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带有水簇(H2O)4的四氰合镍配合物的合成与磁性研究

崔红霞

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引用本文: 崔红霞. 带有水簇(H2O)4的四氰合镍配合物的合成与磁性研究[J]. 无机化学学报, 2013, 29(7): 1485-1489. doi: 10.3969/j.issn.1001-4861.2013.00.217 shu
Citation:  CUI Hong-Xia. Synthesis and Magnetic Property of a Novel Tetracyanonickelate(Ⅱ) Complex with Discrete Water Cluster (H2O)4[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1485-1489. doi: 10.3969/j.issn.1001-4861.2013.00.217 shu

带有水簇(H2O)4的四氰合镍配合物的合成与磁性研究

摘要: 一个四氰合镍配合物{[Ni(i-Pr3TACN)][Ni(CN)4]}2·2H2O(1)通过K2[Ni(CN)4]和[NiPr3TACN]Cl2自组装的方法合成,单晶解析表明其配合物中存在一个由4个分子水组成的水簇。4个水分子在一个平面上,每个水分子即是氢键的给体也是氢键的受体。磁化率测定表明配合物中Ni(Ⅱ)间为反铁磁作用且J值为-1.09 cm-1.

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  • 收稿日期:  2012-04-23
  • 网络出版日期:  2013-03-04
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