二(咪唑基)苯及戊二酸根构筑的三维镉配位聚合物的合成、晶体结构与荧光性质

引用本文: 卞常鑫, 王璞玉, 宋玉民, 姚小强. 二(咪唑基)苯及戊二酸根构筑的三维镉配位聚合物的合成、晶体结构与荧光性质[J]. 无机化学学报, 2013, 29(7): 1369-1374. doi: 10.3969/j.issn.1001-4861.2013.00.205 shu

Citation: BIAN Chang-Xin, WANG Pu-Yu, SONG YU-Min, YAO Xiao-Qiang. Synthesis, Crystal Structure and Photoluminescence Property of a 3D Coordination Polymer [Cd(BIMB)_0.5(glu)]_n Constructed by 1,4-Bis(imidazol-1-yl)benzene and Glutaric Acid[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1369-1374. doi: 10.3969/j.issn.1001-4861.2013.00.205 shu

二(咪唑基)苯及戊二酸根构筑的三维镉配位聚合物的合成、晶体结构与荧光性质

基金项目:
国家自然科学基金(No.21062017) (No.21062017)

甘肃省教育厅(110105) (110105)

甘肃省高分子材料重点实验室资助项目。

摘要: 用水热法合成了一个新的镉配位聚合物[Cd(BIMB)_0.5(glu)]_n(BIMB=1,4-二(咪唑基)苯,H₂glu=戊二酸),用红外,元素分析进行了表征。X射线单晶衍射分析表明配位聚合物属于单斜晶系,P2₁/c空间群,a=0.822 06(5) nm,b=0.774 38(5) nm,c=1.877 93(10) nm,β=107.966°,V=1.137 nm³,Z=4,F(000)=684。在配合物中,相邻的镉原子通过2个戊二酸连接成一维链状结构,链状结构通过另一戊二酸拓展成二维层状结构,相邻二维层状结构进一步由BIMB配体拓展成三维骨架结构。热重分析表明配合物具有较好的稳定性,荧光光谱分析表明配合物具有较好的荧光性质。

关键词:

戊二酸;1,4-二(咪唑基)苯;晶体结构;荧光性质

English

Synthesis, Crystal Structure and Photoluminescence Property of a 3D Coordination Polymer [Cd(BIMB)_0.5(glu)]_n Constructed by 1,4-Bis(imidazol-1-yl)benzene and Glutaric Acid

1.
Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China
Received Date: 03 November 2012
Fund Project:
国家自然科学基金(No.21062017)

甘肃省教育厅(110105)

甘肃省高分子材料重点实验室资助项目。

Abstract: A new complex [Cd(BIMB)_0.5(glu)]_n based on rigid ligand BIMB (BIMB=1,4-bis(imidazol-1-yl)benzene) and flexible ligand H₂glu (H₂glu=glutaric acid) has been synthesized by hydrothermal method and characterized by IR and elemental analysis. The complex crystallizes in the monoclinic system P2₁/c space group, a=0.822 06(5) nm,b=0.774 38(5) nm, c=1.877 93(10) nm, β=107.966°, V=1.137 nm³, Z=4, F(000)=684. In complex, the adjacent Cd(Ⅱ) atoms are connected by two glu^2-ligands to result in 1D chains, which are further linked by another glu^2-ligand to generate a 2D layers, and the adjacent 2D layers are linked by BIMB ligand to result in a 3D framework. The TGA analysis shows the complex has good thermal stability. The fluorescence analysis reveals the complex has good fluorescence property. CCDC: 891527.

Key words:

glutaric acid;1,4-bis(1-imidazolyl)-benzene;crystal structure;fluorescence property

