English

Progress on Carbonene Fibers for Energy Devices

• Wenya He ^{1, 2, 3, †,} ,
• Huhu Cheng ^{1, 2, †,} ,
• Liangti Qu ^{1, 2, ,}

• 1.

  Key Laboratory of Organic Optoelectronics & Molecular Engineering, Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China

• 2.

  State Key Laboratory of Tribology, Department of Mechanical Engineering, Tsinghua University, Beijing 100084, China

• 3.

  College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: Liangti Qu, Email: lqu@mail.tsinghua.edu.cn

• Received Date: 04 March 2022
  Accepted Date: 29 March 2022
  Revised Date: 28 March 2022
  Available Online: 15 September 2022
• Fund Project:

  the National Natural Science Foundation of China 

  the National Natural Science Foundation of China 

  the National Natural Science Foundation of China 

  the National Natural Science Foundation of China 

  the National Natural Science Foundation of China 

  the State Key Laboratory of Tribology, China 

  the Tsinghua-Foshan Innovation Special Fund, China 

• ^†These authors contributed equally to this work.

Abstract: Flexible and wearable electronics can integrate multiple functions, such as sensing, actuation, and wireless communication, showing great potential for application in flexible displays, health monitoring, human-computer interaction, and other fields. Energy devices to supply power are an important part of wearable electronics. Traditional energy devices have a relatively rigid plate structure, and their poor mechanical flexibility, low breathability and moisture conductivity make them difficult to adapt to the needs of wearability. These problems have severely limited the development and application of wearable devices, and there is therefore an urgent need to develop flexible, lightweight, high-performance wearable energy devices. Fiber-based energy devices have several obvious advantages. First, the diameter of these devices usually ranges from micrometers to millimeters, which makes them small in size and light in weight. Then, their outstanding flexibility endows them with wearable comfort and stable performance under mechanical deformation. Third, fibers can be woven or knitted into deformable textiles with excellent wearability and breathability. Because of these advantages, fiber-based energy devices have attracted considerable attention. Traditional fiber-based energy devices usually use polymer fibers covered by metal wires as electrodes, but these have inherent defects, such as poor chemical stability, inferior matching with active materials, and a lack of mechanical flexibility, that hinder their application in wearable devices. Carbonene materials are low-dimensional all-carbon materials composed of sp²-hybridized carbon atoms, including carbon nanotubes and graphene, which have the advantages of low density, good mechanical properties, excellent electrical and thermal conductivity, and high stability. "Carbonene fibers" mainly refers to high-performance fiber-like macroscopic assemblies composed of carbonene materials, and includes carbon nanotube fibers, graphene fibers, and graphene/carbon nanotube composite fibers. Carbonene fibers can effectively transfer the excellent performance of carbonene materials at the micro scale to the macro scale, showing high conductivity, strength, flexibility, stability, and ease of manufacture, making them widely used in research on advanced energy devices. In recent years, researchers have developed a variety of carbonene fiber-based energy devices. This paper reviews recent progress in the application of carbonene fibers in energy devices, including energy conversion and energy storage devices such as solar cells, moisture actuators and moisture power generators, thermoelectric generators, supercapacitors, and electrochemical cells. The preparation methods and wearable applications of carbonene fiber-based energy devices are emphasized. Discussion of the development prospects and challenges of energy storage/conversion devices based on carbonene fibers is included, and it is expected that this will provide valuable ideas for the future development of high-performance fiber-based wearable energy devices.

Key words:
• Carbonene fiber
•  /  Carbon nanotube
•  /  Graphene
•  /  Energy conversion device
•  /  Energy storage device

• 1. [1]

     Wang, H.; Zhang, Y.; Liang, X.; Zhang, Y. ACS Nano 2021, 15, 12497. doi: 10.1021/acsnano.1c06230

  2. [2]

     Hasan, M. N.; Sahlan, S.; Osman, K.; Mohamed Ali, M. S. Adv. Mater. Technol. 2021, 6, 2000771. doi: 10.1002/admt.202000771

  3. [3]

     Gao, W.; Ota, H.; Kiriya, D.; Takei, K.; Javey, A. Acc. Chem. Res. 2019, 52, 523. doi: 10.1021/acs.accounts.8b00500

  4. [4]

     Ma, W.; Zhang, Y.; Pan, S.; Cheng, Y.; Shao, Z.; Xiang, H.; Chen, G.; Zhu, L.; Weng, W.; Bai, H.; et al. Chem. Soc. Rev. 2021, 50, 7009. doi: 10.1039/d0cs01603a

  5. [5]

     Huang, L.; Lin, S.; Xu, Z.; Zhou, H.; Duan, J.; Hu, B.; Zhou, J. Adv. Mater. 2020, 32, 1902034. doi: 10.1002/adma.201902034

  6. [6]

     廖春荣, 熊峰, 李贤军, 吴义强, 罗勇锋. 物理化学学报, 2017, 33, 329. doi: 10.3866/PKU.WHXB201611072Liao, C.-R.; Xiong, F.; Li, X.-J.; Wu, Y.-Q.; Luo, Y.-F. Acta Phys. -Chim. Sin. 2017, 33, 329. doi: 10.3866/PKU.WHXB201611072

  7. [7]

     Zhang, Z.; Zhang, Y.; Li, Y.; Peng, H. Acta Polym. Sin. 2016, 10, 1284. doi: 10.11777/j.issn1000-3304

  8. [8]

