以取代三联吡啶及钒氧酸为配体的一维带状化合物[Co(DMPhTPY)V2O6]n的合成、晶体结构及性质研究

引用本文: 杨浩, 陈建国, 冯玉全, 包晓玉, 孙汝中. 以取代三联吡啶及钒氧酸为配体的一维带状化合物[Co(DMPhTPY)V₂O₆]_n的合成、晶体结构及性质研究[J]. 无机化学学报, 2013, 29(7): 1454-1458. doi: 10.3969/j.issn.1001-4861.2013.00.203 shu

Citation: YANG Hao, CHEN Jian-Guo, FENG Yu-Quan, BAO Xiao-Yu, SUN Ru-Zhong. Synthesis, Crystal Structure and Properties of 1D Ribbon-Like Complex [Co(DMPhTPY)V₂O₆]_n with Substituted Terpyridine and Polyoxovanadate Ligand[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1454-1458. doi: 10.3969/j.issn.1001-4861.2013.00.203 shu

以取代三联吡啶及钒氧酸为配体的一维带状化合物[Co(DMPhTPY)V₂O₆]_n的合成、晶体结构及性质研究

基金项目:
河南省科技厅自然科学基金(No.112300410189)资助项目。 (No.112300410189)

摘要: 利用水热反应合成一种新型一维带状配位聚合物[Co(DMPhTPY)V₂O₆]_n (DMPhTPY=6,6"-二甲基-4'-苯基-2,2':6',2"-三联吡啶)。用元素分析、红外光谱和X-射线单晶衍射对其结构进行了表征,该配合物晶体属三斜晶系,P1空间群。同时测定了配合物的热稳定性、荧光性质和磁性质。结果表明,配合物具有较强的热稳定性,钴(Ⅱ)离子间存在反铁磁交换耦合相互作用。

关键词:

