[Fe(N2H5)2(SO4)2]n的合成、结构和磁性质

引用本文: 王艳君, 贾丽慧, 王炳武. [Fe(N₂H₅)₂(SO₄)₂]_n的合成、结构和磁性质[J]. 物理化学学报, doi: 10.3866/PKU.WHXB201302212 shu

Citation: WANG Yan-Jun, JIA Li-Hui, WANG Bing-Wu. Synthesis, Structure and Magnetic Properties of Iron(II) Sulfate Containing Hydrazine[J]. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB201302212 shu

[Fe(N₂H₅)₂(SO₄)₂]_n的合成、结构和磁性质

基金项目:
国家自然科学基金(21101123, 21071008)资助项目 (21101123, 21071008)

摘要:

采用水热合成方法得到一例新的过渡金属铁(Fe)的含肼硫酸盐: [Fe(N₂H₅)₂(SO₄)₂]_n (1). 用单晶X射线衍射的方法对其晶体结构进行了表征. 结果表明, 该化合物以硫酸根为桥连配体, 质子化的肼分子为端基配体, 形成一维(1D)链状结构. 肼分子和硫酸根形成的链间氢键, 将1D链进一步扩展成三维(3D)结构. 磁性测试表明化合物在低温下显示出反铁磁有序的磁行为.

关键词:

English

Synthesis, Structure and Magnetic Properties of Iron(II) Sulfate Containing Hydrazine

1.
1 Key Laboratory for Green Chemical Process of Ministry of Education, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430074, P. R. China;
2 Beijing National Laboratory of Molecular Science, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
Received Date: 10 January 2013
Available Online: 25 March 2013
Fund Project:
国家自然科学基金(21101123, 21071008)资助项目

Abstract:

A novel transition metal iron(II) sulfate containing hydrazine (N₂H₄) ligand: [Fe(N₂H₅)₂(SO₄)₂]_n(1), is prepared by a hydrothermal method. Single-crystal X-ray diffraction reveals that 1 consists of onedimensional (1D) sulfate-bridged homometallic chains with protonated hydrazine molecules as terminal ligands. Hydrogen bonds between protonated hydrazine and sulfate ions connect the chains into a threedimensional (3D) extended framework. Magnetic measurements indicate that 1 exhibits the antiferromagnetic ordering behavior at low temperature.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

[Fe(N₂H₅)₂(SO₄)₂]_n的合成、结构和磁性质

English

Synthesis, Structure and Magnetic Properties of Iron(II) Sulfate Containing Hydrazine

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