引用本文:
何勇, 熊轶嘉, 朱起鹤, 孔繁敖. 酞菁和卟啉分子的超快内转换和振动弛豫[J]. 物理化学学报,
1999, 15(07): 636-642.
doi:
10.3866/PKU.WHXB19990711
Citation: He Yong, Xiong Yi-Jia, Zhu Qi-He, Kong Fan-Ao. Ultrafast Internal Conversion and Vibrational Relaxation of Butylphthalocyanine and Tetraphenylporphyrin in Solution[J]. Acta Physico-Chimica Sinica, 1999, 15(07): 636-642. doi: 10.3866/PKU.WHXB19990711
Citation: He Yong, Xiong Yi-Jia, Zhu Qi-He, Kong Fan-Ao. Ultrafast Internal Conversion and Vibrational Relaxation of Butylphthalocyanine and Tetraphenylporphyrin in Solution[J]. Acta Physico-Chimica Sinica, 1999, 15(07): 636-642. doi: 10.3866/PKU.WHXB19990711
酞菁和卟啉分子的超快内转换和振动弛豫
English
Ultrafast Internal Conversion and Vibrational Relaxation of Butylphthalocyanine and Tetraphenylporphyrin in Solution
Abstract:
Ultrafast internal conversion (IC) and vibrational relaxation dynamics of electronically excited butylphthalocyanine (BuPc ) and tetra-phenylporpyrin (TPP ) molecules in solution are theoretically studied on the basis of the perturbative density operaor method and the transient linear susceptibility theory. Femtosecond time-resolved profile of fluorescence depetion is simulated with a single vibrational mode. The internal conversion, the vibrational relaxation and the solvation rate constants in electronically excited states are determined. The results show that the sharp peak of fluorescence depletion reflects primarily the internal conversion process from the S2 state to the S1 state of BuPc and TPP.IC occurs in a 200 fs time scale.
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