Fe<sub>2</sub>O<sub>3</sub>/rGO纳米复合物的制备及其储锂和储钠性能

引用本文: 李婷, 龙志辉, 张道洪. Fe₂O₃/rGO纳米复合物的制备及其储锂和储钠性能[J]. 物理化学学报, 2016, 32(2): 573-580. doi: 10.3866/PKU.WHXB201511105 shu

Citation: LI Ting, LONG Zhi-Hui, ZHANG Dao-Hong. Synthesis and Electrochemical Properties of Fe₂O₃/rGO Nanocomposites as Lithium and Sodium Storage Materials[J]. Acta Physico-Chimica Sinica, 2016, 32(2): 573-580. doi: 10.3866/PKU.WHXB201511105 shu

Fe₂O₃/rGO纳米复合物的制备及其储锂和储钠性能

1.
中南民族大学化学与材料科学学院, 武汉 430074

通讯作者: 李婷, 张道洪; 李婷, 张道洪

基金项目:
国家自然科学基金(21403305) (21403305)

中南民族大学中央高校基本科研业务费专项资金(CZQ14007)资助项目 (CZQ14007)

摘要: 金属氧化物可通过电化学转换反应与锂离子及钠离子发生多电子可逆结构转换,是一类极具应用前景的高容量锂离子和钠离子电池负极材料。实验以氧化石墨烯和铁盐为前驱体,采用简单的溶剂法,成功将Fe₂O₃纳米单晶粒子均匀负载于石墨烯的导电片层上,获得Fe₂O₃/rGO(还原氧化石墨烯)纳米复合材料。复合电极在锂离子和钠离子电池中都表现出优异的充放电性能和循环稳定性。实验结果表明石墨烯的包覆不仅能降低Fe₂O₃发生转换反应的电荷传递阻抗,而且能够稳定电极在循环过程中带来的结构转变,极大改善电极大电流充放能力和循环稳定性。本研究为发展高容量的锂离子和钠离子电池负极材料提供了可行的途径。

关键词:

English

Synthesis and Electrochemical Properties of Fe₂O₃/rGO Nanocomposites as Lithium and Sodium Storage Materials

1.
College of Chemistry and Materials Science, South-Central University for Nationalities, Wuhan 430074, P. R. China

Corresponding author: 李婷, 张道洪; 李婷, 张道洪

Received Date: 23 September 2015
Fund Project:
国家自然科学基金(21403305)

中南民族大学中央高校基本科研业务费专项资金(CZQ14007)资助项目

Abstract: Metal oxides are promising high-capacity anode materials for lithium and sodium-ion batteries because of the reversible multi-electron structural conversion reactions with lithium and sodium ions. In this study, Fe₂O₃/rGO (reduced graphene oxide) nanocomposites were prepared using graphene oxide sheets and ferric salt as precursors through a one-step solvothermal method. The experimental results demonstrated that the Fe₂O₃ nanocrystals were uniformly dispersed on the surface of reduced graphene oxide sheets. The nanocomposite anodes show superior charge-discharge performances and cyclability in lithium and sodium ion batteries,indicating that reduced graphene oxide sheets can reduce the charge-transfer resistance and stabilize the structure change during cycling. It suggests a potential feasibility to use these metal oxide nanocomposites as high capacity anode materials for lithium and sodium ion batteries.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fe₂O₃/rGO纳米复合物的制备及其储锂和储钠性能

通讯作者: 李婷, 张道洪; 李婷, 张道洪

English

Synthesis and Electrochemical Properties of Fe₂O₃/rGO Nanocomposites as Lithium and Sodium Storage Materials

Corresponding author: 李婷, 张道洪; 李婷, 张道洪

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Fe2O3/rGO纳米复合物的制备及其储锂和储钠性能

通讯作者: 李婷, 张道洪; 李婷, 张道洪

English

Synthesis and Electrochemical Properties of Fe2O3/rGO Nanocomposites as Lithium and Sodium Storage Materials

Corresponding author: 李婷, 张道洪; 李婷, 张道洪

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Fe₂O₃/rGO纳米复合物的制备及其储锂和储钠性能

Synthesis and Electrochemical Properties of Fe₂O₃/rGO Nanocomposites as Lithium and Sodium Storage Materials

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