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两个4-连接配位网络的锌(Ⅱ)配位聚合物的合成、结构和荧光性质

卢文贯 ,  刘宏文 ,  殷旭光 ,  蓝路梅 ,  刘克美 ,  刘海瑶 ,  黄静 ,  吴琪欣 ,  廖彩兰

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引用本文: 卢文贯, 刘宏文, 殷旭光, 蓝路梅, 刘克美, 刘海瑶, 黄静, 吴琪欣, 廖彩兰. 两个4-连接配位网络的锌(Ⅱ)配位聚合物的合成、结构和荧光性质[J]. 无机化学学报, 2013, 29(7): 1433-1441. doi: 10.3969/j.issn.1001-4861.2013.00.234 shu
Citation:  LU Wen-Guan, LIU Hong-Wen, YIN Xu-Guang, LAN Lu-Mei, LIU Ke-Mei, LIU Hai-Yao, HUANG Jing, WU Qi-Xin, LIAO Cai-Lan. Synthesis, Structure and Fluorescent Properties of Two Zn(Ⅱ) Coordination Polymers with 4-Connected Coordination Network[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1433-1441. doi: 10.3969/j.issn.1001-4861.2013.00.234 shu

两个4-连接配位网络的锌(Ⅱ)配位聚合物的合成、结构和荧光性质

  • 基金项目:

    国家自然科学基金(No.21071099) (No.21071099)

    2012年广东省大学生创新训练计划资助项目。 

摘要: 以5-氨基四氮唑(HATz),异烟酸(HPyc)和ZnSO4·7H2O或Zn(NO3)2·6H2O为反应物,在DMF溶剂热条件下分别得到了2个锌(Ⅱ)配位聚合物{[(CH3)2NH2]·[Zn(ATz)(SO4)]}n (1)和{[Zn(ATz)(Pyc)]·0.5DMF}n (2),并对它们的组成和结构进行了表征。配合物1是由4-连接(4,4)网络拓扑的[Zn(ATz)(SO4)]nn-二维阴离子层和[(CH3)2NH2]+阳离子间通过氢键作用形成的二维波浪层结构。配合物2则是1个二重穿插的4-连接金刚烷拓扑的三维微孔金属-有机框架结构,客体DMF分子填充在孔道内。室温下的固体荧光实验表明,在350 nm的光激发下,配合物1和2分别在为445 nm和458 nm处出现强烈的荧光发射。

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  • 收稿日期:  2013-01-27
  • 网络出版日期:  2013-03-26
通讯作者: 陈斌, bchen63@163.com
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