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基于1,1’-二苯乙炔-3,3’,5,5’-四羧酸微孔铜配位聚合物的合成和气体吸附性质

胡云霞 ,  章文伟 ,  王立锋 ,  白俊峰

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引用本文: 胡云霞, 章文伟, 王立锋, 白俊峰. 基于1,1’-二苯乙炔-3,3’,5,5’-四羧酸微孔铜配位聚合物的合成和气体吸附性质[J]. 无机化学学报, 2013, 29(7): 1471-1479. doi: 10.3969/j.issn.1001-4861.2013.00.200 shu
Citation:  HU Yun-Xia, ZHANG Wen-Wei, WANG Li-Feng, BAI Jun-Feng. Synthesis and Gas Sorption Properties of Cupric Microporous Metal-Organic Framework Based on 1,1’-Ethynebenzene-3,3’,5,5’-tetracarboxylate[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(7): 1471-1479. doi: 10.3969/j.issn.1001-4861.2013.00.200 shu

基于1,1’-二苯乙炔-3,3’,5,5’-四羧酸微孔铜配位聚合物的合成和气体吸附性质

  • 基金项目:

    国家自然科学基金(No.20771058) (No.20771058)

    国家自然科学基金创新研究群体(No.20721002) (No.20721002)

    教育部博士点基金(No.200802840011) (No.200802840011)

    新疆凝聚态相变与微结构实验室开放课题基金(No.XJDX0912-2011-01)资助项目。 (No.XJDX0912-2011-01)

摘要: 本文报道了配合物[Cu2(EBTC)(H2O)2]·8H2O·DMF·DMSO(1,EBTC=1,1'-二苯乙炔-3,3',5,5'-四羧酸根;DMF=N,N-二甲基甲酰胺;DMSO=二甲基亚砜)的合成、晶体结构和吸附性质。1拥有内径为0.85 nm和0.85 nm×2.15 nm的两种孔洞,分别被6个和12个四羧酸根桥联的[Cu2(CO2)4]螺旋桨式结构围绕,并被EBTC连接成三维超分子结构,该结构拥有可容纳溶剂分子的一维孔道。1为(3,4)-连接的fof(sqc1575)拓扑结构,具有非常大的孔体积,其值高达单位晶胞体积的72.8%。去除溶剂分子后的1a表现出永久孔性,其Langmuir表面积为2844 m2·g-1,BET 表面积为1 852 m2·g-1。它对H2、CO2、CH4和C2H2具有可观的气体吸附量和相对较高的吸附焓。特别是,在迄今所有已报道的孔性金属-有机材料中,1a在273 K、1.0×105 Pa下,表现出最高的乙炔吸附量(252 cm3·g-1)和很高的吸附焓(吸附量为1 mmol·g-1时的吸附焓为34.5 kJ·mol-1)。

English

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  • 收稿日期:  2012-08-07
  • 网络出版日期:  2013-03-17
通讯作者: 陈斌, bchen63@163.com
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