聚乙烯亚胺修饰的氧化硅纳米管基吸附剂的制备及其CO<sub>2</sub>吸附应用

引用本文: 姚蔓莉, 董艳艳, 谢菁, 贾爱平, 谢冠群, 胡庚申, 罗孟飞. 聚乙烯亚胺修饰的氧化硅纳米管基吸附剂的制备及其CO₂吸附应用[J]. 物理化学学报, 2014, 30(4): 789-796. doi: 10.3866/PKU.WHXB201402123 shu

Citation: YAO Man-Li, DONG Yan-Yan, XIE Jing, JIA Ai-Ping, XIE Guan-Qun, HU Geng-Shen, LUO Meng-Fei. Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO₂ Adsorption[J]. Acta Physico-Chimica Sinica, 2014, 30(4): 789-796. doi: 10.3866/PKU.WHXB201402123 shu

聚乙烯亚胺修饰的氧化硅纳米管基吸附剂的制备及其CO₂吸附应用

基金项目:
国家自然科学基金（21203167）资助项目

摘要:

以P123为模板，1，2-二（三甲氧基硅基）乙烷（BTME）为硅源合成了介孔氧化硅纳米管（E-SNTs）. 将ESNTs经过聚乙烯亚胺（PEI）修饰后制得吸附剂用于捕捉CO₂. 对吸附剂进行了透射电镜（TEM）、物理吸附、傅里叶变换红外（FTIR）光谱、热重分析（TGA）等表征. E-SNTs-PEI 吸附剂的最佳CO₂吸附温度为75 ℃. 吸附剂的CO₂吸附量随着PEI负载量的增加呈现先增大后减小的趋势，其中50%为最佳负载量，此时吸附剂的吸附量最大为3.32 mmol·g^-1. 相比较SBA-15 基吸附剂，E-SNTs 基吸附剂具有更优异的吸附性能. 在有水汽的存在下，吸附剂E-SNTs-50 的CO₂吸附量达到3.75 mmol·g^-1. 经过四次循环吸脱附实验测试E-SNTs-PEI 吸附剂的稳定性能，结果表明其CO₂吸附量基本不变，该吸附剂表现出较好的稳定性和可再生能力.

关键词:

English

Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO₂ Adsorption

1.
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, Zhejiang Province, P. R. China
Received Date: 30 December 2013
Available Online: 31 March 2014
Fund Project:
国家自然科学基金（21203167）资助项目

Abstract:

Mesoporous ethane-silica nanotubes (E-SNTs) were synthesized using P123 as a template and 1,2-bis(trimethoxysilyl)ethane (BTME) as a silica source. E-SNTs were modified with polyethylenimine (PEI) as sorbents for CO₂ adsorption. These new composite sorbents were characterized by transmission electron microscopy (TEM), nitrogen adsorption/desorption, Fourier transform infrared (FTIR) spectroscopy, and thermal gravimetric analysis (TGA). We found that 75 ℃ is the optimal temperature for CO₂ adsorption. E-SNTs with a 50% (w) PEI loading (E-SNTs-50) exhibited a higher CO₂ adsorption capacity (3.32 mmol·g^-1) than the other materials. The E-SNTs-based sorbents show better CO₂ capture performance than the SBA-15-based sorbents. Additionally, CO₂ uptake was further enhanced to 3.75 mmol·g^-1 in the presence of moisture. Cyclic CO₂ adsorption-desorption test results indicated that the composite sorbents are stable and can be regenerated.

Key words:

1. [1]
  
