氧化石墨烯对水中内分泌干扰物双酚A的吸附性能

引用本文: 徐婧, 朱永法. 氧化石墨烯对水中内分泌干扰物双酚A的吸附性能[J]. 物理化学学报, doi: 10.3866/PKU.WHXB201301211 shu

Citation: XU Jing, ZHU Yong-Fa. Elimination of Bisphenol A from Water via Graphene Oxide Adsorption[J]. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB201301211 shu

氧化石墨烯对水中内分泌干扰物双酚A的吸附性能

徐婧 ^1, ,
朱永法 ^1,2,

基金项目:
国家重点基础研究发展计划(973) (2013CB632403) (973) (2013CB632403)

国家高技术研究发展计划(863) (2012AA062701) (863) (2012AA062701)

科技部创新方法工作专项(2009IM030500) (2009IM030500)

江苏省大气环境监测与污染控制高技术研究重点实验室开放基金(AEMPC201103)资助项目 (AEMPC201103)

摘要:

以氧化石墨烯( )为吸附剂, 内分泌干扰物双酚A (BPA)为目标污染物, 考察了对水中BPA的吸附性能. 结果表明: 对BPA的最大吸附量(q_m)约为87.80 mg·g^-1 (25℃), 30 min左右即可达到吸附平衡, 远快于活性碳; 吸附动力学和等温线数据分别符合准二级动力学模型和Langmuir 吸附模型; 在溶液接近中性和低温的条件下有利于吸附的进行, 在溶液中存在电解质的条件下不利于吸附的进行. 具有优异的循环吸附性能, 经过多次循环使用后依然可以保持良好的吸附能力. 对BPA的吸附机理主要是由于本身的片状结构以及表面的含氧极性基团, 会与BPA之间产生π-π色散作用和氢键作用. 虽然对BPA的吸附能力不如石墨烯, 但是相比于石墨烯, 表面含有大量极性基团, 具有良好的亲水性, 且合成方法相对简单, 可批量生产用于工业污水处理. 因此, 在水处理领域, 有能力成为新型高效的吸附剂.

关键词:

English

Elimination of Bisphenol A from Water via Graphene Oxide Adsorption

XU Jing ^1, ,
ZHU Yong-Fa ^1,2,

1.
1 Department of Chemistry, Tsinghua University, Beijing 100084, P.R. China;
2 Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Nanjing University of Information Science and Technology, Nanjing 210044, P.R. China
Received Date: 31 October 2012
Available Online: 25 March 2013
Fund Project:
国家重点基础研究发展计划(973) (2013CB632403)

国家高技术研究发展计划(863) (2012AA062701)

科技部创新方法工作专项(2009IM030500)

江苏省大气环境监测与污染控制高技术研究重点实验室开放基金(AEMPC201103)资助项目

Abstract:

The elimination of bisphenol A (BPA) from aqueous solution by adsorption on graphene oxide ( ) was investigated. The maximum adsorption capacity (q_m) of for BPA estimated from the Langmuir isotherm was 87.80 mg·g^-1 at 25℃. The required contact time to reach adsorption equilibrium was about 30 min, which was much shorter than that of activated carbon. The adsorption kinetics and isotherm data fitted well with the pseudo-second-order kinetic model and the Langmuir isotherm, respectively. Neutral pH and low solution temperature were favorable for adsorption, whereas the presence of NaCl in the solution was unfavorable. The had od recyclability and could be reused several times with a slight decline in adsorption ability. Both hydrogen bonding and π-π interaction were thought to be responsible for the adsorption of BPA on . The excellent adsorption capacity and high adsorption rate of result from its sheet-like structure and the abundant oxygen-containing groups on its surface. Although q_m of for BPA is lower than that of graphene, has the benefits of large scale production, a hydrophilic surface with plenty of oxygen-containing groups, and od dispersion in water. Therefore, can be regarded as a od potential adsorbent for water treatment.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

氧化石墨烯对水中内分泌干扰物双酚A的吸附性能

English

Elimination of Bisphenol A from Water via Graphene Oxide Adsorption

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氧化石墨烯对水中内分泌干扰物双酚A的吸附性能

English

Elimination of Bisphenol A from Water via Graphene Oxide Adsorption

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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