     Behabtu, N.; Young, C. C.; Tsentalovich, D. E.; Kleinerman, O.; Wang, X.; Ma, A. W. K.; Bengio, E. A.; Waarbeek, R. F. T.; Jong, J. J. D.; Hoogerwerf, R. E.; et al. Science 2013, 339, 182. doi: 10.1126/science.1228061

  9. [9]

     Marinho, B.; Ghislandi, M.; Tkalya, E.; Koning, C. E.; de With, G. Powder Technol. 2012, 221, 351. doi: 10.1016/j.powtec.2012.01.024

  10. [10]

      温烨烨, 任明, 邸江涛, 张锦. 物理化学学报, 2022, 38, 2107006. doi: 10.3866/PKU.WHXB202107006Wen, Y.; Ren, M.; Di, J.; Zhang, J. Acta Phys. -Chim. Sin. 2022, 38, 2107006. doi: 10.3866/PKU.WHXB202107006

  11. [11]

      Thostensona, E. T.; Renb, Z.; Choua, T.-W. Compos. Sci. Technol. 2001, 61, 1899. doi: 10.1016/s0266-3538(01)00094-x

  12. [12]

      Zhang, P.; Xu, Q.; Liao, Q.; Yao, H.; Wang, D.; Geng, H.; Cheng, H.; Li, C.; Ma, T.; Qu, L. Sci. China Mater. 2020, 63, 1948. doi: 10.1007/s40843-020-1491-x

  13. [13]

      Yao, H.; Zhang, P.; Yang, C.; Liao, Q.; Hao, X.; Huang, Y.; Zhang, M.; Wang, X.; Lin, T.; Cheng, H.; et al. Energy Environ. Sci. 2021, 14, 5330. doi: 10.1039/d1ee01381e

  14. [14]

      陈清, 赵健, 程虎虎, 曲良体. 物理化学学报, 2022, 38, 2101020. doi: 10.3866/PKU.WHXB202101020Chen, Q.; Zhao, J.; Cheng, H.; Qu, L. Acta Phys. -Chim. Sin. 2022, 38, 2101020. doi: 10.3866/PKU.WHXB202101020

  15. [15]

      Bulmer, J. S.; Kaniyoor, A.; Elliott, J. A. Adv. Mater. 2021, 33, 2008432. doi: 10.1002/adma.202008432

  16. [16]

      Lee, S.-H.; Park, J. H.; Kim, S. M. J. Korean Ceram. Soc. 2021, 58, 148. doi: 10.1007/s43207-020-00106-0

  17. [17]

      Qian, L.; Xie, Y.; Zou, M.; Zhang, J. J. Am. Chem. Soc. 2021, 143, 18805. doi: 10.1021/jacs.1c08554

  18. [18]

      吴昆杰, 张永毅, 勇振中, 李清文. 物理化学学报, 2022, 38, 2106034. doi: 10.3866/PKU.WHXB202106034Wu, K.; Zhang, Y.; Yong, Z.; Li, Q. Acta Phys. -Chim. Sin. 2022, 38, 2106034. doi: 10.3866/PKU.WHXB202106034

  19. [19]

      Zhang, X.; Lu, W.; Zhou, G.; Li, Q. Adv. Mater. 2020, 32, 1902028. doi: 10.1002/adma.201902028

  20. [20]

      Hu, C.; Zhao, Y.; Cheng, H.; Wang, Y.; Dong, Z.; Jiang, C.; Zhai, X.; Jiang, L.; Qu, L. Nano Lett. 2012, 12, 5879. doi: 10.1021/nl303243h

  21. [21]

      Meng, F.; Lu, W.; Li, Q.; Byun, J. H.; Oh, Y.; Chou, T. W. Adv. Mater. 2015, 27, 5113. doi: 10.1002/adma.201501126

  22. [22]

      Yu, G.-H.; Han, Q.; Qu, L.-T. Chinese J. Polym. Sci. 2019, 37, 535. doi: 10.1007/s10118-019-2245-9

  23. [23]

      Fang, B.; Chang, D.; Xu, Z.; Gao, C. Adv. Mater. 2020, 32, 1902664. doi: 10.1002/adma.201902664

  24. [24]

      Xu, T.; Zhang, Z.; Qu, L. Adv. Mater. 2020, 32, 1901979. doi: 10.1002/adma.201901979

  25. [25]

      蹇木强, 张莹莹, 刘忠范. 物理化学学报, 2022, 38, 2007093. doi: 10.3866/PKU.WHXB202007093Jian, M.; Zhang, Y.; Liu, Z. Acta Phys. -Chim. Sin. 2022, 38, 2007093. doi: 10.3866/PKU.WHXB202007093

  26. [26]

      夏洲, 邵元龙. 物理化学学报, 2022, 38, 2103046. doi: 10.3866/PKU.WHXB202103046Xia, Z.; Shao, Y. Acta Phys. -Chim. Sin. 2022, 38, 2103046. doi: 10.3866/PKU.WHXB202103046

  27. [27]

      程熠, 王坤, 亓月, 刘忠范. 物理化学学报, 2022, 38, 2006046. doi: 10.3866/PKU.WHXB202006046Cheng, Y.; Wang, K.; Qi, Y.; Liu, Z. Acta Phys. -Chim. Sin. 2022, 38, 2006046. doi: 10.3866/PKU.WHXB202006046

  28. [28]

      Lv, T.; Yao, Y.; Li, N.; Chen, T. Nano Today 2016, 11, 644. doi: 10.1016/j.nantod.2016.08.010

  29. [29]

