注册 English

石墨烯包覆碳纳米管-硫(CNT-S)复合材料及锂硫电池性能

郑加飞 ,  郑明波 ,  李念武 ,  吕洪岭 ,  邱兰 ,  曹洁明 ,  姬广斌

downloadPDF
引用本文: 郑加飞, 郑明波, 李念武, 吕洪岭, 邱兰, 曹洁明, 姬广斌. 石墨烯包覆碳纳米管-硫(CNT-S)复合材料及锂硫电池性能[J]. 无机化学学报, 2013, 29(7): 1355-1360. doi: 10.3969/j.issn.1001-4861.2013.00.218 shu
Citation:  ZHENG Jia-Fei, ZHENG Ming-Bo, LI Nian-Wu, LU Hong-Ling, QIU Lan, CAO Jie-Ming, JI Guang-Bin. Preparation of Graphene Coated Carbon Nanotube-Sulfur Composite and Its Performance for Lithium-Sulfur Battery[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1355-1360. doi: 10.3969/j.issn.1001-4861.2013.00.218 shu

石墨烯包覆碳纳米管-硫(CNT-S)复合材料及锂硫电池性能

  • 基金项目:

    国家自然科学基金(No.51202106,No.51172109) (No.51202106,No.51172109)

    江苏省自然科学基金(No.BK2010497)资助项目。 (No.BK2010497)

摘要: 针对锂硫电池研究与实际应用中遇到的主要问题,本文通过一种简单有效的水热法还原氧化石墨烯对商用碳纳米管-硫(CNT-S)纳米复合材料进行包覆,形成一种可有效抑制多硫聚合物扩散的石墨烯包覆结构。X射线衍射(XRD),扫描电子显微镜(SEM)表征结果表明硫均匀地负载在碳纳米管上,并且在CNT-S复合材料外表面包覆有一层石墨烯。电化学测试结果表明,这种包覆结构能显著提高CNT-S复合材料的锂硫电池性能。

English

  • 

    1. [1] Yang Y, Yu G H, Cui Y, et al. ACS Nano, 2011,5(11):9187-9193[1] Yang Y, Yu G H, Cui Y, et al. ACS Nano, 2011,5(11):9187-9193

    2. [2] Bruce P G, Freunberger S A, Hardwick L J, et al. Nat. Mater., 2012,11:19-29[2] Bruce P G, Freunberger S A, Hardwick L J, et al. Nat. Mater., 2012,11:19-29

    3. [3] Bruce P G, Hardwick L J, Abraham K M. MRS Bull., 2011, 36(7):506-512[3] Bruce P G, Hardwick L J, Abraham K M. MRS Bull., 2011, 36(7):506-512

    4. [4] Jayaprakash N, Shen J, Moganty S S, et al. Angew. Chem., 2011,123(26):6026-6030[4] Jayaprakash N, Shen J, Moganty S S, et al. Angew. Chem., 2011,123(26):6026-6030

    5. [5] Wang C, Chen J J, Zheng M S, et al. Electrochimica Acta, 2010,55(23):7010-7015[5] Wang C, Chen J J, Zheng M S, et al. Electrochimica Acta, 2010,55(23):7010-7015

    6. [6] Ji X L, Evers S, Nazar L F, et al. Nat. Commun., 2011,2:325[6] Ji X L, Evers S, Nazar L F, et al. Nat. Commun., 2011,2:325

    7. [7] Ji X L, Lee K T, Nazar L F. Nat. Mater., 2009,8:500-506[7] Ji X L, Lee K T, Nazar L F. Nat. Mater., 2009,8:500-506

    8. [8] Xiao L F, Cao Y L, Liu J, et al. Adv. Mater., 2012,24(9): 1176-1181[8] Xiao L F, Cao Y L, Liu J, et al. Adv. Mater., 2012,24(9): 1176-1181

    9. [9] Ji X L, Nazar L F. J. Mater. Chem., 2010,20:9821-9826[9] Ji X L, Nazar L F. J. Mater. Chem., 2010,20:9821-9826

    10. [10] DONG Quan-Feng(董全峰), WANG Chong(王翀), ZHENG Ming-Sen(郑明森). Prog. Chem.(Huaxue Jinzhan), 2011,23 (2/3):533-539[10] DONG Quan-Feng(董全峰), WANG Chong(王翀), ZHENG Ming-Sen(郑明森). Prog. Chem.(Huaxue Jinzhan), 2011,23 (2/3):533-539

    11. [11] YANG Xue-Bing(杨学兵), WANG Chuan-Xin(王传新), WANG Jian-Hua(汪建华), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011,27(12):2431-2436[11] YANG Xue-Bing(杨学兵), WANG Chuan-Xin(王传新), WANG Jian-Hua(汪建华), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011,27(12):2431-2436

