引用本文:
Ai Jun LI, Ji Cheng CHU, Hong Sheng GUO, Xue Qin ZHOU, Dong Zhi LIU. Stereoselective Addition of N-Alkylhydroxylamines to α,β-Unsaturated Nitro Compounds[J]. Chinese Chemical Letters,
2006, 17(7): 859-862.
Citation: Ai Jun LI, Ji Cheng CHU, Hong Sheng GUO, Xue Qin ZHOU, Dong Zhi LIU. Stereoselective Addition of N-Alkylhydroxylamines to α,β-Unsaturated Nitro Compounds[J]. Chinese Chemical Letters, 2006, 17(7): 859-862.
Citation: Ai Jun LI, Ji Cheng CHU, Hong Sheng GUO, Xue Qin ZHOU, Dong Zhi LIU. Stereoselective Addition of N-Alkylhydroxylamines to α,β-Unsaturated Nitro Compounds[J]. Chinese Chemical Letters, 2006, 17(7): 859-862.
Stereoselective Addition of N-Alkylhydroxylamines to α,β-Unsaturated Nitro Compounds
摘要:
N-Alkylhydroxylamines have been shown to undergo a stereospecific cis addition to 1-phenyl-2 -nitropropene compounds, whereas the corresponding O-alkylhydroxylamines give no diastereoselectivity. The concerted addition mechanism was provided to explain the difference.
English
Stereoselective Addition of N-Alkylhydroxylamines to α,β-Unsaturated Nitro Compounds
Abstract:
N-Alkylhydroxylamines have been shown to undergo a stereospecific cis addition to 1-phenyl-2 -nitropropene compounds, whereas the corresponding O-alkylhydroxylamines give no diastereoselectivity. The concerted addition mechanism was provided to explain the difference.
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