HY分子筛为模板合成的微孔炭及其电化学电容性能

引用本文: 李文, 周晋, 邢伟, 禚淑萍, 吕忆民. HY分子筛为模板合成的微孔炭及其电化学电容性能[J]. 物理化学学报, 2011, 27(03): 620-626. doi: 10.3866/PKU.WHXB20110331 shu

Citation: LI Wen, ZHOU Jin, XING Wei, ZHUO Shu-Ping, Lü Yi-Min. Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance[J]. Acta Physico-Chimica Sinica, 2011, 27(03): 620-626. doi: 10.3866/PKU.WHXB20110331 shu

HY分子筛为模板合成的微孔炭及其电化学电容性能

基金项目:
山东省优秀中青年科学家科研奖励基金(BS2009NJ014) (BS2009NJ014)

山东省科技攻关项目(2009GG10007006)资助 (2009GG10007006)

摘要:

以HY分子筛为模板, 采用糠醇浸渍炭化法和糠醇浸渍-乙腈气相沉积炭化法制备了多种微孔炭材料, 分别标记为PFA系列和AN系列, 并研究了其电化学电容性能. X射线衍射(XRD)测试表明AN系列炭材料较好地复制了HY分子筛模板的孔结构有序性. X射线光电子能谱仪(XPS)测试表明, 乙腈气相沉积在炭材料中引入丰富的含氮官能团. 氮气吸附测试表明, 炭材料是典型的微孔材料, 具有较高的比表面积, 较窄的孔径分布范围. 电化学测试表明, AN系列炭材料电容性能较好, 并具有明显的赝电容, 其中AN8的比电容最大可达210 F·g^-1. AN系列炭材料的电容保持率与材料的导电性和介孔率有关.

关键词:

English

Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance

1.
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, Shandong Province, P. R. China
Received Date: 07 October 2010
Available Online: 03 March 2011
Fund Project:
山东省优秀中青年科学家科研奖励基金(BS2009NJ014)

山东省科技攻关项目(2009GG10007006)资助

Abstract:

Several microporous carbons were prepared by polyfurfuryl alcohol-impregnation and impregnation-acetonitrile chemical vapor deposition (CVD) using zeolite HY as a template, denoted as PFA carbons and AN carbons, respectively. These were used as electrode materials for supercapacitors. X-ray diffraction (XRD) patterns show that the structural regularity of the zeolite was well-replicated by the carbon structures prepared by impregnation-CVD. X-ray photoelectron spectroscopy (XPS) confirmed that the AN carbons possess abundant nitrogen-containing groups because of the CVD of acetonitrile. The prepared carbons were typical microporous materials as determined by N₂ adsorption/desorption test and they had a high BET surface area and narrow pore size distribution. Electrochemical tests showed that the AN carbons had higher capacitance because of their evident pseudo-capacitance from the nitrogen- containing groups. AN8 had a high capacitance up to 210 F·g^-1. The capacitance retention ratio of the AN carbons were determined to its electric conductivity and mesoporosity.

Key words:

1. [1]
  