    12. [12] Cao Y L, Li X L, Liu J, et al. Phys. Chem. Chem. Phys., 2011,13:7660-7665[12] Cao Y L, Li X L, Liu J, et al. Phys. Chem. Chem. Phys., 2011,13:7660-7665

    13. [13] Wang J Z, Lu L, Xu X, et al. J. Power Sources, 2011,196 (16):7030-7034[13] Wang J Z, Lu L, Xu X, et al. J. Power Sources, 2011,196 (16):7030-7034

    14. [14] Liang C D, Dudney N J, Howe J Y. Chem. Mater., 2009,21 (19):4724-4730[14] Liang C D, Dudney N J, Howe J Y. Chem. Mater., 2009,21 (19):4724-4730

    15. [15] Wang J, Chew S Y, Zhao Z W, et al. Carbon, 2008,46(2): 229-235[15] Wang J, Chew S Y, Zhao Z W, et al. Carbon, 2008,46(2): 229-235

    16. [16] Yuan L X, Yuan H P, Qiu X P, et al. J. Power Sources, 2009,189(2):1141-1146[16] Yuan L X, Yuan H P, Qiu X P, et al. J. Power Sources, 2009,189(2):1141-1146

    17. [17] WU Feng(吴峰), WU Sheng-Xian(吴生先), CHEN Ren-Jie (陈人杰), et al. New Carbon Mater.(Xinxing Tancailiao), 2010,25(6):421-425[17] WU Feng(吴峰), WU Sheng-Xian(吴生先), CHEN Ren-Jie (陈人杰), et al. New Carbon Mater.(Xinxing Tancailiao), 2010,25(6):421-425

    18. [18] Dörfler S, Hagen M, Althues H, et al. Chem. Commun., 2012,48:4097-4099[18] Dörfler S, Hagen M, Althues H, et al. Chem. Commun., 2012,48:4097-4099

    19. [19] XUE Lu-Ping(薛露平), ZHENG Ming-Bo(郑明波), SHEN Cheng-Fei(沈辰飞), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(8):1375-1381[19] XUE Lu-Ping(薛露平), ZHENG Ming-Bo(郑明波), SHEN Cheng-Fei(沈辰飞), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(8):1375-1381

    20. [20] Zhang F F, Zhang X B, Wang L M, et al. J. Mater. Chem., 2012,22:11452-11454[20] Zhang F F, Zhang X B, Wang L M, et al. J. Mater. Chem., 2012,22:11452-11454

    21. [21] Wang H L, Yang Y, Dai H J, et al. Nano Lett., 2011,11(7): 2644-2647[21] Wang H L, Yang Y, Dai H J, et al. Nano Lett., 2011,11(7): 2644-2647

    22. [22] Li N W, Zheng M B, Cao J M, et al. Chem. Commun., 2012, 48(34):4106-4108[22] Li N W, Zheng M B, Cao J M, et al. Chem. Commun., 2012, 48(34):4106-4108

    23. [23] Zhou Y, Bao Q L, Zhong Y L, et al. Chem. Mater., 2009,21 (13):2950-2956[23] Zhou Y, Bao Q L, Zhong Y L, et al. Chem. Mater., 2009,21 (13):2950-2956

    24. [24] Shen J F, Yan B, Shi M, et al. J. Mater. Chem., 2011,21: 3415-3421[24] Shen J F, Yan B, Shi M, et al. J. Mater. Chem., 2011,21: 3415-3421

    25. [25] Navarro C B, Coronado E, Gastaldo C M, et al. Nanoscale, 2012,4:3977-3982[25] Navarro C B, Coronado E, Gastaldo C M, et al. Nanoscale, 2012,4:3977-3982

    26. [26] Hummers W S, Offeman R E. J. Am. Chem. Soc., 1958,80 (6):1339-1339[26] Hummers W S, Offeman R E. J. Am. Chem. Soc., 1958,80 (6):1339-1339

    27. [27] ZHUO Hua-Lan(卓华兰), YUAN Zhong-Zhi(袁中直), LIU Jin-Cheng(刘金城). Chinese J. Power Sources(Dianyuan Jishu), 2010,34(12):1242-1245[27] ZHUO Hua-Lan(卓华兰), YUAN Zhong-Zhi(袁中直), LIU Jin-Cheng(刘金城). Chinese J. Power Sources(Dianyuan Jishu), 2010,34(12):1242-1245

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  842
  • HTML全文浏览量:  146
文章相关
  • 收稿日期:  2013-01-10
  • 网络出版日期:  2013-03-15
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net