      Zheng, X.; Hu, Q.; Zhou, X.; Nie, W.; Li, C.; Yuan, N. Mater. Design 2021, 201, 109476. doi: 10.1016/j.matdes.2021.109476

  30. [30]

      Cao, Y.; Zhou, T.; Wu, K.; Yong, Z.; Zhang, Y. RSC Adv. 2021, 11, 6628. doi: 10.1039/d0ra09482j

  31. [31]

      Wu, J.; Hong, Y.; Wang, B. J. Semicond. 2018, 39, 011004. doi: 10.1088/1674-4926/39/1/011004

  32. [32]

      Chen, L.; Liu, Y.; Zhao, Y.; Chen, N.; Qu, L. Nanotechnology 2016, 27, 032001. doi: 10.1088/0957-4484/27/3/032001

  33. [33]

      Luo, Y.; Li, X.; Zhang, J.; Liao, C.; Li, X. J. Nanomater. 2014, 2014, 580256. doi: 10.1155/2014/580256

  34. [34]

      Sun, H.; You, X.; Deng, J.; Chen, X.; Yang, Z.; Ren, J.; Peng, H. Adv. Mater. 2014, 26, 2868. doi: 10.1002/adma.201305188

  35. [35]

      Fu, X.; Sun, H.; Xie, S.; Zhang, J.; Pan, Z.; Liao, M.; Xu, L.; Li, Z.; Wang, B.; Sun, X.; et al. J. Mater. Chem. A 2018, 6, 45. doi: 10.1039/c7ta08637g

  36. [36]

      Li, Z.; Huang, T.; Gao, W.; Xu, Z.; Chang, D.; Zhang, C.; Gao, C. ACS Nano 2017, 11, 11056. doi: 10.1021/acsnano.7b05092

  37. [37]

      Kou, L.; Huang, T.; Zheng, B.; Han, Y.; Zhao, X.; Gopalsamy, K.; Sun, H.; Gao, C. Nat. Commun. 2014, 5, 3754. doi: 10.1038/ncomms4754

  38. [38]

      Bai, Y.; Jantunen, H.; Juuti, J. Adv. Mater. 2018, 30, 1707271. doi: 10.1002/adma.201707271

  39. [39]

      Huang, Y.; Zhu, M.; Huang, Y.; Pei, Z.; Li, H.; Wang, Z.; Xue, Q.; Zhi, C. Adv. Mater. 2016, 28, 8344. doi: 10.1002/adma.201601928

  40. [40]

      Liu, R.; Liu, Y.; Zou, H.; Song, T.; Sun, B. Nano Res. 2017, 10, 1545. doi: 10.1007/s12274-017-1450-5

  41. [41]

      Cole, J. M.; Pepe, G.; Al Bahri, O. K.; Cooper, C. B. Chem. Rev. 2019, 119, 7279. doi: 10.1021/acs.chemrev.8b00632

  42. [42]

      Wu, J.; Lan, Z.; Lin, J.; Huang, M.; Huang, Y.; Fan, L.; Luo, G.; Lin, Y.; Xie, Y.; Wei, Y. Chem. Soc. Rev. 2017, 46, 5975. doi: 10.1039/c6cs00752j

  43. [43]

      Chen, T.; Wang, S.; Yang, Z.; Feng, Q.; Sun, X.; Li, L.; Wang, Z. S.; Peng, H. Angew. Chem. Int. Ed. 2011, 50, 1815. doi: 10.1002/anie.201003870

  44. [44]

      Chen, T.; Qiu, L.; Cai, Z.; Gong, F.; Yang, Z.; Wang, Z.; Peng, H. Nano Lett. 2012, 12, 2568. doi: 10.1021/nl300799d

  45. [45]

      Zhang, S.; Ji, C.; Bian, Z.; Yu, P.; Zhang, L.; Liu, D.; Shi, E.; Shang, Y.; Peng, H.; Cheng, Q.; et al. ACS Nano 2012, 6, 7191. doi: 10.1021/nn3022553

  46. [46]

      Ali, A.; Shah, S. M.; Bozar, S.; Kazici, M.; Keskin, B.; Kaleli, M.; Akyurekli, S.; Gunes, S. Nanotechnology 2016, 27, 384003. doi: 10.1088/0957-4484/27/38/384003

  47. [47]

      Xu, Z.; Gao, C. Nat. Commun. 2011, 2, 571. doi: 10.1038/ncomms1583

  48. [48]

      Dong, Z.; Jiang, C.; Cheng, H.; Zhao, Y.; Shi, G.; Jiang, L.; Qu, L. Adv. Mater. 2012, 24, 1856. doi: 10.1002/adma.201200170

  49. [49]

      Meng, Y.; Zhao, Y.; Hu, C.; Cheng, H.; Hu, Y.; Zhang, Z.; Shi, G.; Qu, L. Adv. Mater. 2013, 25, 2326. doi: 10.1002/adma.201300132

  50. [50]

      Chen, T.; Dai, L. Angew. Chem. Int. Ed. 2015, 54, 14947. doi: 10.1002/anie.201507246

  51. [51]

      Yang, Z.; Sun, H.; Chen, T.; Qiu, L.; Luo, Y.; Peng, H. Angew. Chem. Int. Ed. 2013, 52, 7545. doi: 10.1002/anie.201301776

  52. [52]

      Zhang, L.; Shi, E.; Ji, C.; Li, Z.; Li, P.; Shang, Y.; Li, Y.; Wei, J.; Wang, K.; Zhu, H.; et al. Nanoscale 2012, 4, 4954. doi: 10.1039/c2nr31440a

