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二苄基锡水杨醛缩邻氨基苯酚Schiff碱配合物的合成、结构及荧光性质研究

张复兴 ,  王剑秋 ,  邝代治 ,  冯泳兰 ,  陈志敏 ,  许志锋 ,  庾江喜

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引用本文: 张复兴, 王剑秋, 邝代治, 冯泳兰, 陈志敏, 许志锋, 庾江喜. 二苄基锡水杨醛缩邻氨基苯酚Schiff碱配合物的合成、结构及荧光性质研究[J]. 无机化学学报, 2013, 29(7): 1442-1446. doi: 10.3969/j.issn.1001-4861.2013.00.206 shu
Citation:  ZHANG Fu-Xing, WANG Jian-Qiu, KUANG Dai-Zhi, FENG Yong-Lan, CHEN Zhi-Ming, XU Zhi-Feng, YU Jiang-Xi. Synthesis, Crystal Structure and Photoluminescence Properties of Dibenzyl Tin Complex with Salicylidene-2-aminophenol[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1442-1446. doi: 10.3969/j.issn.1001-4861.2013.00.206 shu

二苄基锡水杨醛缩邻氨基苯酚Schiff碱配合物的合成、结构及荧光性质研究

  • 基金项目:

    湖南省高校创新平台开放基金项目(No.12K124) (No.12K124)

    湖南省自然科学基金项目(No.11JJ3021) (No.11JJ3021)

    湖南省重点学科基金和湖南省高校重点实验 室开放基金(No.11K01)资助项目。 (No.11K01)

摘要: 二苄基二氯化锡和水杨醛缩邻氨基苯酚Schiff碱按物质的量比1:1反应,合成了二苄基锡水杨醛邻缩氨基苯酚Schiff碱配合物。经X-射线衍射方法测定了其晶体结构,属单斜晶系,空间群为P21/n,晶体学参数a=1.110 03(3) nm,b=1.719 87(5) nm,c=1.176 09(3) nm,β=100.564 0(10)°,V=2.207 23(10) nm3,Z=4,Dc=1.541 g·cm-3,μ(Mo Kα)=11.81 cm-1,F(000)=1 023,R1=0.026 8,wR2=0.061 9,中心锡原子为五配位的畸变三角双锥构型。对其结构进行量子化学从头计算,探讨了配合物的稳定性、分子轨道能量以及部分前沿分子轨道的组成特征。研究了配合物的荧光性质。

English

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  • 收稿日期:  2012-08-24
  • 网络出版日期:  2013-02-03
通讯作者: 陈斌, bchen63@163.com
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