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3-羧基苯氧乙酸根及邻菲咯啉构筑的钕(Ⅲ)配位聚合物的合成、晶体结构及磁性质

顾金忠 ,  邵永亮 ,  朱孔阳

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引用本文: 顾金忠, 邵永亮, 朱孔阳. 3-羧基苯氧乙酸根及邻菲咯啉构筑的钕(Ⅲ)配位聚合物的合成、晶体结构及磁性质[J]. 无机化学学报, 2013, 29(7): 1480-1484. doi: 10.3969/j.issn.1001-4861.2013.00.223 shu
Citation:  GU Jin-Zhong, SHAO Yong-Liang, ZHU Kong-Yang. Synthesis, Crystal Structure and Magnetic Properties of a Nd(Ⅲ) Coordination Polymer Constructed by 3-Carboxyphenoxyacetate and 1,10-Phenanthroline[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1480-1484. doi: 10.3969/j.issn.1001-4861.2013.00.223 shu

3-羧基苯氧乙酸根及邻菲咯啉构筑的钕(Ⅲ)配位聚合物的合成、晶体结构及磁性质

  • 基金项目:

    国家自然科学基金(No.21071068)资助项目。 (No.21071068)

摘要: 在水热反应条件下,采用3-羧基苯氧乙酸(3-H2CPOA=3-carboxyphenoxyacetatic acid)和phen (phen=1,10-phenanthroline)与NdCl3·6H2O反应,合成了1个具有三维结构的配位聚合物[Nd(3-CPOA)1.5(phen)]n (1),并对其结构和磁性质进行了研究。结构分析结果表明该聚合物的晶体属于单斜晶系,P21/c空间群。2个钕(Ⅲ)离子、3个3-CPOA2-配体和2个phen配体形成了1个[Nd2(3-CPOA)3(phen)2]双核轮状结构单元,这些双核单元通过钕(Ⅲ)离子与3-CPOA2-配体的配位作用形成了1个三维框架结构。磁性研究表明,该聚合物中相邻的钕(Ⅲ)离子之间存在很强的反铁磁相互作用。

English

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    1. [1] Yan X H, Li Y F, Wang Q, et al. Cryst. Growth Des., 2011, 11:4205-4212[1] Yan X H, Li Y F, Wang Q, et al. Cryst. Growth Des., 2011, 11:4205-4212

    2. [2] Lu W G, Jiang L, Lu T B. Cryst. Growth Des., 2010,10:4310-4318[2] Lu W G, Jiang L, Lu T B. Cryst. Growth Des., 2010,10:4310-4318

    3. [3] Zhou R S, Cui X B, Song J F, et al. J. Solid State Chem., 2008,181:2099-2107[3] Zhou R S, Cui X B, Song J F, et al. J. Solid State Chem., 2008,181:2099-2107

    4. [4] Gu J Z, Gao, Z Q, Tang Y. Cryst. Growth Des., 2012,12: 3312-3323[4] Gu J Z, Gao, Z Q, Tang Y. Cryst. Growth Des., 2012,12: 3312-3323

    5. [5] Gándara F, De Andrés A, Gómez-Lor B, et al. Cryst. Growth Des., 2008,8:378-380[5] Gándara F, De Andrés A, Gómez-Lor B, et al. Cryst. Growth Des., 2008,8:378-380

    6. [6] Aillaud I, Collin J, Duhayon C, et al. Chem. Eur. J., 2008, 14:2189-2200[6] Aillaud I, Collin J, Duhayon C, et al. Chem. Eur. J., 2008, 14:2189-2200

    7. [7] LIU Zhong-Yue(刘忠月), LIU Kun(刘昆), ZHANG Yun-Xing (张运兴), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(4):710-714[7] LIU Zhong-Yue(刘忠月), LIU Kun(刘昆), ZHANG Yun-Xing (张运兴), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(4):710-714

    8. [8] Devic T, Serre C, Audebrand N, et al. J. Am. Chem. Soc., 2005,127:12788-12789[8] Devic T, Serre C, Audebrand N, et al. J. Am. Chem. Soc., 2005,127:12788-12789

    9. [9] Chandler B D, Cramb D T, Shimizu G K H. J. Am. Chem. Soc., 2006,128:10403-10412[9] Chandler B D, Cramb D T, Shimizu G K H. J. Am. Chem. Soc., 2006,128:10403-10412

    10. [10] Ramya A R, Reddy M L P, Cowley A H, et al. Inorg. Chem., 2010,49:2407-2415[10] Ramya A R, Reddy M L P, Cowley A H, et al. Inorg. Chem., 2010,49:2407-2415

    11. [11] Su S Q, Chen W, Qin C, et al. Cryst. Growth Des., 2012,12: 1808-1815[11] Su S Q, Chen W, Qin C, et al. Cryst. Growth Des., 2012,12: 1808-1815

    12. [12] Chen B L, Wang L B, Xiao Y Q, et al. Angew. Chem., Int. Ed., 2009,48:500-503[12] Chen B L, Wang L B, Xiao Y Q, et al. Angew. Chem., Int. Ed., 2009,48:500-503

    13. [13] Yu L Q, Huang R D, Xu Y Q, et al. Inorg. Chem. Acta, 2008,361:2115-2122[13] Yu L Q, Huang R D, Xu Y Q, et al. Inorg. Chem. Acta, 2008,361:2115-2122

    14. [14] Bao S S, Ma L F, Wang Y, et al. Chem. Eur. J., 2007,13: 2333-2343[14] Bao S S, Ma L F, Wang Y, et al. Chem. Eur. J., 2007,13: 2333-2343

    15. [15] Li Z Y, Zhu G S, Guo X D, et al. Inorg. Chem., 2007,46: 5174-5178[15] Li Z Y, Zhu G S, Guo X D, et al. Inorg. Chem., 2007,46: 5174-5178

    16. [16] Deng Z P, Huo L H, Gao S, et al. Z. Anorg. Allg. Chem., 2010,636:835-839[16] Deng Z P, Huo L H, Gao S, et al. Z. Anorg. Allg. Chem., 2010,636:835-839

    17. [17] GAO Shan(高山), GU Chang-Sheng(谷长生), ZHAO Hhui (赵辉), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2004,20(12):1437-1440[17] GAO Shan(高山), GU Chang-Sheng(谷长生), ZHAO Hhui (赵辉), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2004,20(12):1437-1440

    18. [18] Gu C S, Liu J W, Huo L H, et al. Acta Cryst., 2004,E60: o760-o761[18] Gu C S, Liu J W, Huo L H, et al. Acta Cryst., 2004,E60: o760-o761

    19. [19] Sheldrick G M. SHELXL NT Version 5.1, Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany, 1997.[19] Sheldrick G M. SHELXL NT Version 5.1, Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany, 1997.

    20. [20] Lu T B, Ji L N, Tan M Y, et al. Polyhedron, 1997,16:1149-1156[20] Lu T B, Ji L N, Tan M Y, et al. Polyhedron, 1997,16:1149-1156

    21. [21] LIN Xiu-Yun(林秀云), HUANG Ling(黄玲), HUANG Chun-Hun(黄春辉), et al. Chinese J. Struct. Chem.(Jiegou Huaxue), 1997,16(2):133-136[21] LIN Xiu-Yun(林秀云), HUANG Ling(黄玲), HUANG Chun-Hun(黄春辉), et al. Chinese J. Struct. Chem.(Jiegou Huaxue), 1997,16(2):133-136

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  • 收稿日期:  2012-02-16
  • 网络出版日期:  2013-01-31
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