Synthesis and characterization of asymmetric substituted dicarbamates

Chao Zhao Peng Fei Yang Shun Ping Wang Jun Ying Li Tian Duo Li

引用本文: Chao Zhao,  Peng Fei Yang,  Shun Ping Wang,  Jun Ying Li,  Tian Duo Li. Synthesis and characterization of asymmetric substituted dicarbamates[J]. Chinese Chemical Letters, 2011, 22(10): 1167-1170. doi: 10.1016/j.cclet.2011.05.009 shu
Citation:  Chao Zhao,  Peng Fei Yang,  Shun Ping Wang,  Jun Ying Li,  Tian Duo Li. Synthesis and characterization of asymmetric substituted dicarbamates[J]. Chinese Chemical Letters, 2011, 22(10): 1167-1170. doi: 10.1016/j.cclet.2011.05.009 shu

Synthesis and characterization of asymmetric substituted dicarbamates

  • 基金项目:

    The authors are grateful for the financial support from the National Natural Science Foundation of China (No.20676074).

摘要: Several new asymmetric substituted dicarbamates were synthesized with a convenient route. Firstly, tolylene-2, 4-diisocyanate dimmer was obtained from monomer with tributylphosphine as catalyst. Then, the dimmer reacted with alcohol (R1OH) to prepare carbamate substituted uretidione. Finally, uretidione ring was opened and the released isocyanate reacted with another alcohol (R2OH, R1≠R2).

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  • 收稿日期:  2011-01-21
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