  (1) Samanta, A.; Zhao, A.; Shimizu, G. K. H.; Sarkar, P.; Gupta, R. Ind. Eng. Chem. Res. 2012, 51, 1438. doi: 10.1021/ie200686q
  (1) Samanta, A.; Zhao, A.; Shimizu, G. K. H.; Sarkar, P.; Gupta, R. Ind. Eng. Chem. Res. 2012, 51, 1438. doi: 10.1021/ie200686q
2. [2]
  (2) Liu, L.; Deng, Q. F.; Hou, X. X.; Yuan, Z. Y. J. Mater. Chem. 2012, 22, 15540.(2) Liu, L.; Deng, Q. F.; Hou, X. X.; Yuan, Z. Y. J. Mater. Chem. 2012, 22, 15540.
3. [3]
  (3) Kamarudin, K. S. N.; Alias, N. Fuel Process. Technol. 2013, 106, 332. doi: 10.1016/j.fuproc.2012.08.017(3) Kamarudin, K. S. N.; Alias, N. Fuel Process. Technol. 2013, 106, 332. doi: 10.1016/j.fuproc.2012.08.017
4. [4]
  (4) Gupta, M.; da Silva, E. F.; Hartono, A.; Svendsen, H. F. J. Phys. Chem. B 2013, 117, 9457. doi: 10.1021/jp404356e(4) Gupta, M.; da Silva, E. F.; Hartono, A.; Svendsen, H. F. J. Phys. Chem. B 2013, 117, 9457. doi: 10.1021/jp404356e
5. [5]
  (5) Zoannou, K. S.; Sapsford, D. J.; Griffiths, A. J. International Journal of Greenhouse Gas Control 2013, 17, 423. doi: 10.1016/j.ijggc.2013.05.026(5) Zoannou, K. S.; Sapsford, D. J.; Griffiths, A. J. International Journal of Greenhouse Gas Control 2013, 17, 423. doi: 10.1016/j.ijggc.2013.05.026
6. [6]
  (6) Khoshnevisan, B.; Rafiee, S.; Omid, M.; Mousazadeh, H. Energy 2013, 55, 676. doi: 10.1016/j.energy.2013.04.021(6) Khoshnevisan, B.; Rafiee, S.; Omid, M.; Mousazadeh, H. Energy 2013, 55, 676. doi: 10.1016/j.energy.2013.04.021
7. [7]
  (7) Sema, T.; Naami, A.; Fu, K. Y.; Chen, G. Y.; Liang, Z. W.; Idem, R.; Tontiwachwuthikul, P. Chem. Eng. Sci. 2013, 100, 183. doi: 10.1016/j.ces.2012.12.030(7) Sema, T.; Naami, A.; Fu, K. Y.; Chen, G. Y.; Liang, Z. W.; Idem, R.; Tontiwachwuthikul, P. Chem. Eng. Sci. 2013, 100, 183. doi: 10.1016/j.ces.2012.12.030
8. [8]
  (8) Wang, X. X.; Schwartz, V.; Clark, J. C.; Ma, X. L.; Overbury, S. H.; Xu, X. C.; Song, C. S. J. Phys. Chem. C 2009, 113, 7260. doi: 10.1021/jp809946y(8) Wang, X. X.; Schwartz, V.; Clark, J. C.; Ma, X. L.; Overbury, S. H.; Xu, X. C.; Song, C. S. J. Phys. Chem. C 2009, 113, 7260. doi: 10.1021/jp809946y
9. [9]
  (9) Veawab, A.; Tontiwachwuthikul;, P.; Chakma., A. Ind. Eng. Chem. Res. 1999, 38, 3917. doi: 10.1021/ie9901630(9) Veawab, A.; Tontiwachwuthikul;, P.; Chakma., A. Ind. Eng. Chem. Res. 1999, 38, 3917. doi: 10.1021/ie9901630
10. [10]
  (10) Xu, X.; Song, C.; Wincek, R.; Andresen, J. M.; Miller, B. G.; Scaroni, A. W. Fuel Chemistry Division Preprints 2003, 48, 162.(10) Xu, X.; Song, C.; Wincek, R.; Andresen, J. M.; Miller, B. G.; Scaroni, A. W. Fuel Chemistry Division Preprints 2003, 48, 162.
11. [11]
  (11) Wang, X. X.; Ma, X. L.; Song, C. S.; Locke, D. R.; Siefert, S.; Winans, R. E.; Mollmer, J.; Lange, M.; Moller, A.; Glaser, R. Microporous Mesoporous Mater. 2013, 169, 103. doi: 10.1016/j.micromeso.2012.09.023(11) Wang, X. X.; Ma, X. L.; Song, C. S.; Locke, D. R.; Siefert, S.; Winans, R. E.; Mollmer, J.; Lange, M.; Moller, A.; Glaser, R. Microporous Mesoporous Mater. 2013, 169, 103. doi: 10.1016/j.micromeso.2012.09.023
12. [12]
  (12) Choi, D. H.; Ryoo, R. J. Mater. Chem. 2010, 20, 5544. doi: 10.1039/c0jm00671h(12) Choi, D. H.; Ryoo, R. J. Mater. Chem. 2010, 20, 5544. doi: 10.1039/c0jm00671h
13. [13]
  (13) Belmabkhout, Y.; Serna-Guerrero, R.; Sayari, A. Ind. Eng. Chem. Res. 2010, 49, 359. doi: 10.1021/ie900837t(13) Belmabkhout, Y.; Serna-Guerrero, R.; Sayari, A. Ind. Eng. Chem. Res. 2010, 49, 359. doi: 10.1021/ie900837t
14. [14]