  (1) Conway, B. E. Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications; Chemical Industry Press: Beijing, 2005; translated by Chen, A.; Wu, M. Q.; Zhang, X. L.; Gao, N. W.
  (1) Conway, B. E. Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications; Chemical Industry Press: Beijing, 2005; translated by Chen, A.; Wu, M. Q.; Zhang, X. L.; Gao, N. W.
2. [2]
  [Conway, B. E. 电化学超级电容器——科学原理及技术应用. 陈艾, 吴孟强, 张绪礼, 高能武译. 北京: 化学工业出版社, 2005.][Conway, B. E. 电化学超级电容器——科学原理及技术应用. 陈艾, 吴孟强, 张绪礼, 高能武译. 北京: 化学工业出版社, 2005.]
3. [3]
  (2) Aricò, A. S.; Bruce, P.; Scrosati, B.; Tarascon, J. M.; Van Schalkwijk, W. Nat. Mater. 2005, 4, 366.(2) Aricò, A. S.; Bruce, P.; Scrosati, B.; Tarascon, J. M.; Van Schalkwijk, W. Nat. Mater. 2005, 4, 366.
4. [4]
  (3) Pandolfo, A. G.; Hollenkamp, A. F. J. Power Sources 2006, 157, 11.(3) Pandolfo, A. G.; Hollenkamp, A. F. J. Power Sources 2006, 157, 11.
5. [5]
  (4) Liu, Y. L.; Li, L. X.; Chen, X. H.; Song, H. H. Acta Phys. -Chim. Sin. 2007, 23, 1399.(4) Liu, Y. L.; Li, L. X.; Chen, X. H.; Song, H. H. Acta Phys. -Chim. Sin. 2007, 23, 1399.
6. [6]
  [刘宇林, 李丽霞, 陈晓红, 宋怀河. 物理化学学报, 2007, 23, 1399.][刘宇林, 李丽霞, 陈晓红, 宋怀河. 物理化学学报, 2007, 23, 1399.]
7. [7]
  (5) Li, L. M.; Liu, E. H.; Li, J.; Yang, Y. J.; Shen, H. J.; Huang, Z. Z.; Xiang, X. X. Acta Phys. -Chim. Sin. 2010, 26, 1521.(5) Li, L. M.; Liu, E. H.; Li, J.; Yang, Y. J.; Shen, H. J.; Huang, Z. Z.; Xiang, X. X. Acta Phys. -Chim. Sin. 2010, 26, 1521.
8. [8]
  [李利民, 刘恩辉, 李剑, 杨艳静, 沈海杰, 黄铮铮, 向晓霞. 物理化学学报, 2010, 26, 1521.][李利民, 刘恩辉, 李剑, 杨艳静, 沈海杰, 黄铮铮, 向晓霞. 物理化学学报, 2010, 26, 1521.]
9. [9]
  (6) Ji, Q. Q.; Guo, P. Z.; Zhao. X. S. Acta Phys. -Chim. Sin. 2010, 26, 1254.(6) Ji, Q. Q.; Guo, P. Z.; Zhao. X. S. Acta Phys. -Chim. Sin. 2010, 26, 1254.
10. [10]
  [季倩倩, 郭培志, 赵修松. 物理化学学报, 2010, 26, 1254][季倩倩, 郭培志, 赵修松. 物理化学学报, 2010, 26, 1254]
11. [11]
  (7) Dillon, A. C.; Jones, K. M.; Bekkedahl, T. A.; Kiang, C. H.; Bethune, D. S.; Heben, M. J. Nature 1997, 386, 377.(7) Dillon, A. C.; Jones, K. M.; Bekkedahl, T. A.; Kiang, C. H.; Bethune, D. S.; Heben, M. J. Nature 1997, 386, 377.
12. [12]
  (8) Kang, M.; Yi, S. H.; Lee, H. I.; Yie, J. E.; Kim, J. M. Chem. Commun. 2002, 17, 1944.(8) Kang, M.; Yi, S. H.; Lee, H. I.; Yie, J. E.; Kim, J. M. Chem. Commun. 2002, 17, 1944.
13. [13]
  (9) Yang, Z.; Xia, Y.; Mokaya, R. Adv. Mater. 2004, 16, 1553.(9) Yang, Z.; Xia, Y.; Mokaya, R. Adv. Mater. 2004, 16, 1553.
14. [14]
  (10) Kyotani, T.; Nagai, T.; Inoue, S.; Tomita, A. Chem. Mater. 1997, 9, 609.(10) Kyotani, T.; Nagai, T.; Inoue, S.; Tomita, A. Chem. Mater. 1997, 9, 609.
15. [15]
  (11) Xing, W.; Qiao, S. Z.; Ding, R. G.; Li, F.; Lu, G. Q.; Yan, Z. F.; Cheng, H. M. Carbon 2006, 44, 216.(11) Xing, W.; Qiao, S. Z.; Ding, R. G.; Li, F.; Lu, G. Q.; Yan, Z. F.; Cheng, H. M. Carbon 2006, 44, 216.
16. [16]
  (12) Ryoo, R.; Joo, S. H.; Jun, S. J. J. Phys. Chem. B 1999, 103, 7743.(12) Ryoo, R.; Joo, S. H.; Jun, S. J. J. Phys. Chem. B 1999, 103, 7743.
17. [17]
  (13) Yuan, D. S.; Chen, J. X.; Tan, S. X.; Xia, N. N.; Liu, Y. L. Electrochem. Commun. 2009, 11, 1191.(13) Yuan, D. S.; Chen, J. X.; Tan, S. X.; Xia, N. N.; Liu, Y. L. Electrochem. Commun. 2009, 11, 1191.
18. [18]
  (14) Ma, Z. X.; Kyotani, T.; Liu, Z.; Terasaki, O.; Tomita, A. Chem. Mater. 2001, 13, 4413.(14) Ma, Z. X.; Kyotani, T.; Liu, Z.; Terasaki, O.; Tomita, A. Chem. Mater. 2001, 13, 4413.
19. [19]
  (15) Ma, Z. X.; Kyotani, T.; Tomita, A. Carbon 2002, 40, 2367.(15) Ma, Z. X.; Kyotani, T.; Tomita, A. Carbon 2002, 40, 2367.
20. [20]
  (16) Matsuoka, K.; Yamagishi, Y.; Yamazaki, T.; Setoyama, N.; Tomita, A.; Kyotani, T. Carbon 2005, 43, 876.(16) Matsuoka, K.; Yamagishi, Y.; Yamazaki, T.; Setoyama, N.; Tomita, A.; Kyotani, T. Carbon 2005, 43, 876.
21. [21]
  (17) Kyotani, T.; Ma, Z.; Tomita, A. Carbon 2003, 41, 1451.(17) Kyotani, T.; Ma, Z.; Tomita, A. Carbon 2003, 41, 1451.
22. [22]
  (18) Hou, P. X.; Orikasa, H.; Yamazaki, T.; Koichi, M.; Tomita ,A.; Setoyama, N.; Fukushima, Y.; Kyotani, T. Chem. Mater. 2005, 17, 5187.(18) Hou, P. X.; Orikasa, H.; Yamazaki, T.; Koichi, M.; Tomita ,A.; Setoyama, N.; Fukushima, Y.; Kyotani, T. Chem. Mater. 2005, 17, 5187.
23. [23]
  (19) Su, F.; Zhao, X. S.; Lv, L.; Zhou, Z. Carbon 2004, 42, 2821.(19) Su, F.; Zhao, X. S.; Lv, L.; Zhou, Z. Carbon 2004, 42, 2821.
24. [24]
  (20) Ania, C. O.; Khomenko, V.; Raymundo-Piñero, E.; Parra, J. B.; Bguin, F. Adv. Funct. Mater. 2007, 17, 1828.(20) Ania, C. O.; Khomenko, V.; Raymundo-Piñero, E.; Parra, J. B.; Bguin, F. Adv. Funct. Mater. 2007, 17, 1828.
25. [25]
  (21) Portet, C.; Yang, Z.; Korenblit, Y.; tsi, Y.; Mokaya, R.; Yushin, G. J. Electrochem. Soc. 2009, 156, A1-6.(21) Portet, C.; Yang, Z.; Korenblit, Y.; tsi, Y.; Mokaya, R.; Yushin, G. J. Electrochem. Soc. 2009, 156, A1-6.
26. [26]
  (22) Wang, H. L.; Gao, Q. M.; Hu, J.; Chen, Z. Carbon 2009, 47, 2259.(22) Wang, H. L.; Gao, Q. M.; Hu, J.; Chen, Z. Carbon 2009, 47, 2259.
27. [27]
  (23) Yang, Z. X.; Xia, Y. D.; Mokaya, R. Microporous Mesoporous Mat. 2005, 86, 69.(23) Yang, Z. X.; Xia, Y. D.; Mokaya, R. Microporous Mesoporous Mat. 2005, 86, 69.
28. [28]
  (24) Hulicova, D.; Kodama M.; Hatori H. Chem. Mater. 2006, 18, 2318.(24) Hulicova, D.; Kodama M.; Hatori H. Chem. Mater. 2006, 18, 2318.
29. [29]
  (25) Ra, E. J.; Raymundo-Pi?ero, E.; Lee, Y. H.; Béguin, F. Carbon 2009, 47, 2984.(25) Ra, E. J.; Raymundo-Pi?ero, E.; Lee, Y. H.; Béguin, F. Carbon 2009, 47, 2984.
30. [30]
  (26) MacDonald, D. D. Electrochim. Acta 2006, 51, 1376.
  (26) MacDonald, D. D. Electrochim. Acta 2006, 51, 1376.

扫一扫看文章

计量

PDF下载量: 1544
文章访问数: 2936
HTML全文浏览量: 8

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

HY分子筛为模板合成的微孔炭及其电化学电容性能

English

Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

HY分子筛为模板合成的微孔炭及其电化学电容性能

English

Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs