引用本文:
张秋禹, 严宝珍, 郭洪猷, 王作新, 徐广智. 用31P NMR研究硫代磷酸酯水解反应历程[J]. 物理化学学报,
1992, 8(02): 232-235.
doi:
10.3866/PKU.WHXB19920217
Citation: Zhang Qiu-Yu, Yan Bao-Zhen, Guo Hong-You, Wang Zuo-Xin, Xu Guang-Zhi. Studies on the Hydrolysis Mechanism of Thiophosphate by 31P NMR[J]. Acta Physico-Chimica Sinica, 1992, 8(02): 232-235. doi: 10.3866/PKU.WHXB19920217
Citation: Zhang Qiu-Yu, Yan Bao-Zhen, Guo Hong-You, Wang Zuo-Xin, Xu Guang-Zhi. Studies on the Hydrolysis Mechanism of Thiophosphate by 31P NMR[J]. Acta Physico-Chimica Sinica, 1992, 8(02): 232-235. doi: 10.3866/PKU.WHXB19920217
用31P NMR研究硫代磷酸酯水解反应历程
English
Studies on the Hydrolysis Mechanism of Thiophosphate by 31P NMR
Abstract:
~(31)P NMR spectra during the hydrolysis process of thiophosphate(A) ??? in neutral, acid and basic media were recorded. By analyzing the ~(31)P NMR date obtained, hydrolysis mechanism was confirmed. Information of hydrolysis rate in different media was also obtained. In addition, the solvent effects of ~(31)P NMR of thiophosphate were investigated in detail.
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Key words:
- Hydrolysis mechanism; 31P NMR; Thiophosphate
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