枝晶状Pt 薄膜的制备及其特殊红外效应

引用本文: 周志有, 林建龙, 商淑静, 任洁, 孙世刚. 枝晶状Pt 薄膜的制备及其特殊红外效应[J]. 物理化学学报, 2012, 28(07): 1745-1750. doi: 10.3866/PKU.WHXB201205082 shu

Citation: ZHOU Zhi-You, LIN Jian-Long, SHANG Shu-Jing, REN Jie, SUN Shi-Gang. Preparation of Dendritic Pt Thin Films and Their Anomalous Infrared Effects[J]. Acta Physico-Chimica Sinica, 2012, 28(07): 1745-1750. doi: 10.3866/PKU.WHXB201205082 shu

枝晶状Pt 薄膜的制备及其特殊红外效应

基金项目:
国家自然科学基金(21073152, 20933004, 20833005, 21021002) (21073152, 20933004, 20833005, 21021002)

福建省高校杰出青年科研人才培育计划(JA10003)资助项目 (JA10003)

摘要:

采用方波电位, 在10×10^-3 mol·L^-1 K₂PtCl₆+3×10^-4 mol·L^-1 PbAc₂+0.5 mol·L^-1 HClO₄溶液中, 于本体Pt 电极上电沉积制备出枝晶状Pt 薄膜. 随着沉积时间的增加, 枝晶长度逐渐由400 nm增加到900 nm, 且枝晶上的小晶粒(~10 nm大小)变得密集. 根据循环伏安(CV)曲线中氢吸脱附电量可得出Pt 薄膜具有中等粗糙度(C_r=9-36), 且电极表面的粗糙度随着沉积时间增加而增大. 观察到Pt 薄膜上吸附态CO的原位红外光谱具有明显的增强吸收效应, 当沉积时间为6 min 时所制得的枝晶Pt 电极的红外增强效应最大. CO呈现多种谱峰形状, 随着沉积时间的增加, 谱峰形状依次为左高右低的双极峰(类Fano 红外效应), 单极向下(表面增强红外吸收), 左高右低的双极峰, 单极向上(异常红外效应), 左低右高的双极峰和单极向下. 这表明纳米材料薄膜所呈现出的特殊红外性能, 与纳米材料的尺度和聚集状态等密切相关. 所制备的枝晶状Pt 薄膜有望为深入认识纳米材料的特殊红外性能提供一个良好的模型材料.

关键词:

English

Preparation of Dendritic Pt Thin Films and Their Anomalous Infrared Effects

1.
State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
Received Date: 24 February 2012
Available Online: 07 June 2012
Fund Project:
国家自然科学基金(21073152, 20933004, 20833005, 21021002)

福建省高校杰出青年科研人才培育计划(JA10003)资助项目

Abstract:

Dendritic Pt thin films are electrodeposited on bulk Pt electrodes in 10×10^-3 mol·L^-1 K₂PtCl₆+3× 10^-4 mol·L^-1 PbAc₂ + 0.5 mol·L^-1 HClO₄ using square-wave potential pulses. As the deposition time increases, the length of the Pt dendrites increases from 400 to 900 nm, and the distribution density of Pt nanoparticles (~10 nm), which consist of coiled Pt dendrites, increases greatly. From hydrogen adsorption/ desorption obtained from cyclic voltammograms (CV), the surface of the dendritic Pt thin film electrodes has a relative roughness (C_r), which increases from 9 to 36 as the deposition time increases. Maximum enhanced IR absorption of adsorbed CO (CO_ad) is observed at the deposition time of 6 min. Anomalous infrared effects for CO_ad are also seen on the dendritic Pt thin film electrodes. The line shapes of CO_ad change with increasing deposition time, in order: bipolar→downward→bipolar→upward→bipolar→ downward bands. Fano-like infrared effects (bipolar), surface enhanced IR absorption (enhanced downward band), and abnormal IR effects (enhanced upward band) are highly dependent on the surface architecture of the nanostructures. The as-prepared dendritic Pt thin films provide model substrates for in-depth studies of the anomalous infrared effects of CO_ad in metal nanostructures.

