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以5-甲基-3-吡唑甲酸为配体构建的具有六方孔道的钴(Ⅱ)、镍(Ⅱ)超分子化合物：合成、晶体结构和性质

包金婷 ,  程美令 ,  刘琦 ,  韩伟 ,  纪云洲 ,  翟长伟 ,  洪健 ,  孙小强

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引用本文: 包金婷, 程美令, 刘琦, 韩伟, 纪云洲, 翟长伟, 洪健, 孙小强. 以5-甲基-3-吡唑甲酸为配体构建的具有六方孔道的钴(Ⅱ)、镍(Ⅱ)超分子化合物：合成、晶体结构和性质[J]. 无机化学学报, 2013, 29(7): 1504-1512. doi: 10.3969/j.issn.1001-4861.2013.00.215 shu
Citation:  BAO Jin-Ting, CHENG Mei-Ling, LIU Qi, HAN Wei, JI Yun-Zhou, ZHAI Chang-Wei, HONG Jian, SUN Xiao-Qiang. Cobalt and Nickel Supramolecular Complexes with Hexagonal Channels Constructed from 5-Methyl-1H-Pyrazole-3-Carboxylic Acid：Synthesis, Crystal Structures and Properties[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1504-1512. doi: 10.3969/j.issn.1001-4861.2013.00.215 shu

以5-甲基-3-吡唑甲酸为配体构建的具有六方孔道的钴(Ⅱ)、镍(Ⅱ)超分子化合物：合成、晶体结构和性质

  • 基金项目:

    国家自然科学基金(No.20971060 

    南京大学配位化学国家重点实验室开放基金 

    江苏高校优势学科建设工程资助项目。 

摘要: 利用5-甲基-3-吡唑甲酸,分别与CoCl2·6H2O和Ni(NO3)2·6H2O反应,得到了配合物[M(MPA)2(H2O)2](1:M=Co;2:M=Ni)(HMPA=5-甲基-3-吡唑甲酸)。用元素分析、红外光谱、X-单晶衍射结构分析对其进行了表征。配合物1和2的晶体结构参数如下:配合物1和2的晶体都属于六方晶系,空间群为R3c。配合物1的晶胞参数为a=1.483 94(4) nm,b=1.483 94(4) nm,c= 3.207 66(6) nm,V=6.117 2(3) nm3,Z=18;配合物2的晶胞参数为a=1.466 53(14) nm,b=1.466 53(14) nm,c=3.243 0(6) nm,V= 6.04 03(14) nm3,Z=18。金属离子与来自2个5-甲基-3-吡唑甲酸配体中的2个氮原子及2个氧原子,2个水分子中的2个氧原子配位,形成八面体配位构型。配合物中的独立结构单元[M(MPA)2(H2O)2]通过分子间氢键形成具有六方孔道的三维结构。热重分析表明配合物1和2具有较高的热稳定性。此外, 考察了配合物1和2的荧光和电化学性质。CCDC: 900677,1;900678,2。

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  • 收稿日期:  2012-11-26
  • 网络出版日期:  2013-02-25
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