水热合成;配位聚合物;晶体结构;热稳定性;发光性质;磁性质

English

1. [1] Meng Q H, Clegg J C, Jolliffe K A, et al. J. Inorg. Chem. Commun., 2010,13:558-562[1] Meng Q H, Clegg J C, Jolliffe K A, et al. J. Inorg. Chem. Commun., 2010,13:558-562
2. [2] Lee J, Farha O K, Roberts J, et al. Chem. Soc. Rev., 2009, 38:1450-1459[2] Lee J, Farha O K, Roberts J, et al. Chem. Soc. Rev., 2009, 38:1450-1459
3. [3] Li J R, Kuppler R J, Zhou H C. Chem. Soc. Rev., 2009,38: 1477-1504[3] Li J R, Kuppler R J, Zhou H C. Chem. Soc. Rev., 2009,38: 1477-1504
4. [4] Strrb C, Ritchie C, Long D, et al. J. Angew. Chem. Int. Ed., 2007,46(40):7579-7582[4] Strrb C, Ritchie C, Long D, et al. J. Angew. Chem. Int. Ed., 2007,46(40):7579-7582
5. [5] Park K S, Zheng N, Cote A P, et al. J. PANS, 2006,103(27): 10186-10191[5] Park K S, Zheng N, Cote A P, et al. J. PANS, 2006,103(27): 10186-10191
6. [6] Zhou Y Z, Qiao H P. J. Inorg. Chem. Commun., 2007,10: 1318-1320[6] Zhou Y Z, Qiao H P. J. Inorg. Chem. Commun., 2007,10: 1318-1320
7. [7] Chen L J, He X, Xia C K, et al. J. Crystal Growth Design, 2006,6(9):2076-2085[7] Chen L J, He X, Xia C K, et al. J. Crystal Growth Design, 2006,6(9):2076-2085
8. [8] Ouellette W, Burkholder E, Manzar S, et al. J. Solid State Sciences, 2004,6:77-84[8] Ouellette W, Burkholder E, Manzar S, et al. J. Solid State Sciences, 2004,6:77-84
9. [9] Whittingham M S. J. Electrochem. Soc., 1976,123:315-318[9] Whittingham M S. J. Electrochem. Soc., 1976,123:315-318
10. [10] Whittingham M S, Song Y, Lutta S, et al. J. Mater. Chem., 2005,15:3362-3379[10] Whittingham M S, Song Y, Lutta S, et al. J. Mater. Chem., 2005,15:3362-3379
11. [11] Li W, Dahn J R, Wainwright D S. Science, 1994,264:1115-1117[11] Li W, Dahn J R, Wainwright D S. Science, 1994,264:1115-1117
12. [12] Cento G, Trifiro F. J. Appl. Catal. A, 1996,143:3-16[12] Cento G, Trifiro F. J. Appl. Catal. A, 1996,143:3-16
13. [13] Vejiux A, Courtini P. J. Solid State Chem., 1986,63:179-184[13] Vejiux A, Courtini P. J. Solid State Chem., 1986,63:179-184
14. [14] Allionetti S, Cavani F, Trifiro F. Catal. Rev. Sci. Eng., 1996,38:413-418[14] Allionetti S, Cavani F, Trifiro F. Catal. Rev. Sci. Eng., 1996,38:413-418
15. [15] Qi Y J, Wang Y H, Li H M, et al. J. Mol. Struct., 2003,650: 123-129[15] Qi Y J, Wang Y H, Li H M, et al. J. Mol. Struct., 2003,650: 123-129
16. [16] Qi Y J, Yang Y L, Cao M H, et al. J. Mol. Struct., 2003, 648:191-201[16] Qi Y J, Yang Y L, Cao M H, et al. J. Mol. Struct., 2003, 648:191-201
17. [17] Yucesan G, Gabriel N, Zubieta J. Inorg. Chim. Acta, 2006, 359:4557-4564[17] Yucesan G, Gabriel N, Zubieta J. Inorg. Chim. Acta, 2006, 359:4557-4564
18. [18] Devi R N, Rabu P, Golub V O, et al. J. Solid State Sciences, 2002,4:1095-1102[18] Devi R N, Rabu P, Golub V O, et al. J. Solid State Sciences, 2002,4:1095-1102
19. [19] Hagrman P J, Bridges C, Greedan J E, et al. J. Chem. Soc. Dalton Trans., 1999:2901-2903[19] Hagrman P J, Bridges C, Greedan J E, et al. J. Chem. Soc. Dalton Trans., 1999:2901-2903
20. [20] Yan B, Olmstead M M, Maggard P A. J. Am. Chem. Soc., 2007,129:12646-12647[20] Yan B, Olmstead M M, Maggard P A. J. Am. Chem. Soc., 2007,129:12646-12647
21. [21] YANG Hao(杨浩), CHEN Wen-Tao(陈文涛), FENG Yu-Quan(冯玉泉), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(1):62-66[21] YANG Hao(杨浩), CHEN Wen-Tao(陈文涛), FENG Yu-Quan(冯玉泉), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(1):62-66
22. [22] QIU Dong-Fang(邱东方), ZHAO Qian(赵茜), YANG Hao(杨浩), et al. Chinese J. Anal. Chem.(Fenxi Huaxue), 2002,30 (2):175-177[22] QIU Dong-Fang(邱东方), ZHAO Qian(赵茜), YANG Hao(杨浩), et al. Chinese J. Anal. Chem.(Fenxi Huaxue), 2002,30 (2):175-177
23. [23] YANG Hao(杨浩), LIU Jian-Chao(刘建超), BAO Xiao-Yu (包晓玉), et al. Acta Chim. Sinica(Huaxue Xuebao), 2010, 68(6):508-514[23] YANG Hao(杨浩), LIU Jian-Chao(刘建超), BAO Xiao-Yu (包晓玉), et al. Acta Chim. Sinica(Huaxue Xuebao), 2010, 68(6):508-514
24. [24] YANG Hao(杨浩), LIU Dong(刘东), WANG De-Fen(王德粉), et al. Chinese J. Synth. Chem.(Hecheng Huaxue), 1996, 4(1):1-4[24] YANG Hao(杨浩), LIU Dong(刘东), WANG De-Fen(王德粉), et al. Chinese J. Synth. Chem.(Hecheng Huaxue), 1996, 4(1):1-4
25. [25] Brown I D, Altermatt D. Acta Cryst., 1985,B41:244-247[25] Brown I D, Altermatt D. Acta Cryst., 1985,B41:244-247
26. [26] Sheldrick G M. SHELXTL, Program for the Solution and the Refinement of Crystal Structures, Universitt Gtötingen, Germany, 1997.[26] Sheldrick G M. SHELXTL, Program for the Solution and the Refinement of Crystal Structures, Universitt Gtötingen, Germany, 1997.

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以取代三联吡啶及钒氧酸为配体的一维带状化合物[Co(DMPhTPY)V₂O₆]_n的合成、晶体结构及性质研究

English

Synthesis, Crystal Structure and Properties of 1D Ribbon-Like Complex [Co(DMPhTPY)V₂O₆]_n with Substituted Terpyridine and Polyoxovanadate Ligand

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