引用本文:
Lian Kun Jia, Li Xiang Gong, Wen Jiao Ji, Cheng You Kan. Synthesis of vegetable oil based polyol with cottonseed oil and sorbitol derived from natural source[J]. Chinese Chemical Letters,
2011, 22(11): 1289-1292.
doi:
10.1016/j.cclet.2011.05.043
Citation: Lian Kun Jia, Li Xiang Gong, Wen Jiao Ji, Cheng You Kan. Synthesis of vegetable oil based polyol with cottonseed oil and sorbitol derived from natural source[J]. Chinese Chemical Letters, 2011, 22(11): 1289-1292. doi: 10.1016/j.cclet.2011.05.043
Citation: Lian Kun Jia, Li Xiang Gong, Wen Jiao Ji, Cheng You Kan. Synthesis of vegetable oil based polyol with cottonseed oil and sorbitol derived from natural source[J]. Chinese Chemical Letters, 2011, 22(11): 1289-1292. doi: 10.1016/j.cclet.2011.05.043
Synthesis of vegetable oil based polyol with cottonseed oil and sorbitol derived from natural source
摘要:
In order to prepare the polyol with all bio-based components as raw materials, cottonseed oil was first epoxidized by peroxyformic acid generated in situ from hydrogen peroxide and formic acid, and the cottonseed oil based polyols with variable hydroxyl value were then prepared by the ring-opening of epoxidized cottonseed oil with sorbitol, which is a multi-functional hydroxyl compound derived from a natural source. The chemical structure of the products was characterized with FTIR analysis, and the residual epoxy oxygen content and hydroxyl value of the polyol versus the ring-opening time were investigated.
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关键词:
- Vegetable oil
- / Sorbitol
- / Polyol
- / Epoxidation
- / Ring opening reaction
English
Synthesis of vegetable oil based polyol with cottonseed oil and sorbitol derived from natural source
Abstract:
In order to prepare the polyol with all bio-based components as raw materials, cottonseed oil was first epoxidized by peroxyformic acid generated in situ from hydrogen peroxide and formic acid, and the cottonseed oil based polyols with variable hydroxyl value were then prepared by the ring-opening of epoxidized cottonseed oil with sorbitol, which is a multi-functional hydroxyl compound derived from a natural source. The chemical structure of the products was characterized with FTIR analysis, and the residual epoxy oxygen content and hydroxyl value of the polyol versus the ring-opening time were investigated.
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Key words:
- Vegetable oil
- / Sorbitol
- / Polyol
- / Epoxidation
- / Ring opening reaction
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