  (14) Jo, C.; Kim, K.; Ryoo, R. Microporous Mesoporous Mater. 2009, 124, 45. doi: 10.1016/j.micromeso.2009.04.037(14) Jo, C.; Kim, K.; Ryoo, R. Microporous Mesoporous Mater. 2009, 124, 45. doi: 10.1016/j.micromeso.2009.04.037
15. [15]
  (15) Liu, L.; Deng, Q. F.; Ma, T. Y.; Lin, X. Z.; Hou, X. X.; Liu, Y. P.; Yuan, Z. Y. J. Mater. Chem. 2011, 21, 16001. doi: 10.1039/c1jm12887f(15) Liu, L.; Deng, Q. F.; Ma, T. Y.; Lin, X. Z.; Hou, X. X.; Liu, Y. P.; Yuan, Z. Y. J. Mater. Chem. 2011, 21, 16001. doi: 10.1039/c1jm12887f
16. [16]
  (16) Xu, X.; Song, C.; Andresen, J. M.; Miller, B. G.; Scaroni, A. W. Energy Fuels 2002, 16, 1463. doi: 10.1021/ef020058u(16) Xu, X.; Song, C.; Andresen, J. M.; Miller, B. G.; Scaroni, A. W. Energy Fuels 2002, 16, 1463. doi: 10.1021/ef020058u
17. [17]
  (17) Ma, X. L.; Wang, X. X.; Song, C. S. J. Am. Chem. Soc. 2009, 131, 5777. doi: 10.1021/ja8074105(17) Ma, X. L.; Wang, X. X.; Song, C. S. J. Am. Chem. Soc. 2009, 131, 5777. doi: 10.1021/ja8074105
18. [18]
  (18) Liu, X.; Li, X. B.; Guan, Z. H.; Liu, J.; Zhao, J.; Yang, Y.; Yang, Q. H. Chem. Commun. 2011, 47, 8073. doi: 10.1039/c1cc12136g(18) Liu, X.; Li, X. B.; Guan, Z. H.; Liu, J.; Zhao, J.; Yang, Y.; Yang, Q. H. Chem. Commun. 2011, 47, 8073. doi: 10.1039/c1cc12136g
19. [19]
  (19) Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, doi: 10.3878/j.issn.1006-9895.2013.13159(19) Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, doi: 10.3878/j.issn.1006-9895.2013.13159
20. [20]
  (20) Feng, X. X.; Hu, G. S.; Hu, X.; Xie, G. Q.; Xie, Y. L.; Lu, J. Q.; Luo, M. F. Ind. Eng. Chem. Res. 2013, 52, 4221. 10.1021/ie301946p(20) Feng, X. X.; Hu, G. S.; Hu, X.; Xie, G. Q.; Xie, Y. L.; Lu, J. Q.; Luo, M. F. Ind. Eng. Chem. Res. 2013, 52, 4221. 10.1021/ie301946p
21. [21]
  (21) Feng, X.X; Xie, J.; Hu, G. S.; Jia, A. P.; Xie, G. Q.; Luo, M.F. Acta Phys. -Chim. Sin. 2013, 29, 1266. [冯星星, 谢菁, 胡庚申, 贾爱平, 谢冠群, 罗孟飞. 物理化学学报. 2013, 29, 1266.] doi: 10.3866/PKU.WHXB201304091(21) Feng, X.X; Xie, J.; Hu, G. S.; Jia, A. P.; Xie, G. Q.; Luo, M.F. Acta Phys. -Chim. Sin. 2013, 29, 1266. [冯星星, 谢菁, 胡庚申, 贾爱平, 谢冠群, 罗孟飞. 物理化学学报. 2013, 29, 1266.] doi: 10.3866/PKU.WHXB201304091
22. [22]
  (22) Xu, X.; Song, C.; Andrésen, J. M.; Miller, B. G.; Scaroni, A. W. Microporous Mesoporous Mater. 2003, 62, 29. 10.1016/S1387-1811(03)00388-3(22) Xu, X.; Song, C.; Andrésen, J. M.; Miller, B. G.; Scaroni, A. W. Microporous Mesoporous Mater. 2003, 62, 29. 10.1016/S1387-1811(03)00388-3
23. [23]
  (23) Son, W. J.; Choi, J. S.; Ahn, W. S. Microporous Mesoporous Mater. 2008, 113, 31. doi: 10.1016/j.micromeso.2007.10.049(23) Son, W. J.; Choi, J. S.; Ahn, W. S. Microporous Mesoporous Mater. 2008, 113, 31. doi: 10.1016/j.micromeso.2007.10.049
24. [24]
  (24) Satyapal, S.; Filburn, T.; Trela, J.; Strange, J. Energy Fuels 2001, 15, 250. doi: 10.1021/ef0002391
  (24) Satyapal, S.; Filburn, T.; Trela, J.; Strange, J. Energy Fuels 2001, 15, 250. doi: 10.1021/ef0002391

扫一扫看文章

计量

PDF下载量: 572
文章访问数: 945
HTML全文浏览量: 12

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

聚乙烯亚胺修饰的氧化硅纳米管基吸附剂的制备及其CO₂吸附应用

English

Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO₂ Adsorption

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

聚乙烯亚胺修饰的氧化硅纳米管基吸附剂的制备及其CO2吸附应用

English

Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO2 Adsorption

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

聚乙烯亚胺修饰的氧化硅纳米管基吸附剂的制备及其CO₂吸附应用

Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO₂ Adsorption

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs