阴阳离子表面活性剂混合体系在克拉玛依油田中获得超低界面张力

引用本文: 赵海娜, 程新皓, 赵欧狄, 黄建滨, 刘晨江, 赵波. 阴阳离子表面活性剂混合体系在克拉玛依油田中获得超低界面张力[J]. 物理化学学报, 2014, 30(4): 693-698. doi: 10.3866/PKU.WHXB201402121 shu

Citation: ZHAO Hai-Na, CHENG Xin-Hao, ZHAO Ou-Di, HUANG Jian-Bin, LIU Chen-Jiang, ZHAO Bo. Mixed Cationic and Anionic Surfactant Systems Achieve Ultra-Low Interfacial Tension in the Karamay Oil Field[J]. Acta Physico-Chimica Sinica, 2014, 30(4): 693-698. doi: 10.3866/PKU.WHXB201402121 shu

阴阳离子表面活性剂混合体系在克拉玛依油田中获得超低界面张力

基金项目:
国家重点基础研究发展规划项目（973）（2013CB933800)

教育部博士点研究基金及新疆维吾尔自治区高技术研究发展计划项目（201215138）资助

摘要:

利用阴阳离子表面活性剂复配技术，在克拉玛依油田实际油水体系中获得了超低界面张力. 通过添加非离子保护剂的第三组分，阴阳离子表面活性剂混合体系在克拉玛依油田回注水体系中的溶解度大大提高. 确定了相关体系能够获得超低界面张力的表面活性剂的浓度和混合的比例范围，在克拉玛依油田的多个实际油水体系中获得了具有较大复配比例和较低表面活性剂浓度的实际配方，其中部分体系油水界面张力可接近10^-4 mN·m^-1. 同时，这类阴阳离子表面活性剂混合体系具有很好的抗吸附能力，在石英砂吸附72 h后体系依然呈现优良的超低界面张力.

关键词:

English

Mixed Cationic and Anionic Surfactant Systems Achieve Ultra-Low Interfacial Tension in the Karamay Oil Field

1.
1 Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, College of Chemistry and chemical Engineering, Xinjiang University, Urumqi 830046, P. R. China;
2 College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China;
3 Xinjiang Keli New Technology Development Ltd., Karamay 834099, Xinjiang Uygur Autonomous Region, P. R. China
Received Date: 31 October 2013
Available Online: 31 March 2014
Fund Project:
国家重点基础研究发展规划项目（973）（2013CB933800)

教育部博士点研究基金及新疆维吾尔自治区高技术研究发展计划项目（201215138）资助

Abstract:

Based on cationic and anionic surfactant mixed systems, ultra-low interfacial tension was achieved in the Karamay oil field systems. Upon the addition of a non-ionic third component, the solubility of the mixed cationic-anionic surfactant systems increased significantly. The mixed surfactant ratio and the concentration were determined by the application in the five areas of the Karamay oil field. The interfacial tension in some real systems was found to be around 10^-4 mN·m^-1. These cationic and anionic surfactant mixed systems have a super-resistance adsorption capacity. The results show that after 72 h of quartz adsorption, these systems can still reduce the interfacial tension to an ultra-low level.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

阴阳离子表面活性剂混合体系在克拉玛依油田中获得超低界面张力

English

Mixed Cationic and Anionic Surfactant Systems Achieve Ultra-Low Interfacial Tension in the Karamay Oil Field

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

阴阳离子表面活性剂混合体系在克拉玛依油田中获得超低界面张力

English

Mixed Cationic and Anionic Surfactant Systems Achieve Ultra-Low Interfacial Tension in the Karamay Oil Field

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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