二维炭基多孔材料的合成及应用

引用本文: 贺雷, 张向倩, 陆安慧. 二维炭基多孔材料的合成及应用[J]. 物理化学学报, 2017, 33(4): 709-728. doi: 10.3866/PKU.WHXB201612201 shu

Citation: HE Lei, ZHANG Xiang-Qian, LU An-Hui. Two-Dimensional Carbon-Based Porous Materials: Synthesis and Applications[J]. Acta Physico-Chimica Sinica, 2017, 33(4): 709-728. doi: 10.3866/PKU.WHXB201612201 shu

二维炭基多孔材料的合成及应用

大连理工大学化工学院, 精细化工国家重点实验室, 辽宁大连 116024
基金项目:
国家自然科学基金（21225312，21403027，21506022）资助项目

摘要: 二维材料是指厚度在纳米尺度，且在两个维度（长和宽）具有较大尺寸的材料。与块体材料相比，二维材料最大的特点是具有极高的表面/体积比，有利于传质、传热和离子扩散，因而在吸附、催化以及储能等领域有广泛的应用。近年来，随着石墨烯引发的二维材料研究浪潮，二维炭基多孔材料成为全世界关注的研究热点。而二维炭基材料的孔结构是影响其性能的关键因素。本文介绍了近年来二维炭基多孔材料的合成方法，包括炭纳米片及炭-无机复合纳米片的制备，讨论了制备条件对材料孔结构的影响。在此基础上，着重介绍了二维炭基材料在吸附、多相催化及储能方面的应用。最后，对新型炭基二维材料开发中仍存在的关键科学问题进行了总结和展望。

关键词:

二维材料
/ 炭
/ 孔结构
/ 合成方法
/ 吸附
/ 催化
/ 储能

English

Two-Dimensional Carbon-Based Porous Materials: Synthesis and Applications

State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China
Received Date: 21 October 2016
Revised Date: 20 December 2016
Available Online: 20 December 2016
Fund Project:
The project was supported by the National Natural Science Foundation of China (21225312, 21403027, 21506022).

Abstract: Two-dimensional (2D) materials possess nanoscale thickness with large aspect ratios on the other two dimensions. The ultrahigh surface-to-volume ratio of 2D materials is the most important property different from their bulk counterparts, and is beneficial for mass and heat transport, and ion diffusion. Among the various 2D materials, carbon-based materials have attracted tremendous attentions since the first explosive research on graphene. Therefore, they provide opportunities for applications in adsorption, catalysis, and electrical energy storage. The porous structure of such carbon materials is a key influence on the properties of these 2D materials. This review focuses on recent developments in synthesis strategies for 2D carbon-based materials, especially the preparation of carbon nanosheets and carbon-inorganic hybrids/composites nanosheets. The main factors influencing the porous structure of the material are discussed for each method. Applications of the materials are introduced, mainly in the fields of adsorption, heterogeneous catalysis, and electrical energy storage. Finally, the leading-edge issues of novel 2D carbon-based materials for the future are discussed.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

二维炭基多孔材料的合成及应用

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

二维炭基多孔材料的合成及应用

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Two-Dimensional Carbon-Based Porous Materials: Synthesis and Applications

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

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