3-硝基-1,3,4-三唑-5-酮金属(Li, Na, Pb, Cu)盐的制备反应热动力学

引用本文: 李娜, 赵凤起, 高红旭, 胡荣祖, 肖立柏, 姚二岗, 黄新萍, 常佩. 3-硝基-1,3,4-三唑-5-酮金属(Li, Na, Pb, Cu)盐的制备反应热动力学[J]. 物理化学学报, 2013, 29(10): 2101-2106. doi: 10.3866/PKU.WHXB201307153 shu

Citation: LI Na, ZHAO Feng-Qi, GAO Hong-Xu, HU Rong-Zu, XIAO Li-Bai, YAO Er-Gang, HUANG Xin-Ping, CHANG Pei. Thermokinetics of the Formation Reactions of Metal (Li, Na, Pb, Cu) Salts of 3-Nitro-1,2,4-triazol-5-one[J]. Acta Physico-Chimica Sinica, 2013, 29(10): 2101-2106. doi: 10.3866/PKU.WHXB201307153 shu

3-硝基-1,3,4-三唑-5-酮金属(Li, Na, Pb, Cu)盐的制备反应热动力学

基金项目:
国家自然科学基金(21173163) (21173163)

燃烧与爆炸技术重点实验室基金(9140C350307110C3506)资助项目 (9140C350307110C3506)

摘要:

在常压、298.15 K条件下, 用RD496-2000微量热仪开展了3-硝基-1,3,4-三唑-5-酮(NTO)金属(Li, Na,Pb, Cu)盐制备反应的热动力学研究, 得到了反应过程中的热力学参数(活化焓、活化熵和活化自由能), 速率常数和动力学参数(活化能、指前因子和反应级数), 还得到了在25-40℃范围内NTO金属(Li, Na, Pb, Cu)盐制备反应过程的反应焓. 结果表明, NTO金属(Li, Na, Pb, Cu)盐的制备反应较容易发生. 基于Hess定律, 得到了Δ_fH_m⁰ (Li(NTO)·2H₂O, aq, 298.15 K)和Δ_fH_m⁰ (Na(NTO)·H₂O, aq, 298.15 K)的值.

关键词:

English

Thermokinetics of the Formation Reactions of Metal (Li, Na, Pb, Cu) Salts of 3-Nitro-1,2,4-triazol-5-one

1.
Laboratory of Science and Technology on Combustion and Explosion, Xi'an Modern Chemistry Research Institute, Xi'an 710065, P. R. China
Received Date: 03 June 2013
Available Online: 26 September 2013
Fund Project:
国家自然科学基金(21173163)

燃烧与爆炸技术重点实验室基金(9140C350307110C3506)资助项目

Abstract:

The thermokinetics of the formation reactions of metal (Li, Na, Pb, Cu) salts of 3-nitro-1,2,4-triazol- 5-one (NTO) was studied using a microcalorimeter. On the basis of experimental and calculated results, three thermodynamic parameters (activation energy, pre-exponential constant, and reaction order), rate constant, three thermokinetic parameters (activation enthalpy, activation entropy, and activation free energy) and the enthalpies of the reactions to prepare the metal salts of NTO in the temperature range of 25-40℃ were obtained. The title reactions occur easily in the studied temperature range. Based on Hess' law, the values of Δ_fH_m⁰ (Li(NTO)·2H₂O, aq, 298.15 K) and Δ_fH_m⁰ (Na(NTO)·2H₂O, aq, 298.15 K) are obtained.

Key words:

Metal salts of 3-nitro-1,2,4-triazol-5-one
/ Formation reaction
/ Microcalorimeter
/ Thermokinetics

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

3-硝基-1,3,4-三唑-5-酮金属(Li, Na, Pb, Cu)盐的制备反应热动力学

English

Thermokinetics of the Formation Reactions of Metal (Li, Na, Pb, Cu) Salts of 3-Nitro-1,2,4-triazol-5-one

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

3-硝基-1,3,4-三唑-5-酮金属(Li, Na, Pb, Cu)盐的制备反应热动力学

English

Thermokinetics of the Formation Reactions of Metal (Li, Na, Pb, Cu) Salts of 3-Nitro-1,2,4-triazol-5-one

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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中国化学会秘书处

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