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3-羧基苯氧乙酸根及邻菲咯啉构筑的钕(Ⅲ)配位聚合物的合成、晶体结构及磁性质

顾金忠 ,  邵永亮 ,  朱孔阳

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引用本文: 顾金忠, 邵永亮, 朱孔阳. 3-羧基苯氧乙酸根及邻菲咯啉构筑的钕(Ⅲ)配位聚合物的合成、晶体结构及磁性质[J]. 无机化学学报, 2013, 29(7): 1480-1484. doi: 10.3969/j.issn.1001-4861.2013.00.223 shu
Citation:  GU Jin-Zhong, SHAO Yong-Liang, ZHU Kong-Yang. Synthesis, Crystal Structure and Magnetic Properties of a Nd(Ⅲ) Coordination Polymer Constructed by 3-Carboxyphenoxyacetate and 1,10-Phenanthroline[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1480-1484. doi: 10.3969/j.issn.1001-4861.2013.00.223 shu

3-羧基苯氧乙酸根及邻菲咯啉构筑的钕(Ⅲ)配位聚合物的合成、晶体结构及磁性质

  • 基金项目:

    国家自然科学基金(No.21071068)资助项目。 (No.21071068)

摘要: 在水热反应条件下,采用3-羧基苯氧乙酸(3-H2CPOA=3-carboxyphenoxyacetatic acid)和phen (phen=1,10-phenanthroline)与NdCl3·6H2O反应,合成了1个具有三维结构的配位聚合物[Nd(3-CPOA)1.5(phen)]n (1),并对其结构和磁性质进行了研究。结构分析结果表明该聚合物的晶体属于单斜晶系,P21/c空间群。2个钕(Ⅲ)离子、3个3-CPOA2-配体和2个phen配体形成了1个[Nd2(3-CPOA)3(phen)2]双核轮状结构单元,这些双核单元通过钕(Ⅲ)离子与3-CPOA2-配体的配位作用形成了1个三维框架结构。磁性研究表明,该聚合物中相邻的钕(Ⅲ)离子之间存在很强的反铁磁相互作用。

English

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  • 收稿日期:  2012-02-16
  • 网络出版日期:  2013-01-31
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