  53. [53]

      Liu, D.; Zhao, M.; Li, Y.; Bian, Z.; Zhang, L.; Shang, Y.; Xia, X.; Zhang, S.; Yun, D.; Liu, Z.; et al. ACS Nano 2012, 6, 11027. doi: 10.1021/nn304638z

  54. [54]

      Ko, H.; Javey, A. Acc. Chem. Res. 2017, 50, 691. doi: 10.1021/acs.accounts.6b00612

  55. [55]

      Jang, Y.; Kim, S. M.; Spinks, G. M.; Kim, S. J. Adv. Mater. 2020, 32, 1902670. doi: 10.1002/adma.201902670

  56. [56]

      Poppinga, S.; Zollfrank, C.; Prucker, O.; Ruhe, J.; Menges, A.; Cheng, T.; Speck, T. Adv. Mater. 2018, 30, 1703653. doi: 10.1002/adma.201703653

  57. [57]

      Gao, T.; Xu, G.; Wen, Y.; Cheng, H.; Li, C.; Qu, L. Nanoscale Horiz. 2020, 5, 1226. doi: 10.1039/d0nh00268b

  58. [58]

      Cheng, H.; Liu, J.; Zhao, Y.; Hu, C.; Zhang, Z.; Chen, N.; Jiang, L.; Qu, L. Angew. Chem. Int. Ed. 2013, 52, 10482. doi: 10.1002/anie.201304358

  59. [59]

      Cheng, H.; Hu, Y.; Zhao, F.; Dong, Z.; Wang, Y.; Chen, N.; Zhang, Z.; Qu, L. Adv. Mater. 2014, 26, 2909. doi: 10.1002/adma.201305708

  60. [60]

      He, S.; Chen, P.; Qiu, L.; Wang, B.; Sun, X.; Xu, Y.; Peng, H. Angew. Chem. Int. Ed. 2015, 54, 14880. doi: 10.1002/anie.201507108

  61. [61]

      Gu, X.; Fan, Q.; Yang, F.; Cai, L.; Zhang, N.; Zhou, W.; Zhou, W.; Xie, S. Nanoscale 2016, 8, 17881. doi: 10.1039/c6nr06185k

  62. [62]

      Wang, H.; Cheng, H.; Huang, Y.; Yang, C.; Wang, D.; Li, C.; Qu, L. Nano Energy 2020, 67, 104238. doi: 10.1016/j.nanoen.2019.104238

  63. [63]

      Huang, Y.; Cheng, H.; Qu, L. ACS Mater. Lett. 2021, 3, 193. doi: 10.1021/acsmaterialslett.0c00474

  64. [64]

      Wang, H.; Sun, Y.; He, T.; Huang, Y.; Cheng, H.; Li, C.; Xie, D.; Yang, P.; Zhang, Y.; Qu, L. Nat. Nanotechnol. 2021, 16, 811. doi: 10.1038/s41565-021-00903-6

  65. [65]

      Wang, Z.; Li, J.; Shao, C.; Lin, X.; Yang, Y.; Chen, N.; Wang, Y.; Qu, L. Nano Energy 2021, 90, 106529. doi: 10.1016/j.nanoen.2021.106529

  66. [66]

      Bai, J.; Huang, Y.; Wang, H.; Guang, T.; Liao, Q.; Cheng, H.; Deng, S.; Li, Q.; Shuai, Z.; Qu, L. Adv. Mater. 2022, 2103897. doi: 10.1002/adma.202103897

  67. [67]

      Cheng, H.; Huang, Y.; Zhao, F.; Yang, C.; Zhang, P.; Jiang, L.; Shi, G.; Qu, L. Energy Environ. Sci. 2018, 11, 2839. doi: 10.1039/c8ee01502c

  68. [68]

      Bai, J.; Huang, Y.; Cheng, H.; Qu, L. Nanoscale 2019, 11, 23083. doi: 10.1039/c9nr06113d

  69. [69]

      Liang, Y.; Zhao, F.; Cheng, Z.; Zhou, Q.; Shao, H.; Jiang, L.; Qu, L. Nano Energy 2017, 32, 329. doi: 10.1016/j.nanoen.2016.12.062

  70. [70]

      Shao, C.; Gao, J.; Xu, T.; Ji, B.; Xiao, Y.; Gao, C.; Zhao, Y.; Qu, L. Nano Energy 2018, 53, 698. doi: 10.1016/j.nanoen.2018.09.043

  71. [71]

      Xu, Y.; Chen, P.; Zhang, J.; Xie, S.; Wan, F.; Deng, J.; Cheng, X.; Hu, Y.; Liao, M.; Wang, B.; et al. Angew. Chem. Int. Ed. 2017, 56, 12940. doi: 10.1002/anie.201706620

  72. [72]

      Chen, W.-Y.; Shi, X.-L.; Zou, J.; Chen, Z.-G. Nano Energy 2021, 81, 105684. doi: 10.1016/j.nanoen.2020.105684

  73. [73]

      Shi, X.-L.; Chen, W.-Y.; Zhang, T.; Zou, J.; Chen, Z.-G. Energy Environ. Sci. 2021, 14, 729. doi: 10.1039/d0ee03520c

  74. [74]

      Yadav, A.; Pipe, K. P.; Shtein, M. J. Power Sources 2008, 175, 909. doi: 10.1016/j.jpowsour.2007.09.096

  75. [75]

      Zhang, L.; Lin, S.; Hua, T.; Huang, B.; Liu, S.; Tao, X. Adv. Energy Mater. 2018, 8, 1700524. doi: 10.1002/aenm.201700524

  76. [76]

      Balandin, A. A. Nat. Mater. 2011, 10, 569. doi: 10.1038/nmat3064

  77. [77]

      Blackburn, J. L.; Ferguson, A. J.; Cho, C.; Grunlan, J. C. Adv. Mater. 2018, 30, 1704386. doi: 10.1002/adma.201704386

  78. [78]

      Xu, Y.; Li, Z.; Duan, W. Small 2014, 10, 2182. doi: 10.1002/smll.201303701

  79. [79]

      Lin, Y.; Liu, J.; Wang, X.; Xu, J.; Liu, P.; Nie, G.; Liu, C.; Jiang, F. Compos. Commun. 2019, 16, 79. doi: 10.1016/j.coco.2019.09.002

  80. [80]

      Liu, J.; Liu, G.; Xu, J.; Liu, C.; Zhou, W.; Liu, P.; Nie, G.; Duan, X.; Jiang, F. ACS Appl. Energy Mater. 2020, 3, 6165. doi: 10.1021/acsaem.0c00001

  81. [81]

      Komatsu, N.; Ichinose, Y.; Dewey, O. S.; Taylor, L. W.; Trafford, M. A.; Yomogida, Y.; Wehmeyer, G.; Pasquali, M.; Yanagi, K.; Kono, J. Nat. Commun. 2021, 12, 4931. doi: 10.1038/s41467-021-25208-z

  82. [82]

      Lee, T.; Lee, J. W.; Park, K. T.; Kim, J. S.; Park, C. R.; Kim, H. ACS Nano 2021, 15, 13118. doi: 10.1021/acsnano.1c02508

  83. [83]

      Li, X.; Wang, Y.; Zhao, Y.; Zhang, J.; Qu, L. Small Structures 2022, 3, 2100124. doi: 10.1002/sstr.202100124

  84. [84]

      Dubal, D. P.; Ayyad, O.; Ruiz, V.; Gomez-Romero, P. Chem. Soc. Rev. 2015, 44, 1777. doi: 10.1039/c4cs00266k

  85. [85]

      Wang, G.; Zhang, L.; Zhang, J. Chem. Soc. Rev. 2012, 41, 797. doi: 10.1039/c1cs15060j

  86. [86]

      Lu, B.; Liu, F.; Sun, G.; Gao, J.; Xu, T.; Xiao, Y.; Shao, C.; Jin, X.; Yang, H.; Zhao, Y.; et al. Adv. Mater. 2020, 32, 1907005. doi: 10.1002/adma.201907005

  87. [87]

      Lu, B.; Jin, X.; Han, Q.; Qu, L. Small 2021, 17, 2006827. doi: 10.1002/smll.202006827

  88. [88]

      Chen, D.; Jiang, K.; Huang, T.; Shen, G. Adv. Mater. 2020, 32, 1901806. doi: 10.1002/adma.201901806

  89. [89]

      Senthilkumar, S. T.; Wang, Y.; Huang, H. J. Mater. Chem. A 2015, 3, 20863. doi: 10.1039/c5ta04731e

  90. [90]

      Cheng, H.; Li, Q.; Zhu, L.; Chen, S. Small Methods 2021, 5, 2100502. doi: 10.1002/smtd.202100502

  91. [91]

      Choi, C.; Lee, J. A.; Choi, A. Y.; Kim, Y. T.; Lepro, X.; Lima, M. D.; Baughman, R. H.; Kim, S. J. Adv. Mater. 2014, 26, 2059. doi: 10.1002/adma.201304736

  92. [92]

      Lu, Z.; Foroughi, J.; Wang, C.; Long, H.; Wallace, G. G. Adv. Energy Mater. 2017, 8, 1702047. doi: 10.1002/aenm.201702047

  93. [93]

      Xu, P.; Gu, T.; Cao, Z.; Wei, B.; Yu, J.; Li, F.; Byun, J.-H.; Lu, W.; Li, Q.; Chou, T.-W. Adv. Energy Mater. 2014, 4, 1300759. doi: 10.1002/aenm.201300759

  94. [94]

      Dalton, A. B.; Collins, S.; Muñoz, E.; Razal, J. M.; Ebron, V. H.; Ferraris, J. P.; N. J.; Coleman; Kim, B. G.; Baughman, R. H. Science 2003, 423, 703. doi: 10.1038/423703a

  95. [95]

      Chen, X.; Qiu, L.; Ren, J.; Guan, G.; Lin, H.; Zhang, Z.; Chen, P.; Wang, Y.; Peng, H. Adv. Mater. 2013, 25, 6436. doi: 10.1002/adma.201301519

  96. [96]

      Meng, Q.; Wu, H.; Meng, Y.; Xie, K.; Wei, Z.; Guo, Z. Adv. Mater. 2014, 26, 4100. doi: 10.1002/adma.201400399

  97. [97]

      Liang, Y.; Wang, Z.; Huang, J.; Cheng, H.; Zhao, F.; Hu, Y.; Jiang, L.; Qu, L. J. Mater. Chem. A 2015, 3, 2547. doi: 10.1039/c4ta06574c

  98. [98]

      Hu, Y.; Cheng, H.; Zhao, F.; Chen, N.; Jiang, L.; Feng, Z.; Qu, L. Nanoscale 2014, 6, 6448. doi: 10.1039/c4nr01220h

