以硼氢化钠为还原剂化学镀镍的电化学研究

引用本文: 贾飞, 王周成. 以硼氢化钠为还原剂化学镀镍的电化学研究[J]. 物理化学学报, 2011, 27(03): 633-640. doi: 10.3866/PKU.WHXB20110302 shu

Citation: JIA Fei, WANG Zhou-Cheng. Electrochemical Study on Electroless Nickel Plating Using Sodium Borohydride as the Reductant[J]. Acta Physico-Chimica Sinica, 2011, 27(03): 633-640. doi: 10.3866/PKU.WHXB20110302 shu

以硼氢化钠为还原剂化学镀镍的电化学研究

贾飞 ,
王周成

基金项目:
国家自然科学基金(20573086)资助项目 (20573086)

摘要:

采用线性电位扫描伏安法研究了以硼氢化钠为还原剂的化学镀镍体系, 考查了镀液组成及工艺条件对化学镀镍硼阴、阳极过程的影响, 结果表明: 乙酸镍和硼氢化钠含量的提高分别促进了Ni²⁺的还原反应和BH₄^-的氧化反应; 乙二胺、氢氧化钠以及添加剂硫脲、糖精钠对阴、阳极反应均有不同程度的抑制作用, 同时添加剂中的硫元素加速了镍的氧化; 升高温度有利于阴、阳极反应的进行.

关键词:

English

Electrochemical Study on Electroless Nickel Plating Using Sodium Borohydride as the Reductant

JIA Fei ,
WANG Zhou-Cheng

1.
Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
Received Date: 23 September 2010
Available Online: 03 March 2011
Fund Project:
国家自然科学基金(20573086)资助项目

Abstract:

We studied electroless Ni-B plating with sodium borohydride as the reductant by linear sweep voltammetry. The effects of bath solution composition and operating conditions on the cathodic reduction and anodic oxidation were studied. Increases in the concentrations of nickel acetate and sodium borohydride accelerated the reduction of Ni²⁺ and the oxidation of BH₄^-, respectively. Ethylenediamine, sodium hydroxide, thiourea and saccharin sodium inhibited both the cathodic and anodic reactions to varying degrees. Additionally, sulfur in the additives promoted the dissolution of nickel. High temperature was beneficial to both the cathodic reduction and anodic oxidation.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

以硼氢化钠为还原剂化学镀镍的电化学研究

English

Electrochemical Study on Electroless Nickel Plating Using Sodium Borohydride as the Reductant

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

以硼氢化钠为还原剂化学镀镍的电化学研究

English

Electrochemical Study on Electroless Nickel Plating Using Sodium Borohydride as the Reductant

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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