引用本文:
Qun LIU, Kocienski PHILIP. A NEW METHOD FOR THE PREPARATION OF PHENOLS AND ITS DERIVATIVES[J]. Chinese Chemical Letters,
1991, 2(5): 353-356.
Citation: Qun LIU, Kocienski PHILIP. A NEW METHOD FOR THE PREPARATION OF PHENOLS AND ITS DERIVATIVES[J]. Chinese Chemical Letters, 1991, 2(5): 353-356.
Citation: Qun LIU, Kocienski PHILIP. A NEW METHOD FOR THE PREPARATION OF PHENOLS AND ITS DERIVATIVES[J]. Chinese Chemical Letters, 1991, 2(5): 353-356.
A NEW METHOD FOR THE PREPARATION OF PHENOLS AND ITS DERIVATIVES
摘要:
α-Oxo ketene dithioacetals 2 via 1,2-nucleophilie addition by methallyl magnesium chloride afforded corresponding alcohols (3). Treated with water or methanol and catalyzed by Lewis acid, the alcohols 3 were converted regiospecifically to substituted phenols 5'or related phenol methyl ethers 5 respectively. This reaction is a novel approach to the synthesis of phenols and their derivatives starting from non-aromatic precursors.
English
A NEW METHOD FOR THE PREPARATION OF PHENOLS AND ITS DERIVATIVES
Abstract:
α-Oxo ketene dithioacetals 2 via 1,2-nucleophilie addition by methallyl magnesium chloride afforded corresponding alcohols (3). Treated with water or methanol and catalyzed by Lewis acid, the alcohols 3 were converted regiospecifically to substituted phenols 5'or related phenol methyl ethers 5 respectively. This reaction is a novel approach to the synthesis of phenols and their derivatives starting from non-aromatic precursors.
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