  99. [99]

      Cai, W.; Lai, T.; Ye, J. J. Mater. Chem. A 2015, 3, 5060. doi: 10.1039/c5ta00365b

  100. [100]

       Wang, D. W.; Li, F.; Liu, M.; Lu, G. Q.; Cheng, H. M. Angew. Chem. Int. Ed. 2008, 47, 373. doi: 10.1002/anie.200702721

  101. [101]

       Chmiola, J.; Yushin, G.; Gogotsi, Y.; Portet, C.; Simon, P.; Taberna, P. L. Science 2006, 313, 1760. doi: 10.1126/science.1132195

  102. [102]

       Lu, C.; Meng, J.; Zhang, J.; Chen, X.; Du, M.; Chen, Y.; Hou, C.; Wang, J.; Ju, A.; Wang, X.; et al. ACS Appl. Mater. Interfaces 2019, 11, 25205. doi: 10.1021/acsami.9b06406

  103. [103]

       Meng, J.; Nie, W.; Zhang, K.; Xu, F.; Ding, X.; Wang, S.; Qiu, Y. ACS Appl. Mater. Interfaces 2018, 10, 13652. doi: 10.1021/acsami.8b04438

  104. [104]

       Zheng, X.; Zhang, K.; Yao, L.; Qiu, Y.; Wang, S. J. Mater. Chem. A 2018, 6, 896. doi: 10.1039/c7ta08362a

  105. [105]

       Cai, S.; Huang, T.; Chen, H.; Salman, M.; Gopalsamy, K.; Gao, C. J. Mater. Chem. A 2017, 5, 22489. doi: 10.1039/c7ta07937k

  106. [106]

       Liu, K.; Chen, Z.; Lv, T.; Yao, Y.; Li, N.; Li, H.; Chen, T. Nano-Micro Lett. 2020, 12, 64. doi: 10.1007/s40820-020-0390-x

  107. [107]

       Cheng, H.; Dong, Z.; Hu, C.; Zhao, Y.; Hu, Y.; Qu, L.; Chen, N.; Dai, L. Nanoscale 2013, 5, 3428. doi: 10.1039/c3nr00320e

  108. [108]

       Yu, D.; Goh, K.; Wang, H.; Wei, L.; Jiang, W.; Zhang, Q.; Dai, L.; Chen, Y. Nat. Nanotechnol. 2014, 9, 555. doi: 10.1038/nnano.2014.93

  109. [109]

       Park, H.; Ambade, R. B.; Noh, S. H.; Eom, W.; Koh, K. H.; Ambade, S. B.; Lee, W. J.; Kim, S. H.; Han, T. H. ACS Appl. Mater. Interfaces 2019, 11, 9011. doi: 10.1021/acsami.8b17908

  110. [110]

       Wei, W.; Cui, X.; Chen, W.; Ivey, D. G. Chem. Soc. Rev. 2011, 40, 1697. doi: 10.1039/c0cs00127a

  111. [111]

       Augustyn, V.; Simon, P.; Dunn, B. Energy Environ. Sci. 2014, 7, 1597. doi: 10.1039/c3ee44164d

  112. [112]

       Liu, C.; Yu, Z.; Neff, D.; Zhamu, A.; Jang, B. Z. Nano Lett. 2010, 10, 4863. doi: 10.1021/nl102661q

  113. [113]

       Wu, Z.-S.; Zhou, G.; Yin, L.-C.; Ren, W.; Li, F.; Cheng, H.-M. Nano Energy 2012, 1, 107. doi: 10.1016/j.nanoen.2011.11.001

  114. [114]

       Wang, K.; Meng, Q.; Zhang, Y.; Wei, Z.; Miao, M. Adv. Mater. 2013, 25, 1494. doi: 10.1002/adma.201204598

  115. [115]

       Cheng, X.; Zhang, J.; Ren, J.; Liu, N.; Chen, P.; Zhang, Y.; Deng, J.; Wang, Y.; Peng, H. J. Phys. Chem. C 2016, 120, 9685. doi: 10.1021/acs.jpcc.6b02794

  116. [116]

       Zheng, X.; Yao, L.; Qiu, Y.; Wang, S.; Zhang, K. ACS Appl. Energy Mater. 2019, 2, 4335. doi: 10.1021/acsaem.9b00558

  117. [117]

       Salman, A.; Padmajan Sasikala, S.; Kim, I. H.; Kim, J. T.; Lee, G. S.; Kim, J. G.; Kim, S. O. Nanoscale 2020, 12, 20239. doi: 10.1039/d0nr06636b

  118. [118]

       Wang, B.; Fang, X.; Sun, H.; He, S.; Ren, J.; Zhang, Y.; Peng, H. Adv. Mater. 2015, 27, 7854. doi: 10.1002/adma.201503441

  119. [119]

       Yang, Z.; Zhang, J.; Kintner-Meyer, M. C. W.; Lu, X.; Choi, D.; Lemmon, J. P.; Liu, J. Chem. Rev. 2011, 111, 3577. doi: 10.1021/cr100290v

  120. [120]

       Wu, J.; Pan, Z.; Zhang, Y.; Wang, B.; Peng, H. J. Mater. Chem. A 2018, 6, 12932. doi: 10.1039/c8ta03968b

  121. [121]

       Xi, Z.; Zhang, X.; Ma, Y.; Zhou, C.; Yang, J.; Wu, Y.; Li, X.; Luo, Y.; Chen, D. ChemElectroChem 2018, 5, 3127. doi: 10.1002/celc.201800741

