注册 English

带有水簇(H2O)4的四氰合镍配合物的合成与磁性研究

崔红霞

downloadPDF
引用本文: 崔红霞. 带有水簇(H2O)4的四氰合镍配合物的合成与磁性研究[J]. 无机化学学报, 2013, 29(7): 1485-1489. doi: 10.3969/j.issn.1001-4861.2013.00.217 shu
Citation:  CUI Hong-Xia. Synthesis and Magnetic Property of a Novel Tetracyanonickelate(Ⅱ) Complex with Discrete Water Cluster (H2O)4[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1485-1489. doi: 10.3969/j.issn.1001-4861.2013.00.217 shu

带有水簇(H2O)4的四氰合镍配合物的合成与磁性研究

摘要: 一个四氰合镍配合物{[Ni(i-Pr3TACN)][Ni(CN)4]}2·2H2O(1)通过K2[Ni(CN)4]和[NiPr3TACN]Cl2自组装的方法合成,单晶解析表明其配合物中存在一个由4个分子水组成的水簇。4个水分子在一个平面上,每个水分子即是氢键的给体也是氢键的受体。磁化率测定表明配合物中Ni(Ⅱ)间为反铁磁作用且J值为-1.09 cm-1.

English

  • 

    1. [1] Zhao C C, Ni W W, Tao J, et al. CrystEngComm., 2009,11: 632-637[1] Zhao C C, Ni W W, Tao J, et al. CrystEngComm., 2009,11: 632-637

    2. [2] Itaya K, Uchida I, Neff V D. Acc. Chem. Res., 1986,19:162-168[2] Itaya K, Uchida I, Neff V D. Acc. Chem. Res., 1986,19:162-168

    3. [3] Dunbar K R, Heintz R A. Prog. Inorg. Chem., 1997,45:283-391[3] Dunbar K R, Heintz R A. Prog. Inorg. Chem., 1997,45:283-391

    4. [4] Verdaguer M, Bleuzen A, Marvaud V, et al. Coord. Chem. Rev., 1999,223:90-192[4] Verdaguer M, Bleuzen A, Marvaud V, et al. Coord. Chem. Rev., 1999,223:90-192

    5. [5] Orendac M, Potocnak I, Chomic J, et al. Coord. Chem. Rev., 2002,224:51-66[5] Orendac M, Potocnak I, Chomic J, et al. Coord. Chem. Rev., 2002,224:51-66

    6. [6] Bozoglian F, Macpherson B P, Martinez M. Coord. Chem. Rev., 2005,249:1902-1916[6] Bozoglian F, Macpherson B P, Martinez M. Coord. Chem. Rev., 2005,249:1902-1916

    7. [7] Olha S, Antonia N, Fritz S, et al. Cryst. Growth Des., 2008,8:3380-3384[7] Olha S, Antonia N, Fritz S, et al. Cryst. Growth Des., 2008,8:3380-3384

    8. [8] Tanase S, Reedijk J. Coord. Chem. Rev., 2006,250:2501-2510[8] Tanase S, Reedijk J. Coord. Chem. Rev., 2006,250:2501-2510

    9. [9] Chapman K W, Southon P D, Weeks C L, et al. Chem. Commun., 2005,3322-3324[9] Chapman K W, Southon P D, Weeks C L, et al. Chem. Commun., 2005,3322-3324

    10. [10] Kaye S S, Long J R. J. Am. Chem. Soc., 2005,127:6506-6507[10] Kaye S S, Long J R. J. Am. Chem. Soc., 2005,127:6506-6507

    11. [11] Ali M, Ray A, Sheldrick W S, et al. New. J. Chem., 2004, 28:412-417[11] Ali M, Ray A, Sheldrick W S, et al. New. J. Chem., 2004, 28:412-417

    12. [12] Maji T K, Mukherjee P S, Mostafa G, et al. Chem. Commun., 2001:1368-1370[12] Maji T K, Mukherjee P S, Mostafa G, et al. Chem. Commun., 2001:1368-1370

    13. [13] Dunbar K R, Heintz R A. Prog. Inorg. Chem., 1997,45:282-391[13] Dunbar K R, Heintz R A. Prog. Inorg. Chem., 1997,45:282-391

    14. [14] Gu Z Z, Sato O, Tyoda T, et al. Chem. Mater., 1997,9:1092-1097[14] Gu Z Z, Sato O, Tyoda T, et al. Chem. Mater., 1997,9:1092-1097

    15. [15] Miller J S, Epstein A J (Eds.). MRS Bull., 2000:21[15] Miller J S, Epstein A J (Eds.). MRS Bull., 2000:21

    16. [16] Yet L. Angew. Chem. Int. Ed., 2001,40:875-877[16] Yet L. Angew. Chem. Int. Ed., 2001,40:875-877

