超分子凝胶性质与溶剂参数关系的研究进展

引用本文: 赵呈孝, 王海涛, 李敏. 超分子凝胶性质与溶剂参数关系的研究进展[J]. 物理化学学报, 2014, 30(12): 2197-2209. doi: 10.3866/PKU.WHXB201410211 shu

Citation: ZHAO Cheng-Xiao, WANG Hai-Tao, LI Min. Research Progress in the Correlation between Gelation Properties and Solvent Parameters[J]. Acta Physico-Chimica Sinica, 2014, 30(12): 2197-2209. doi: 10.3866/PKU.WHXB201410211 shu

超分子凝胶性质与溶剂参数关系的研究进展

基金项目:
国家自然科学基金(51103057, 51073071) (51103057, 51073071)

中国博士后科学基金(2012T50294)资助项目 (2012T50294)

摘要:

为了能有效地开发功能性凝胶, 人们对超分子凝胶机理做了大量研究. 但目前的研究还局限于凝胶因子结构和外界环境等影响因素, 而有关溶剂对超分子凝胶体系的影响规律还不十分清楚. 本文将结合最新研究进展详细地讨论凝胶性质(如凝胶-溶胶转变温度(T_gel)、临界凝胶浓度(CGC)、凝胶流变学性质等)与溶剂参数(如ε、E_T(30)、χ、δ、δ_d、δ_p、δ_h等)的关系, 揭示溶剂影响凝胶性质的规律; 在此基础上, 进一步介绍了超分子凝胶行为预测模型: 一维模型、Teas图模型和Hansen空间模型, 并讨论了各模型的优缺点, 以期为新型超分子凝胶体系的设计提供参考.

关键词:

English

Research Progress in the Correlation between Gelation Properties and Solvent Parameters

1.
1. College of Science, Nanjing Forestry University, Nanjing 210037, P. R. China;
2. School of Materials Science and Engineering, Jilin University, Changchun 130012, P. R. China
Received Date: 03 September 2014
Available Online: 27 November 2014
Fund Project:
国家自然科学基金(51103057, 51073071)

中国博士后科学基金(2012T50294)资助项目

Abstract:

To enable the effective development of functional gels, much effort has been dedicated to elucidating the mechanism of gelation. However, most existing studies have considered only the influence of the chemical structure of the gelators and/or external environmental factors; the contribution of the solvent in the gelation procedure is not yet understood. In this review, to reveal the solvent effects, the relationship between the gelation properties (such as the gel-sol phase transition temperature (T_gel), the critical gelation concentration (CGC), and the gelation behaviors) and the solvent parameters (ε、E_T(30), χ, δ, δ_d, δ_p, δ_h) is systematically discussed, based on recent research progress. Moreover, some experimental models for predicting the solvent effects (such as the one-dimensional model, Teas plot model, and Hansen space models) are introduced and discussed; these models could provide a guide for the development of new supramolecular gel systems.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

超分子凝胶性质与溶剂参数关系的研究进展

English

Research Progress in the Correlation between Gelation Properties and Solvent Parameters

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中国化学会秘书处

超分子凝胶性质与溶剂参数关系的研究进展

English

Research Progress in the Correlation between Gelation Properties and Solvent Parameters

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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