(苄基三乙基铵)双(1,3-二硫杂环戊烯-2-硫酮-4,5-二硫基)-金的三阶非线性光学性质

引用本文: 陈经纬, 王新强, 任诠, 李廷斌, 杨洪亮, 张敬楠, 李国超. (苄基三乙基铵)双(1,3-二硫杂环戊烯-2-硫酮-4,5-二硫基)-金的三阶非线性光学性质[J]. 物理化学学报, 2011, 27(03): 717-721. doi: 10.3866/PKU.WHXB20110340 shu

Citation: CHEN Jing-Wei, WANG Xin-Qiang, REN Quan, LI Ting-Bin, YANG Hong-Liang, ZHANG Jing-Nan, LI Guo-Chao. Third Order Nonlinear Optical Properties of Benzyltriethylamine Bis(2-thioxo-1,3-dithiole-4,5-dithiolato) Aurate(III)[J]. Acta Physico-Chimica Sinica, 2011, 27(03): 717-721. doi: 10.3866/PKU.WHXB20110340 shu

(苄基三乙基铵)双(1,3-二硫杂环戊烯-2-硫酮-4,5-二硫基)-金的三阶非线性光学性质

陈经纬 ^1, ,
王新强 ^2, ,
任诠 ^1, ,
李廷斌 ^3, ,
杨洪亮 ^1, ,
张敬楠 ^1, ,
李国超 ^1,

基金项目:
国家自然科学基金(60778037, 50772059, 11004123) (60778037, 50772059, 11004123)

高等学校全国优秀博士学位论文专项资金(200539) (200539)

山东省自然科学基金(ZR2009GQ007)资助项目 (ZR2009GQ007)

摘要:

合成了一种新的配位化合物(苄基三乙基铵)双(1,3-二硫杂环戊烯-2-硫酮-4,5-二硫基)-金(BTEAADT). 利用旋涂技术制备了该材料与聚甲基丙烯酸甲酯(PMMA)掺杂的复合薄膜, 该材料在复合薄膜中的质量分数为1%. 采用Z扫描方法, 分别测试了该材料的乙腈溶液和该材料与PMMA复合薄膜在波长为1064 nm, 脉宽为20 ps条件下的三阶非线性光学特性. 同时还研究了复合薄膜的线性光学性质. Z扫描的结果表明, 复合薄膜和该材料的乙腈溶液都具有自散焦效应, 非线性折射率都是负值. 在实验条件下, 两者的非线性吸收效应都是可以忽略的. 经过计算得出溶液样品的非线性折射率为-1.459×10^-18 m²·W^-1, 复合薄膜样品的非线性折射率为-3.978×10^-15 m²·W^-1. 该材料在1064 nm处的非线性光学器件方面有潜在应用价值.

关键词:

English

Third Order Nonlinear Optical Properties of Benzyltriethylamine Bis(2-thioxo-1,3-dithiole-4,5-dithiolato) Aurate(III)

1.
1. Department of Optics, Shandong University, Jinan 250100, P. R. China;
2. State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, P. R. China;
3. Department of Material Science and Technology, Taishan University, Tai′an 271021, Shandong Province, P. R. China
Received Date: 29 October 2010
Available Online: 03 March 2011
Fund Project:
国家自然科学基金(60778037, 50772059, 11004123)

高等学校全国优秀博士学位论文专项资金(200539)

山东省自然科学基金(ZR2009GQ007)资助项目

Abstract:

We prepared a new crystalline nonlinear optical coordination compound, benzyltriethylamine bis (2-thioxo-1,3-dithiole-4,5-dithiolato) aurate(III) (BTEAADT). A BTEAADT-doped poly(methyl methacrylate) (PMMA) thin film with a mass fraction of 1% was prepared by spin-coating. The third-order nonlinear optical properties of BTEAADT in acetonitrile and a BTEAADT-doped PMMA film were investigated using the laser Z-scan technique with 20 ps pulses at 1064 nm. The linear optical properties of the polymer thin film were also studied. The Z-scan spectra revealed that the polymer thin film sample possessed negative nonlinear refraction and exhibited a similar self-defocusing effect to that found for the solution. In addition, nonlinear absorption was negligible for both systems under the experimental conditions used. The nonlinear refractive index was calculated to be -1.459×10^-18 m²·W^-1 for the solution sample and -3.978×10^-15 m²·W^-1 for the film. These results suggest that this material is a promising candidate for application in nonlinear optical devices such as all-optical switching manufacture at 1064 nm.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

(苄基三乙基铵)双(1,3-二硫杂环戊烯-2-硫酮-4,5-二硫基)-金的三阶非线性光学性质

English

Third Order Nonlinear Optical Properties of Benzyltriethylamine Bis(2-thioxo-1,3-dithiole-4,5-dithiolato) Aurate(III)

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

(苄基三乙基铵)双(1,3-二硫杂环戊烯-2-硫酮-4,5-二硫基)-金的三阶非线性光学性质

English

Third Order Nonlinear Optical Properties of Benzyltriethylamine Bis(2-thioxo-1,3-dithiole-4,5-dithiolato) Aurate(III)

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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