附着性能优异的碳对电极的制备及其在染料敏化太阳能电池中的应用

引用本文: 储玲玲, 高玉荣, 武明星, 王琳琳, 马廷丽. 附着性能优异的碳对电极的制备及其在染料敏化太阳能电池中的应用[J]. 物理化学学报, 2012, 28(07): 1739-1744. doi: 10.3866/PKU.WHXB201204232 shu

Citation: CHU Ling-Ling, GAO Yu-Rong, WU Ming-Xing, WANG Lin-Lin, MA Ting-Li. Fabrication and Application of a Carbon Counter Electrode with Excellent Adhesion Properties for Dye-Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, 2012, 28(07): 1739-1744. doi: 10.3866/PKU.WHXB201204232 shu

附着性能优异的碳对电极的制备及其在染料敏化太阳能电池中的应用

基金项目:
国家自然科学基金(50773008) (50773008)

国家高技术研究发展计划(863) (2009AA03Z220)资助项目 (863) (2009AA03Z220)

摘要:

通过引入一种低成本商业导电碳浆(CC)作为粘结剂, 以色素碳黑(Cb)作为催化材料, 成功制备了Cb-CC对电极. 着重解决传统碳对电极的主要问题, 即碳与导电基底的附着力问题. 附着力测试结果表明: CC的引入改善了Cb与导电基板之间的附着力, 同时增强了碳对电极的导电性和稳定性. 扫描电镜(SEM)结果显示, CC与Cb混合后, 碳膜的多孔结构依然存在, 即这种对电极能同时增加导电性和催化活性. 采用循环伏安(CV)和电化学阻抗谱(EIS)对Cb-CC对电极的催化活性进行了研究. 光电性能测试结果表明, 基于Cb-CC染料敏化太阳能电池(DSSC)的能量转换效率达到了6.54%, 进一步优化后, 当Cb和CC的质量比为23:77 时效果最佳, 达到最高效率6.81%. 此外, 基于Cb-CC的DSSC长期稳定性测试结果表明, 700 h后各项光电参数无明显下降. 该实验成果为增强整体电池的稳定性和促进低成本DSSC产业化奠定了基础.

关键词:

English

Fabrication and Application of a Carbon Counter Electrode with Excellent Adhesion Properties for Dye-Sensitized Solar Cells

1.
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China
Received Date: 19 March 2012
Available Online: 07 June 2012
Fund Project:
国家自然科学基金(50773008)

国家高技术研究发展计划(863) (2009AA03Z220)资助项目

Abstract:

The aim of this study was to resolve the poor bonding strength between carbon film and the conductive substrate in a carbon counter electrode. A carbon black-conductive carbon (Cb-CC) counter electrode was fabricated using a low-cost commercial conductive carbon paste (CC) as a binder and carbon black (Cb) as a catalyst. Film adhesion test results indicated that the introduction of the CC significantly improved the adhesion between Cb and the conductive substrate, as well as the conductivity and stability of the carbon counter electrode. The porous structure of the mixed CC and Cb carbon films was maintained as illustrated by scanning electron microscopy (SEM). Cyclic-voltammetry (CV) and electrochemical impedance spectroscopy (EIS) measurements showed that the catalytic activity of CC-Cb was superior to that of CC. A dye-sensitized solar cell (DSSC) based on the CC-Cb counter electrode exhibited an excellent photoelectrical performance, reaching an energy conversion efficiency of 6.54%. The amount of CC in the carbon counter electrode was further optimized. Consequently, when the mass ratio of Cb:CC reached 23:77, the corresponding DSSC yielded the highest energy conversion efficiency recorded in this study at 6.81% . In addition, long term stability testing showed that the photovoltaic parameters of the DSSC based on the CC-Cb counter electrode remained similar to the initial values following more than 700 h of light soaking. This work has laid the foundation for improving the stability and the industrialization of low-cost DSSCs.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

附着性能优异的碳对电极的制备及其在染料敏化太阳能电池中的应用

English

Fabrication and Application of a Carbon Counter Electrode with Excellent Adhesion Properties for Dye-Sensitized Solar Cells

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

附着性能优异的碳对电极的制备及其在染料敏化太阳能电池中的应用

English

Fabrication and Application of a Carbon Counter Electrode with Excellent Adhesion Properties for Dye-Sensitized Solar Cells

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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