Citation: CHEN Wei, DONG Xin-Fa, CHEN Zhi-Shan, CHEN Sheng-Zhou, LIN Wei-Ming. Effect of Fe3+ Doping on Photocatalytic Activity of K2La2Ti3O10 for Water Decomposition to Hydrogen under Visible Light[J]. Acta Physico-Chimica Sinica, 2009, 25(06): 1107-1110. doi: 10.3866/PKU.WHXB20090624
可见光下Fe3+掺杂对K2La2Ti3O10分解水制氢性能的影响
采用溶胶-凝胶法制备了Fe3+掺杂的Fe-K2La2Ti3O10光催化剂, 并通过X射线衍射(XRD)、紫外-可见漫反射(DRS)、X射线光电子能谱(XPS)等技术对其进行了表征和分析, 考察了不同掺杂量对K2La2Ti3O10的性质及光催化分解水制氢活性的影响. 结果表明, Fe-K2La2Ti3O10在400-650 nm范围内显示强吸收, 光谱响应扩展到可见光区(λ>400 nm), 掺杂Fe3+后, K2La2Ti3O10的可见光区的光催化制氢活性显著提高, 掺杂量为nFe/nTi=0.04时活性最佳, 当催化剂用量为0.1 g, 反应液为CH3OH(30 mL)+H2O(90 mL)时, 产氢量达到1.92 μmol·h-1, 为未掺杂时的4倍.
English
Effect of Fe3+ Doping on Photocatalytic Activity of K2La2Ti3O10 for Water Decomposition to Hydrogen under Visible Light
Undoped K2La2Ti3O10 and Fe3 + doped K2La2Ti3O10 samples were prepared by the sol-gel method and characterized by X-ray diffraction (XRD), UV-Vis diffuse reflectance spectra (DRS) and X-ray photoelectron spectroscopy (XPS). The effects of Fe3+ doping quantity on the properties and photocatalytic activity for hydrogen evolution were investigated. Results showed that Fe-doped K2La2Ti3O10 showed stronger absorption in the 400-650 nm range and this expanded to the visible light (λ>400 nm). Doping with Fe3+ raised the photocatalytic activity for hydrogen generation and the optimumamount of Fe3+ doping was found to be nFe/nTi=0.04. At this ratio and under visible light the rate of hydrogen evolution of Fe-K2La2Ti3O10 was 1.92 μmol·h-1 and this was 4 times higher than that of undoped K2La2Ti3O10 when 120 mL of reactive liquid (CH3OH(30 mL)+H2O(90 mL)) containing 0.1 g photocatalyst was used.
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Key words:
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Photocatalysis
- / Fe3+-doped
- / K2La2Ti3O10
- / Visible light
- / Water decomposition
- / Hydrogen
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