(1/2): 337-369[17] Malek J. Thermochim. Acta, 1989,138(1/2): 337-369

    18. [18] HU Rong-Zu(胡荣祖), SHI Qi-Zhen(史启祯). Thermal Analysis Kinetics(热分析动力学). Beijing: Science and Technology Press, 2001:1-20[18] HU Rong-Zu(胡荣祖), SHI Qi-Zhen(史启祯). Thermal Analysis Kinetics(热分析动力学). Beijing: Science and Technology Press, 2001:1-20

    19. [19] Matthias Wagner, Translated by LU Li-Ming(陆立明). Thermal Analysis in Practice(热分析应用基础). Shanghai: Donghua University Press, 2011:114-124[19] Matthias Wagner, Translated by LU Li-Ming(陆立明). Thermal Analysis in Practice(热分析应用基础). Shanghai: Donghua University Press, 2011:114-124

    20. [20] XU Jin-Gou(许金钩), WANG Zun-Ben(王尊本). Fluoresce-nce Analysis Method. 3rd Ed.(荧光分析法.3版). Beijing: Science Press, 2006:131-150[20] XU Jin-Gou(许金钩), WANG Zun-Ben(王尊本). Fluoresce-nce Analysis Method. 3rd Ed.(荧光分析法.3版). Beijing: Science Press, 2006:131-150

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  • 收稿日期:  2012-05-22
  • 网络出版日期:  2013-03-06
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