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单分散掺硫碳微球的水热制备及其表征

郑明涛 ,  肖勇 ,  张浩然 ,  董汉武 ,  龚学斌 ,  徐汝淳 ,  雷炳富 ,  刘应亮 ,  刘晓瑭

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引用本文: 郑明涛, 肖勇, 张浩然, 董汉武, 龚学斌, 徐汝淳, 雷炳富, 刘应亮, 刘晓瑭. 单分散掺硫碳微球的水热制备及其表征[J]. 无机化学学报, 2013, 29(7): 1391-1399. doi: 10.3969/j.issn.1001-4861.2013.00.244 shu
Citation:  ZHENG Ming-Tao, XIAO Yong, ZHANG Hao-Ran, DONG Han-Wu, GONG Xue-Bin, XU Ru-Chun, LEI Bing-Fu, LIU Ying-Liang, LIU Xiao-Tang. Hydrothermal Synthesis and Characterization of Sulfur-Doped Carbon Microspheres[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1391-1399. doi: 10.3969/j.issn.1001-4861.2013.00.244 shu

单分散掺硫碳微球的水热制备及其表征

  • 基金项目:

    国家自然科学基金(No.21201065,21031001,U0734005) (No.21201065,21031001,U0734005)

    广东省自然科学基金(No.s2012040007836) (No.s2012040007836)

    广东省高校科技创新计划(No.cxzd1014) (No.cxzd1014)

    华南农业大学校长基金资助项目。 

摘要: 以可溶性淀粉为碳源,采用硫辅助水热碳化法一步制备了平均粒径约为4 μm的单分散掺硫碳微球。利用扫描电镜、透射电镜、X射线衍射、氮气吸脱附、傅里叶变换红外光谱、X射线光电子能谱、固体核磁共振等手段对掺硫碳微球的结构和性质进行了表征。硫辅助水热碳化法可以在高浓度条件下高产量地制备分散性良好的掺硫碳微球,更重要的是硫原子可以同步进入碳的网络结构中。与传统水热碳化法相比,采用硫辅助水热碳化法制备的掺硫碳微球具有更高的比表面积,其可能的原因是硫原子的引入产生了大量的化学与结构缺陷:-S-S-、-S-、-SO2-和-SO-等基团构成化学缺陷,而噻吩等五元环取代石墨六元环形成结构缺陷。

English

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  • 收稿日期:  2013-02-22
  • 网络出版日期:  2013-03-16
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