    17. [17] Cernak J, Chomic J, Baloghova D, et al. Acta Cryst. C, 1988,44:1902-1905[17] Cernak J, Chomic J, Baloghova D, et al. Acta Cryst. C, 1988,44:1902-1905

    18. [18] Cernak J, Chomic J, Domiano P, et al. Acta Cryst. C, 1990,46:2103-2107[18] Cernak J, Chomic J, Domiano P, et al. Acta Cryst. C, 1990,46:2103-2107

    19. [19] Gainsford G J, Curtis N F. Aust. J. Chem., 1984,37:1799-1816[19] Gainsford G J, Curtis N F. Aust. J. Chem., 1984,37:1799-1816

    20. [20] Cernak J, Abboud K A. Acta Cryst. C, 2000,56:783-785[20] Cernak J, Abboud K A. Acta Cryst. C, 2000,56:783-785

    21. [21] Zhan S Z, Guo D, Zhang X Y, et al. Inorg. Chim. Acta, 2000,298:57-62[21] Zhan S Z, Guo D, Zhang X Y, et al. Inorg. Chim. Acta, 2000,298:57-62

    22. [22] Kou H Z, Liao D Z, Jiang Z H, et al. Inorg. Chem. Commun., 2000,3:151-154[22] Kou H Z, Liao D Z, Jiang Z H, et al. Inorg. Chem. Commun., 2000,3:151-154

    23. [23] Kou H Z, Si S F, Gao S. Eur. J. Inorg. Chem., 2002,151: 699-702[23] Kou H Z, Si S F, Gao S. Eur. J. Inorg. Chem., 2002,151: 699-702

    24. [24] Long L S, Wu Y R, et al. Inorg. Chem., 2004,43:3798-3800[24] Long L S, Wu Y R, et al. Inorg. Chem., 2004,43:3798-3800

    25. [25] Cruzan J, Braly L B, Liu K. Science, 1996,271:59-62[25] Cruzan J, Braly L B, Liu K. Science, 1996,271:59-62

    26. [26] Xantheas S S. J. Chem. Phys., 1994,100:7523-7535[26] Xantheas S S. J. Chem. Phys., 1994,100:7523-7535

    27. [27] Xantheas S S. J. Chem. Phys., 1995,102:4505-4518[27] Xantheas S S. J. Chem. Phys., 1995,102:4505-4518

    28. [28] Ugalde J M, Alkorta I, Elguero J. Angew. Chem. Int. Ed., 2000,39:717-721[28] Ugalde J M, Alkorta I, Elguero J. Angew. Chem. Int. Ed., 2000,39:717-721

    29. [29] Gregory J K, Clary D C. J. Phys. Chem., 1996,100:18014-18022[29] Gregory J K, Clary D C. J. Phys. Chem., 1996,100:18014-18022

    30. [30] Hay R W, Norman P R. J. Chem. Soc., Dalton. Trans., 1979: 1441-1445[30] Hay R W, Norman P R. J. Chem. Soc., Dalton. Trans., 1979: 1441-1445

    31. [31] White D W, Karcher B A, Jacobson R A, et al. J. Am. Chem. Soc., 1979,101:4921-4925[31] White D W, Karcher B A, Jacobson R A, et al. J. Am. Chem. Soc., 1979,101:4921-4925

    32. [32] Chen G J, Gao F X, Huang F P, et al. Cryst. Growth Des., 2009,9:2662-2667[32] Chen G J, Gao F X, Huang F P, et al. Cryst. Growth Des., 2009,9:2662-2667

    33. [33] Sheldrick G M. SADABS: Program for Empirical Absorption Correction of Area Detector Data, University of Gttingen, Germany, 1996[33] Sheldrick G M. SADABS: Program for Empirical Absorption Correction of Area Detector Data, University of Gttingen, Germany, 1996

    34. [34] Sheldrick G M. SHELXS-97, Program for the Solutionof Crystal Stuctures, University of Gttingen, 1997[34] Sheldrick G M. SHELXS-97, Program for the Solutionof Crystal Stuctures, University of Gttingen, 1997

    35. [35] Sheldrick G M. SHELXS-97, Program for the Refinement of Crystal Structures, University of Gttingen, 1997[35] Sheldrick G M. SHELXS-97, Program for the Refinement of Crystal Structures, University of Gttingen, 1997

    36. [36] Sariego R, Costamagna J A. J. Inorg. Nucl. Chem., 1971,33: 1528-1532[36] Sariego R, Costamagna J A. J. Inorg. Nucl. Chem., 1971,33: 1528-1532

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  531
  • HTML全文浏览量:  37
文章相关
  • 收稿日期:  2012-04-23
  • 网络出版日期:  2013-03-04
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net