Key words:

In situ Fourier transform infrared spectroscopy
/ Dendritic Pt thin film
/ Fano-like infrared effect
/ Surface enhanced IR absorption
/ Abnormal IR effect

1. [1]
  
  (1) Bjerke, A. E.; Griffiths, P. R.; Theiss,W. Anal. Chem. 1999, 71,1967. doi: 10.1021/ac981093u
  (1) Bjerke, A. E.; Griffiths, P. R.; Theiss,W. Anal. Chem. 1999, 71,1967. doi: 10.1021/ac981093u
2. [2]
  (2) Camara, G. A.; mes, J. F.; Bergamaski, K.; Teixeira-Neto, E.;Nart, F. C. J. Electroanal. Chem. 2008, 617, 171. doi: 10.1016/j.jelechem.2008.02.005(2) Camara, G. A.; mes, J. F.; Bergamaski, K.; Teixeira-Neto, E.;Nart, F. C. J. Electroanal. Chem. 2008, 617, 171. doi: 10.1016/j.jelechem.2008.02.005
3. [3]
  (3) Sato, T.; Okaya, K.; Yano, H.;Wanatabe, M.; Uchida, H. ACS Catal. 2012, 2, 450. doi: 10.1021/cs200550t(3) Sato, T.; Okaya, K.; Yano, H.;Wanatabe, M.; Uchida, H. ACS Catal. 2012, 2, 450. doi: 10.1021/cs200550t
4. [4]
  (4) Zhang, P.;Wang, L. F.; Xu, J. C. Spectroscopy and Spectral Analysis 2003, 23, 46. [张平, 王乐夫, 徐建昌. 光谱学与光谱分析, 2003, 23, 46.](4) Zhang, P.;Wang, L. F.; Xu, J. C. Spectroscopy and Spectral Analysis 2003, 23, 46. [张平, 王乐夫, 徐建昌. 光谱学与光谱分析, 2003, 23, 46.]
5. [5]
  (5) Lin,W. F.; Iwasita, T.; Vielstich,W. J. Phys. Chem. B 1999, 103,3250. doi: 10.1021/jp984491+(5) Lin,W. F.; Iwasita, T.; Vielstich,W. J. Phys. Chem. B 1999, 103,3250. doi: 10.1021/jp984491+
6. [6]
  (6) Harstein, A.; Kirtley, J. R.; Tsang, J. C. Phys. Rev. Lett. 1980,45, 201. doi: 10.1103/PhysRevLett.45.201(6) Harstein, A.; Kirtley, J. R.; Tsang, J. C. Phys. Rev. Lett. 1980,45, 201. doi: 10.1103/PhysRevLett.45.201
7. [7]
  (7) Osawa, M. Bull. Chem. Soc. Jpn. 1997, 70, 2861. doi: 10.1246/bcsj.70.2861(7) Osawa, M. Bull. Chem. Soc. Jpn. 1997, 70, 2861. doi: 10.1246/bcsj.70.2861
8. [8]
  (8) Fano, U. Phys. Rev. 1961, 6, 1866.(8) Fano, U. Phys. Rev. 1961, 6, 1866.
9. [9]
  (9) Lu, G. Q.; Sun, S. G.; Cai, L. R.; Chen, S. P.; Tian, Z.W.Langmuir 2000, 16, 778. doi: 10.1021/la990282k(9) Lu, G. Q.; Sun, S. G.; Cai, L. R.; Chen, S. P.; Tian, Z.W.Langmuir 2000, 16, 778. doi: 10.1021/la990282k
10. [10]
  (10) Miki, A.; Ye, S.; Osawa, M. Chem. Commun. 2002, 1500.(10) Miki, A.; Ye, S.; Osawa, M. Chem. Commun. 2002, 1500.
11. [11]
  (11) Chen, Y. X.; Miki, A.; Ye, S.; Sakai, H.; Osawa, M. J. Am. Chem. Soc. 2003, 125, 3680. doi: 10.1021/ja029044t(11) Chen, Y. X.; Miki, A.; Ye, S.; Sakai, H.; Osawa, M. J. Am. Chem. Soc. 2003, 125, 3680. doi: 10.1021/ja029044t
12. [12]
  (12) Huo, S. J.; Xue, X. K.; Yan, Y. G.; Li, Q. X.; Ma, M.; Cai,W.B.; Xu, Q. J.; Osawa, M. J. Phys. Chem. B 2006, 110, 4162. doi: 10.1021/jp0566966(12) Huo, S. J.; Xue, X. K.; Yan, Y. G.; Li, Q. X.; Ma, M.; Cai,W.B.; Xu, Q. J.; Osawa, M. J. Phys. Chem. B 2006, 110, 4162. doi: 10.1021/jp0566966
13. [13]
  (13) Huo, S. J.; Xue, X. K.; Li, Q. X.; Xu, S. F.; Cai,W. B. J. Phys. Chem. B 2006, 110, 25721. doi: 10.1021/jp064036a(13) Huo, S. J.; Xue, X. K.; Li, Q. X.; Xu, S. F.; Cai,W. B. J. Phys. Chem. B 2006, 110, 25721. doi: 10.1021/jp064036a
14. [14]
  (14) Cai, L. R.; Sun, S. G.; Xia, S. Q.; Chen, F.; Zheng, M. S.; Chen,S. P.; Lu, G. Q. Acta Phys. -Chim. Sin. 1999, 15, 1023. [蔡丽蓉, 孙世刚, 夏盛清, 陈芳, 郑明森, 陈声培, 卢国强. 物理化学学报, 1999, 15, 1023.] doi: 10.3866/PKU.WHXB19991113(14) Cai, L. R.; Sun, S. G.; Xia, S. Q.; Chen, F.; Zheng, M. S.; Chen,S. P.; Lu, G. Q. Acta Phys. -Chim. Sin. 1999, 15, 1023. [蔡丽蓉, 孙世刚, 夏盛清, 陈芳, 郑明森, 陈声培, 卢国强. 物理化学学报, 1999, 15, 1023.] doi: 10.3866/PKU.WHXB19991113
15. [15]
  (15) ng, H.; Sun, S. G.; Li, J. T.; Chen, Y. J.; Chen, S. P.Electrochim. Acta 2003, 48, 2933. doi: 10.1016/S0013-4686(03)00358-X(15) ng, H.; Sun, S. G.; Li, J. T.; Chen, Y. J.; Chen, S. P.Electrochim. Acta 2003, 48, 2933. doi: 10.1016/S0013-4686(03)00358-X
16. [16]
  (16) Chen, Q. S.; Sun, S. G.; Yan, J.W.; Li, J. T.; Zhou, Z. Y.Langmuir 2006, 22, 10575. doi: 10.1021/la0615037(16) Chen, Q. S.; Sun, S. G.; Yan, J.W.; Li, J. T.; Zhou, Z. Y.Langmuir 2006, 22, 10575. doi: 10.1021/la0615037
17. [17]
  (17) Ortiz, R.; Cuesta, A.; Marquez, O. P.; Gutierrez, C.J. Electroanal. Chem. 1999, 465, 234. doi: 10.1016/S0022-0728(99)00099-6(17) Ortiz, R.; Cuesta, A.; Marquez, O. P.; Gutierrez, C.J. Electroanal. Chem. 1999, 465, 234. doi: 10.1016/S0022-0728(99)00099-6
18. [18]
  (18) Orozco, G.; Gutierrez, C. J. Electroanal. Chem. 2000, 484, 64.doi: 10.1016/S0022-0728(00)00062-0(18) Orozco, G.; Gutierrez, C. J. Electroanal. Chem. 2000, 484, 64.doi: 10.1016/S0022-0728(00)00062-0
19. [19]
  (19) Lin,W. G.; Sun, S. G.; Zhou, Z. Y.; Chen, S. P.;Wang, H. C.J. Phys. Chem. B 2002, 106, 11778. doi: 10.1021/jp025917u(19) Lin,W. G.; Sun, S. G.; Zhou, Z. Y.; Chen, S. P.;Wang, H. C.J. Phys. Chem. B 2002, 106, 11778. doi: 10.1021/jp025917u
20. [20]
  (20) Chen, Z.; Sun, S. G.; Ding, N.; Zhou, Z. Y. Chin. Sci. Bull.2001, 46, 1439. doi: 10.1007/BF03187026(20) Chen, Z.; Sun, S. G.; Ding, N.; Zhou, Z. Y. Chin. Sci. Bull.2001, 46, 1439. doi: 10.1007/BF03187026
21. [21]
  (21) Chen, Q. S.; Sun, S. G.; Zhou, Z. Y.; Chen, Y. X.; Deng, S. B.Phys. Chem. Chem. Phys. 2008, 10, 3645.(21) Chen, Q. S.; Sun, S. G.; Zhou, Z. Y.; Chen, Y. X.; Deng, S. B.Phys. Chem. Chem. Phys. 2008, 10, 3645.
22. [22]
  (22) ng, H.; Sun, S. G.; Chen, Y. J.; Chen, S. P. J. Phys. Chem. B2004, 108, 11575. doi: 10.1021/jp0375822(22) ng, H.; Sun, S. G.; Chen, Y. J.; Chen, S. P. J. Phys. Chem. B2004, 108, 11575. doi: 10.1021/jp0375822
23. [23]
  (23) Chen, Y. J.; Sun, S. G.; Chen, S. P.; Li, J. T.; ng, H. Langmuir2004, 20, 9920. doi: 10.1021/la048484q(23) Chen, Y. J.; Sun, S. G.; Chen, S. P.; Li, J. T.; ng, H. Langmuir2004, 20, 9920. doi: 10.1021/la048484q
24. [24]
  (24) Feltham, A. M.; Spiro, M. Chem. Rev. 1971, 71, 177. doi: 10.1021/cr60270a002(24) Feltham, A. M.; Spiro, M. Chem. Rev. 1971, 71, 177. doi: 10.1021/cr60270a002
25. [25]
  (25) Su, Z. F.; Sun, S. G.;Wu, C. X.; Cai, Z. P. J. Chem. Phys. 2008,129, 044707. doi: 10.1063/1.2953441(25) Su, Z. F.; Sun, S. G.;Wu, C. X.; Cai, Z. P. J. Chem. Phys. 2008,129, 044707. doi: 10.1063/1.2953441
26. [26]
  (26) Krauth, O.; Fahsold, G.; Pucci, A. J. Mol. Struct. 1999, 482,237. doi: 10.1016/S0022-2860(98)00851-5(26) Krauth, O.; Fahsold, G.; Pucci, A. J. Mol. Struct. 1999, 482,237. doi: 10.1016/S0022-2860(98)00851-5
27. [27]
  (27) Krauth, O.; Fahsold, G.; Pucci, A. J. Chem. Phys. 1999, 110,3113. doi: 10.1063/1.477907(27) Krauth, O.; Fahsold, G.; Pucci, A. J. Chem. Phys. 1999, 110,3113. doi: 10.1063/1.477907
28. [28]
  (28) Wu, C. X.; Lin, H.; Chen, Y. J.; Li,W. X.; Sun, S. G. J. Chem. Phys. 2004, 121, 1553. doi: 10.1063/1.1763135(28) Wu, C. X.; Lin, H.; Chen, Y. J.; Li,W. X.; Sun, S. G. J. Chem. Phys. 2004, 121, 1553. doi: 10.1063/1.1763135
29. [29]
  (29) Wu, C. X.; Zhao,W.; Iwamoto, M.; Ouyang, Z. C. J. Chem. Phys. 2000, 112, 10548. doi: 10.1063/1.481688
  (29) Wu, C. X.; Zhao,W.; Iwamoto, M.; Ouyang, Z. C. J. Chem. Phys. 2000, 112, 10548. doi: 10.1063/1.481688

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

枝晶状Pt 薄膜的制备及其特殊红外效应

English

Preparation of Dendritic Pt Thin Films and Their Anomalous Infrared Effects

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

枝晶状Pt 薄膜的制备及其特殊红外效应

English

Preparation of Dendritic Pt Thin Films and Their Anomalous Infrared Effects

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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