  122. [122]

       Zhang, T.-W.; Tian, T.; Shen, B.; Song, Y.-H.; Yao, H.-B. Compos. Commun. 2019, 14, 7. doi: 10.1016/j.coco.2019.05.003

  123. [123]

       Mo, F.; Liang, G.; Huang, Z.; Li, H.; Wang, D.; Zhi, C. Adv. Mater. 2020, 32, 1902151. doi: 10.1002/adma.201902151

  124. [124]

       Chen, X.; Ma, Y. Adv. Mater. Technol. 2018, 3, 1800041. doi: 10.1002/admt.201800041

  125. [125]

       Zhou, Y.; Wang, C. H.; Lu, W.; Dai, L. Adv. Mater. 2020, 32, 1902779. doi: 10.1002/adma.201902779

  126. [126]

       Zhang, Y.; Bai, W.; Ren, J.; Weng, W.; Lin, H.; Zhang, Z.; Peng, H. J. Mater. Chem. A 2014, 2, 11054. doi: 10.1039/c4ta01878h

  127. [127]

       Wu, Z.; Liu, K.; Lv, C.; Zhong, S.; Wang, Q.; Liu, T.; Liu, X.; Yin, Y.; Hu, Y.; Wei, D.; et al. Small 2018, 14, 1800414. doi: 10.1002/smll.201800414

  128. [128]

       Zhang, Y.; Weng, W.; Yang, J.; Liang, Y.; Yang, L.; Luo, X.; Zuo, W.; Zhu, M. J. Mater. Sci. 2018, 54, 582. doi: 10.1007/s10853-018-2813-3

  129. [129]

       Ren, J.; Zhang, Y.; Bai, W.; Chen, X.; Zhang, Z.; Fang, X.; Weng, W.; Wang, Y.; Peng, H. Angew. Chem. Int. Ed. 2014, 53, 7864. doi: 10.1002/anie.201402388

  130. [130]

       Zhang, Y.; Bai, W.; Cheng, X.; Ren, J.; Weng, W.; Chen, P.; Fang, X.; Zhang, Z.; Peng, H. Angew. Chem. Int. Ed. 2014, 53, 14564. doi: 10.1002/anie.201409366

  131. [131]

       Weng, W.; Sun, Q.; Zhang, Y.; Lin, H.; Ren, J.; Lu, X.; Wang, M.; Peng, H. Nano Lett. 2014, 14, 3432. doi: 10.1021/nl5009647

  132. [132]

       Hoshide, T.; Zheng, Y.; Hou, J.; Wang, Z.; Li, Q.; Zhao, Z.; Ma, R.; Sasaki, T.; Geng, F. Nano Lett. 2017, 17, 3543. doi: 10.1021/acs.nanolett.7b00623

  133. [133]

       Wang, B.; Ryu, J.; Choi, S.; Song, G.; Hong, D.; Hwang, C.; Chen, X.; Wang, B.; Li, W.; Song, H. K.; et al. ACS Nano 2018, 12, 1739. doi: 10.1021/acsnano.7b08489

  134. [134]

       Rao, J.; Liu, N.; Zhang, Z.; Su, J.; Li, L.; Xiong, L.; Gao, Y. Nano Energy 2018, 51, 425. doi: 10.1016/j.nanoen.2018.06.067

  135. [135]

       Tan, P.; Chen, B.; Xu, H.; Zhang, H.; Cai, W.; Ni, M.; Liu, M.; Shao, Z. Energy Environ. Sci. 2017, 10, 2056. doi: 10.1039/c7ee01913k

  136. [136]

       Mei, J.; Liao, T.; Liang, J.; Qiao, Y.; Dou, S. X.; Sun, Z. Adv. Energy Mater. 2019, 10, 1901997. doi: 10.1002/aenm.201901997

  137. [137]

       Zhang, Y.; Jiao, Y.; Lu, L.; Wang, L.; Chen, T.; Peng, H. Angew. Chem. Int. Ed. 2017, 56, 13741. doi: 10.1002/anie.201707840

  138. [138]

       Li, Y.; Zhong, C.; Liu, J.; Zeng, X.; Qu, S.; Han, X.; Deng, Y.; Hu, W.; Lu, J. Adv. Mater. 2018, 30, 1703657. doi: 10.1002/adma.201703657

  139. [139]

       Xu, Y.; Zhao, Y.; Ren, J.; Zhang, Y.; Peng, H. Angew. Chem. Int. Ed. 2016, 55, 7979. doi: 10.1002/anie.201601804

  140. [140]

       Dai, C.; Hu, L.; Jin, X.; Zhao, Y.; Qu, L. Small 2021, 17, 2008043. doi: 10.1002/smll.202008043

  141. [141]

       Jin, X.; Song, L.; Dai, C.; Xiao, Y.; Han, Y.; Zhang, X.; Li, X.; Bai, C.; Zhang, J.; Zhao, Y.; et al. Adv. Energy Mater. 2021, 11, 2101523. doi: 10.1002/aenm.202101523

  142. [142]

       Jin, X.; Song, L.; Dai, C.; Xiao, Y.; Han, Y.; Li, X.; Wang, Y.; Zhang, J.; Zhao, Y.; Zhang, Z.; et al. Adv. Mater. 2022, 2109450. doi: 10.1002/adma.202109450

  143. [143]