1. [1] Long J R, Yaghi O M. Chem. Soc. Rev., 2009,38(5):1213-1214[1] Long J R, Yaghi O M. Chem. Soc. Rev., 2009,38(5):1213-1214
2. [2] Ma D Y, Wang W X, Li Y W, et al. CrystEngComm, 2010,12 (12):4372-4377[2] Ma D Y, Wang W X, Li Y W, et al. CrystEngComm, 2010,12 (12):4372-4377
3. [3] Sun L P, Niu S Y, Jin J, et al. Inorg. Chem. Commun., 2006,9(7):679-682[3] Sun L P, Niu S Y, Jin J, et al. Inorg. Chem. Commun., 2006,9(7):679-682
4. [4] HUANG Yan-Ju(黄艳菊), NI Liang(倪良). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011,27(8):1649-1643[4] HUANG Yan-Ju(黄艳菊), NI Liang(倪良). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011,27(8):1649-1643
5. [5] Li Z X, Zeng Y F, Ma H, et al. Chem. Commun., 2010,46 (45):8540-8542[5] Li Z X, Zeng Y F, Ma H, et al. Chem. Commun., 2010,46 (45):8540-8542
6. [6] XIE Jing(谢静),CHEN Xuan(陈轩),SUN Wei-Yin(孙为银). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2007,23(7): 1295-1298[6] XIE Jing(谢静),CHEN Xuan(陈轩),SUN Wei-Yin(孙为银). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2007,23(7): 1295-1298
7. [7] Chu Q, Su Z, Sun W Y, et al. Cryst.Growth Des., 2011,11 (9):3885-3894[7] Chu Q, Su Z, Sun W Y, et al. Cryst.Growth Des., 2011,11 (9):3885-3894
8. [8] Li Z X, Xu Y, Zuo Y, et al. Cryst. Growth Des., 2009,9(9): 3904-3909[8] Li Z X, Xu Y, Zuo Y, et al. Cryst. Growth Des., 2009,9(9): 3904-3909
9. [9] Li Z X, Hu T L, Ma H, et al. Cryst. Growth Des., 2010,10(3): 1138-1144[9] Li Z X, Hu T L, Ma H, et al. Cryst. Growth Des., 2010,10(3): 1138-1144
10. [10] Qi Y, Che Y X, Zheng J M, et al. Cryst. Growth Des., 2008,8 (10):3602-3608[10] Qi Y, Che Y X, Zheng J M, et al. Cryst. Growth Des., 2008,8 (10):3602-3608
11. [11] Yang G S, Lan Y Q, Zang H Y, CrystEngComm, 2009,11(2): 274-277[11] Yang G S, Lan Y Q, Zang H Y, CrystEngComm, 2009,11(2): 274-277
12. [12] Xu J, Bai Z S, Sun W Y, et al. CrystEngComm, 2009,11 (12):2728-2733[12] Xu J, Bai Z S, Sun W Y, et al. CrystEngComm, 2009,11 (12):2728-2733
13. [13] Georges M, Nans R, Abdellah K, CrystEngComm, 2010,12 (12):496-3498[13] Georges M, Nans R, Abdellah K, CrystEngComm, 2010,12 (12):496-3498
14. [14] Yang G S, Zang H Y, Lan Y Q, CrystEngComm, 2011,13(5): 461-1466[14] Yang G S, Zang H Y, Lan Y Q, CrystEngComm, 2011,13(5): 461-1466
15. [15] Li Y W, Ma H, Chen Y Q, Cryst. Growth Des., 2012,12(1): 189-196[15] Li Y W, Ma H, Chen Y Q, Cryst. Growth Des., 2012,12(1): 189-196
16. [16] Fan J, Hanson B E. Chem. Commun., 2005,5(18):2327-2329[16] Fan J, Hanson B E. Chem. Commun., 2005,5(18):2327-2329
17. [17] Sheldrick G M. SHELXS-97 and SHELXL-97, University of Göttingen, 1997.[17] Sheldrick G M. SHELXS-97 and SHELXL-97, University of Göttingen, 1997.
18. [18] Dong Y B, Jin G X, Smith M D, et al. Inorg. Chem., 2002, 41(19):4909-4914[18] Dong Y B, Jin G X, Smith M D, et al. Inorg. Chem., 2002, 41(19):4909-4914

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

二(咪唑基)苯及戊二酸根构筑的三维镉配位聚合物的合成、晶体结构与荧光性质

English

Synthesis, Crystal Structure and Photoluminescence Property of a 3D Coordination Polymer [Cd(BIMB)_0.5(glu)]_n Constructed by 1,4-Bis(imidazol-1-yl)benzene and Glutaric Acid

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

二(咪唑基)苯及戊二酸根构筑的三维镉配位聚合物的合成、晶体结构与荧光性质

English

Synthesis, Crystal Structure and Photoluminescence Property of a 3D Coordination Polymer [Cd(BIMB)0.5(glu)]n Constructed by 1,4-Bis(imidazol-1-yl)benzene and Glutaric Acid

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Synthesis, Crystal Structure and Photoluminescence Property of a 3D Coordination Polymer [Cd(BIMB)_0.5(glu)]_n Constructed by 1,4-Bis(imidazol-1-yl)benzene and Glutaric Acid

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs