Al-Fe-P三元系的热力学优化

引用本文: 曹战民, 谢伟, 王昆鹏, 牛春菊, 杜广巍, 乔芝郁. Al-Fe-P三元系的热力学优化[J]. 物理化学学报, 2013, 29(10): 2148-2156. doi: 10.3866/PKU.WHXB201307291 shu

Citation: CAO Zhan-Min, XIE Wei, WANG Kun-Peng, NIU Chun-Ju, DU Guang-Wei, QIAO Zhi-Yu. Thermodynamic Optimization of the Al-Fe-P Ternary System[J]. Acta Physico-Chimica Sinica, 2013, 29(10): 2148-2156. doi: 10.3866/PKU.WHXB201307291 shu

Al-Fe-P三元系的热力学优化

曹战民 ^1, ,
谢伟 ^1, ,
王昆鹏 ^1, ,
牛春菊 ^2, ,
杜广巍 ^1, ,
乔芝郁 ^1,

基金项目:
国家自然科学基金(50934011, 51274034) (50934011, 51274034)

中央高校基础研究基金(FRF-SD-12-010A)资助项目 (FRF-SD-12-010A)

摘要:

采用CALPHAD方法对Al-Fe-P三元系进行了热力学评估, 并根据相关的实验数据对边际二元系Al-P进行了热力学再优化, Al-Fe和Fe-P边际二元系的热力学参数取自之前的研究并做了局部调整. 根据相图数据和热力学数据优化了Al-Fe-P三元系的热力学模型参数, 获得了体系中所有相的Gibbs自由能表达式. 所得参数之间自洽且能很好地重现Al-Fe-P体系的大部分实验相图信息. 通过驱动力判据和本文优化所得的模型参数,从热力学上解释了该体系非晶形成能力与组成之间的关系.

关键词:

Al-Fe-P
/ 相图
/ 热力学
/ 评估
/ 非晶形成能力

English

Thermodynamic Optimization of the Al-Fe-P Ternary System

1.
1 State Key Laboratory of Advanced Metallurgy, School of Metallurgical and Ecological Engineering, University of Science & Technology Beijing, Beijing 100083, P. R. China;
2 School of Materials Science and Engineering, University of Science & Technology Beijing, Beijing 100083, P. R. China
Received Date: 01 April 2013
Available Online: 26 September 2013
Fund Project:
国家自然科学基金(50934011, 51274034)

中央高校基础研究基金(FRF-SD-12-010A)资助项目

Abstract:

A critical thermodynamic optimization of the Al-Fe-P ternary system was performed using the CALPHAD method. Among the sub-binary systems in the Al-Fe-P system, the Al-P systemwas reassessed according to its related experimental information. The thermodynamic descriptions of the Al-Fe and Fe-Pbinary systems were taken from previous studies with minor modifications. The parameters of the thermodynamic model of the Al-Fe-P ternary systemwere optimized based on available experimental phase diagramdata and thermodynamic properties. One set of consistent parameters of the Gibbs energies of all phases, which can satisfactorily reproduce most of the experimental phase diagramdata, was obtained. By employing the driving force criterion with the present thermodynamic description, the experimentally reported composition dependence of the glass-forming ability of the Al-Fe-P systemcould be explained thermodynamically.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Al-Fe-P三元系的热力学优化

English

Thermodynamic Optimization of the Al-Fe-P Ternary System

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Al-Fe-P三元系的热力学优化

English

Thermodynamic Optimization of the Al-Fe-P Ternary System

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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