       Ma, H.; Chen, H.; Hu, Y.; Yang, B.; Feng, J.; Xu, Y.; Sun, Y.; Cheng, H.; Li, C.; Yan, X.; et al. Energy Environ. Sci. 2022, 15, 1131. doi: 10.1039/d1ee03672f

  144. [144]

       Ao, H.; Zhao, Y.; Zhou, J.; Cai, W.; Zhang, X.; Zhu, Y.; Qian, Y. J. Mater. Chem. A 2019, 7, 18708. doi: 10.1039/c9ta06433h

  145. [145]

       Liu, T.; Cheng, X.; Yu, H.; Zhu, H.; Peng, N.; Zheng, R.; Zhang, J.; Shui, M.; Cui, Y.; Shu, J. Energy Stor. Mater. 2019, 18, 68. doi: 10.1016/j.ensm.2018.09.027

  146. [146]

       Zhao, Y.; Chen, Z.; Mo, F.; Wang, D.; Guo, Y.; Liu, Z.; Li, X.; Li, Q.; Liang, G.; Zhi, C. Adv. Sci. 2020, 8, 2002590. doi: 10.1002/advs.202002590

  147. [147]

       Zhang, Y.; Wang, Y.; Wang, L.; Lo, C.-M.; Zhao, Y.; Jiao, Y.; Zheng, G.; Peng, H. J. Mater. Chem. A 2016, 4, 9002. doi: 10.1039/c6ta03477b

  148. [148]

       Fang, G.; Zhou, J.; Pan, A.; Liang, S. ACS Energy Lett. 2018, 3, 2480. doi: 10.1021/acsenergylett.8b01426

  149. [149]

       Xu, W.; Wang, Y. Nano-Micro Lett. 2019, 11, 90. doi: 10.1007/s40820-019-0322-9

  150. [150]

       Zhang, Q.; Li, C.; Li, Q.; Pan, Z.; Sun, J.; Zhou, Z.; He, B.; Man, P.; Xie, L.; Kang, L.; et al. Nano Lett. 2019, 19, 4035. doi: 10.1021/acs.nanolett.9b01403

  151. [151]

       Guo, S.; Yi, J.; Sun, Y.; Zhou, H. Energy Environ. Sci. 2016, 9, 2978. doi: 10.1039/c6ee01807f

  152. [152]

       Hwang, J. Y.; Myung, S. T.; Sun, Y. K. Chem. Soc. Rev. 2017, 46, 3529. doi: 10.1039/c6cs00776g

  153. [153]

       Guo, Z.; Zhao, Y.; Ding, Y.; Dong, X.; Chen, L.; Cao, J.; Wang, C.; Xia, Y.; Peng, H.; Wang, Y. Chem 2017, 3, 348. doi: 10.1016/j.chempr.2017.05.004

  154. [154]

       Chong, W. G.; Huang, J.-Q.; Xu, Z.-L.; Qin, X.; Wang, X.; Kim, J.-K. Adv. Funct. Mater. 2017, 27, 1604815. doi: 10.1002/adfm.201604815

  155. [155]

       Wang, K.; Zhang, X.; Han, J.; Zhang, X.; Sun, X.; Li, C.; Liu, W.; Li, Q.; Ma, Y. ACS Appl. Mater. Interfaces 2018, 10, 24573. doi: 10.1021/acsami.8b07756

  156. [156]

       Li, C.; Zhang, Q.; E, S.; Li, T.; Zhu, Z.; He, B.; Zhou, Z.; Man, P.; Li, Q.; Yao, Y. J. Mater. Chem. A 2019, 7, 2034. doi: 10.1039/c8ta10807b

  157. [157]

       Wang, M.; Xie, S.; Tang, C.; Zhao, Y.; Liao, M.; Ye, L.; Wang, B.; Peng, H. Adv. Funct. Mater. 2019, 30, 1905971. doi: 10.1002/adfm.201905971

  158. [158]

       Fu, Y.; Wu, H.; Ye, S.; Cai, X.; Yu, X.; Hou, S.; Kafafy, H.; Zou, D. Energy Environ. Sci. 2013, 6, 805. doi: 10.1039/c3ee23970e

  159. [159]

       Han, Y.; Wang, W.; Zou, J.; Li, Z.; Cao, X.; Xu, S. Nano Energy 2020, 76, 105008. doi: 10.1016/j.nanoen.2020.105008

  160. [160]

       Zhang, Y.; Zhao, Y.; Cheng, X.; Weng, W.; Ren, J.; Fang, X.; Jiang, Y.; Chen, P.; Zhang, Z.; Wang, Y.; et al. Angew. Chem. Int. Ed. 2015, 54, 11177. doi: 10.1002/anie.201506142

  161. [161]

       Yao, Y.; Lv, T.; Li, N.; Chen, Z.; Zhang, C.; Chen, T. Sci. Bull. 2020, 65, 486. doi: 10.1016/j.scib.2019.11.013

  162. [162]

       Sun, H.; Jiang, Y.; Xie, S.; Zhang, Y.; Ren, J.; Ali, A.; Doo, S.-G.; Son, I. H.; Huang, X.; Peng, H. J. Mater. Chem. A 2016, 4, 7601. doi: 10.1039/C6TA01514J

  163. [163]

       He, J.; Lu, C.; Jiang, H.; Han, F.; Shi, X.; Wu, J.; Wang, L.; Chen, T.; Wang, J.; Zhang, Y.; et al. Nature 2021, 597, 57. doi: 10.1038/s41586-021-03772-0

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