尺寸可控的单分散四氧化三铁微球的省时制备

引用本文: 王丹, 刘传勇, 龙玥, 宋恺, 黄维. 尺寸可控的单分散四氧化三铁微球的省时制备[J]. 物理化学学报, 2017, 33(11): 2310-2316. doi: 10.3866/PKU.WHXB201706093 shu

Citation: WANG Dan, LIU Chuan-Yong, LONG Yue, SONG Kai, HUANG Wei. A Time-Saving Method to Prepare Monodisperse Fe₃O₄ Microspheres with Controllable Sizes and Morphologies[J]. Acta Physico-Chimica Sinica, 2017, 33(11): 2310-2316. doi: 10.3866/PKU.WHXB201706093 shu

尺寸可控的单分散四氧化三铁微球的省时制备

王丹 ^1,3, ,
刘传勇 ^2, ,
龙玥 ^3, ,
宋恺 ^3, ,
黄维 ^1,

1.
南京邮电大学先进生物与化学制造协同创新中心, 有机电子与信息显示国家重点实验室培育基地, 南京 210023;
2.
中国科学院化学研究所, 北京 100190;
3.
中国科学院理化技术研究所, 北京 100190
基金项目:
国家自然科学基金（U1430128）资助

摘要: 用溶剂热法制备了单分散性较好、尺寸可控，饱和磁化强度高的四氧化三铁磁性微球，并用多种手段调控制备了不同尺寸和形貌的四氧化三铁微球，如氯化铁、醋酸钠、水的量以及反应时间。结果表明所得四氧化三铁产物纯净、结晶度高，形状近乎球形、无团聚，大小均一、具有很好的单分散性。此方法可以在2-4 h内制备400-700 nm范围内尺寸可控、高饱和磁化强度的四氧化三铁微球，产率达到了94%。

关键词:

English

A Time-Saving Method to Prepare Monodisperse Fe₃O₄ Microspheres with Controllable Sizes and Morphologies

1.
Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials(IAM), Jiangsu National Synergetic Innovation Centre for Advanced Materials(SICAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, P. R. China;
2.
Beijing National Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
3.
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
Received Date: 18 April 2017
Revised Date: 29 May 2017
Fund Project:
The project was supported by the National Natural Science Foundation of China (U1430128).

Abstract: Monodisperse Fe₃O₄ microspheres with tunable diameters and high magnetic saturation were synthesized by a solvothermal reduction method. It was found that the morphology and structure of the Fe₃O₄ microspheres could be tuned by simply altering the amount of the reactants such as ferric chloride, sodium acetate, water, and the reaction time. The Fe₃O₄ microspheres obtained via this method possessed high purity, crystallinity, and a nearly spherical shape. Furthermore, they were monodispersed and no aggregation was found. Such monodisperse Fe₃O₄ microspheres had tunable diameters of 400-700 nm and the fabrication time was only 2-4 h. The products showed high magnetic saturation values, and their yields were typically more than 94%.

Key words:

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尺寸可控的单分散四氧化三铁微球的省时制备

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尺寸可控的单分散四氧化三铁微球的省时制备

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