酸性介质中羧甲基纤维素钠在低碳钢表面的吸附和缓蚀作用

BAYOL E. GVRTEN A. A. DURSUN M. KAYAKIRILMAZ K.

引用本文: BAYOL E., GVRTEN A. A., DURSUN M., KAYAKIRILMAZ K.. 酸性介质中羧甲基纤维素钠在低碳钢表面的吸附和缓蚀作用[J]. 物理化学学报, 2008, 24(12): 2236-2242. doi: 10.1016/S1872-1508(08)60085-6 shu
Citation:  BAYOL E., GVRTEN A. A., DURSUN M., KAYAKIRILMAZ K.. Adsorption Behavior and Inhibition Corrosion Effect of Sodium Carboxymethyl Cellulose on Mild Steel in Acidic Medium[J]. Acta Physico-Chimica Sinica, 2008, 24(12): 2236-2242. doi: 10.1016/S1872-1508(08)60085-6 shu

酸性介质中羧甲基纤维素钠在低碳钢表面的吸附和缓蚀作用

摘要: The effect of sodiumcarboxymethyl cellulose (Na-CMC) on the corrosion behavior of mild steel in 1.0 mol·L-1 HCl solution has been investigated by using weight loss (WL) measurement, potentiodynamic polarization, linear polarization resistance (LPR), and electrochemical impedance spectroscopy (EIS) methods. These results showed that the inhibition efficiency of Na-CMC increased with increasing the inhibitor concentration. Potentiodynamic polarization studies revealed that the Na-CMC was a mixed type inhibitor in 1.0 mol·L-1 HCl. The adsorption of the inhibitor on mild steel surface has been found to obey the Langmuir isotherm. The effect of temperature on the corrosion behavior of mild steel in 1.0 mol·L -1 HCl with addition of 0.04% of Na-CMC has been studied in the temperature range of 298-328 K. The associated apparent activation energy (E*a) of corrosion reaction has been determined. Scanning electron microscopy (SEM) has been applied to investigate the surface morphology of mild steel in the absence and presence of the inhibitor molecules.

English

  • 加载中
计量
  • PDF下载量:  1891
  • 文章访问数:  3510
  • HTML全文浏览量:  47
文章相关
  • 发布日期:  2008-12-04
  • 收稿日期:  2008-06-12
  • 网络出版日期:  2008-10-09
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章