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两种马来二腈基二硫烯镍(Ⅲ)近红外吸收配合物的结构、磁和电化学性质

周宏 ,  于姗姗 ,  段海宝 ,  任小明

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引用本文: 周宏, 于姗姗, 段海宝, 任小明. 两种马来二腈基二硫烯镍(Ⅲ)近红外吸收配合物的结构、磁和电化学性质[J]. 无机化学学报, 2013, 29(7): 1375-1384. doi: 10.3969/j.issn.1001-4861.2013.00.239 shu
Citation:  ZHOU Hong, YU Shan-Shan, DUAN Hai-Bao, REN Xiao-Ming. Crystal Structure, Magnetic, Near-Infrared Absorption and Electrochemical Properties of Two [Ni(mnt)2]-Based Compounds[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1375-1384. doi: 10.3969/j.issn.1001-4861.2013.00.239 shu

两种马来二腈基二硫烯镍(Ⅲ)近红外吸收配合物的结构、磁和电化学性质

  • 基金项目:

    国家自然科学基金(No.21171097,21201103)资助项目。 (No.21171097,21201103)

摘要: 合成并表征了两种新的离子对化合物(BMIB)[(Ni(mnt)2]2 (1)和(BMIO)[(Ni(mnt)2)]2 (2)(其中mnt2-=马来二氰基二硫烯,BMIB=1,4-bis(1-methylimidazolium)butane,BMIO=1,8-bis(1-methylimidazolium)octane)。在化合物1中,[Ni(mnt)2]-阴离子排列形成阴离子三聚体以及与阳离子交替排列形成阴、阳离子混合柱。化合物2的堆积结构与化合物1不同,阴、阳离子堆积成非等间距的阴、阳离子柱。化合物1和2分别在861和857 nm近红外波段处出现较强的近红外吸收。电化学性质研究结果表明,2个化合物均出现了两对不可逆的电化学氧化/还原过程,且平衡阳离子的烷基链长显著影响化合物的氧化、还原电极电势。变温磁化率测量表明,在2~400 K温度范围内,化合物1表现出弱的顺磁性质,变温摩尔磁化率遵循简单的Curie-Weiss定律。化合物2表现出低维反铁磁交换自旋体系磁化率特征。

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  • 收稿日期:  2012-08-06
  • 网络出版日期:  2013-04-05
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